CHEMISTRY GLOSSARY

pectin    →   pektin

Pectins are complex highmolecular carbohydrates, formed mostly from galacturonic acid. They are present in many kinds of fruit and vegetable and are used in the production of fruit jellies.

pentose    →   pentoza

Pentose is a monosaccharide with five carbon atoms in its chain.

petroleum ether    →   petroleter

Petroleum ether is the petroleum fraction consisting of C₅ and C₆ hydrocarbons and boiling in the range 35 °C to 60 °C; commonly used as a laboratory solvent.

pit coal    →   kameni ugljen

Pit coal is natural black coal that has a carbon content of 75 %-90 %. It is an important raw material in organic industry

polyens    →   polieni

Polyens are unsaturated acyclic compounds with many conjugated double connections between atoms of carbon (CH₂=CH-CH=CH-CH=CH₂).

groups in periodic system of elements    →   skupine periodnog sustava

Periodic system of elements is divided into 18 groups of chemical elements. Elements belonging to the same group have a same number of valence electrons and similar chemical properties. Elements of main groups are in 1., 2., and in groups 13. to 18. Different groups of elements can be named according to the first element in the group (elements of boron group, elements of carbon group), or they have some special names (noble gases, halogenic elements, halyde elements, earthalkali and alkali metals).

Hesse’s law    →   Hessov zakon

Hesse’s law says that reaction heat of some chemical change does not depend on the way in which the reaction is conducted, but only on starting and ending system state. Hesse’s law is also known as the law of constant heat summation. Hesse’s law is also known as the law of constant heat summation. The law was first put forward in 1840 by the Swiss-born Russian chemist Germain Henri Hess (1802-1850).

Hesse’s law can be used to obtain thermodynamic data that cannot be measured directly. For example, it is very difficult to control the oxidation of graphite to give pure CO. However, enthalpy for the oxidation of graphite to CO₂ can easily be measured. So can the enthalpy of oxidation of CO to CO₂. The application of Hess’s law enables us to estimate the enthalpy of formation of CO.

The equation shows the standard enthalpy of formation of CO to be -110 kJ/mol.

polyvalent element    →   polivalentni elementi

Polyvalent element is a molecule which having more than one valence, for example oxygen is a divalent in H₂O, nitrogen is a trivalent in NH₃, carbon is a tetravalent in methane (CH₄).

primary alcohol    →   primarni alkohol

Primary alcohols are alcohols where the hydroxyl group is attached to a primary carbon atom. Thus, it has the general structure, RCH₂OH, where R is a hydrogen atom or an alkyl group.

hydrophobic interaction    →   hidrofobne interakcije

Hydrophobic interaction is the tendency of hydrocarbons (or of lipophilic hydrocarbon-like groups in solutes) to form intermolecular aggregates in an aqueous medium, and analogous intramolecular interactions. The name arises from the attribution of the phenomenon to the apparent repulsion between water and hydrocarbons. Use of the misleading alternative term hydrophobic bond is discouraged.