CHEMISTRY GLOSSARY
unequal-arm balance → vaga s različitim krakovima
The lever principle on which these scales are constructed is based on the law of physics that at equilibrium the force applied at one end of the lever multiplied by the length of the arm (distance from the fulcrum to the point where the force is applied) must be equal to the product of the force acting at the opposite end of the lever and the length of the other arm.
The unequal-arm balance is preferred for work when large amounts are to be weighed.
equal-arm balance → vaga s jednakim krakovima
The simplest type of balance, the equal-arm balance, is an application of a first class lever. The beam of the balance is supported on a central knife-edge, usually of agate, which rests upon a plane agate plate. The point of support is called the fulcrum. Two pans of equal weight are suspended from the beam, one at each end, at points equidistant from the fulcrum. A long pointer attached at right angles to the beam at the fulcrum indicates zero on a scale when the beam is at rest parallel to a level surface.
To prevent the knife-edge from becoming dull under the weight of the beam and pans the balance is equipped with a special device called an arrest. The arrest is operated by means of milled knob underneath the base plate in the middle and in front of the balance (sometimes the arrest knob is at one side of the balance).
The object to be weighed is placed on one pan, and standard weights are added to the other until the balance of the beam is established again. When not in use and during loading or unloading of the pans, the balance should be arrested.
analytical balance → analitička vaga
Analytical balances are instruments used for precise determining mass of matter. Analytical balances are sensitive and expensive instruments, and upon their accuracy and precision the accuracy of analysis result depends. The most widely used type of analytical balances are balances with a capacity of 100 g and a sensitivity of 0.1 mg. Not one quantitative chemical analysis is possible without usage of balances, because, regardless of which analytical method is being used, there is always a need for weighing a sample for analysis and the necessary quantity of reagents for solution preparation.
The working part of the balance is enclosed in a glass-fitted case. The baseplate is usually of black glass or black slate. The beam has agate knife-edges at its extremes, supporting stirrups from which balance pans are suspended. Another agate or steel knife-edge is fixed exactly in the middle of the beam on its bottom side. This knife-edge faces downwards and supports the beam. When not in use and during loading or unloading of the pans, the balance should be arrested.
The principle of operation of a modern laboratory balance bears some resemblance to its predecessor - the equal arm balance. The older instrument opposed the torque exerted by an unknown mass on one side of a pivot to that of an adjustable known weight on the other side. When the pointer returned to the center position, the torques must be equal, and the weight was determined by the position of the moving weights.
Modern electronic laboratory balances work on the principle of magnetic force restoration. In this system, the force exerted by the object being weighed is lifted by an electromagnet. A detector measures the current required to oppose the downward motion of the weight in the magnetic field.
balance → vaga
Balance is an instrument to measure the mass (or weight) of a body. Balance beam type scales are the oldest type and measure weight using a fulcrum or pivot and a lever with the unknown weight placed on one end of the lever, and a counterweight applied to the other end. When the lever is balanced, the unknown weight and the counterweight are equal. The equal-arm balance consists of two identical pans hung from either end of a centrally suspended beam. The unequal-arm balance is made with one arm of the balance much longer than the other.
More modern substitution balances use the substitution principle. In this calibrated weights are removed from the single lever arm to bring the single pan suspended from it into equilibrium with a fixed counter weight. The substitution balance is more accurate than the two-pan device and enables weighing to be carried out more rapidly.
Electromagnetic force restoration balances also use a lever system but a magnetic field is used to generate the force on the opposite end of the lever and balance out the unknown mass. The current used to drive the magnetic coil is proportional to the mass of the object placed on the platform.
precision balance → tehnička vaga
Precision balances typically display results from three to one decimal places (0.001 g up to 0.1 g). The readability precision balances are reduced when compared to analytical balances but, precision balances accommodate higher capacities (up to several kilograms). In its traditional form, it consists of a pivoted horizontal lever of equal length arms, called the beam, with a weighing pan, also called scale, suspended from each arm.
In electronic top pan, or toploader balances, mass is determined not by mechanical deflection but by electronically controlled compensation of an electric force. The signal generated enables the mass to be read from a digital display. The mass of the empty container can be stored in the balance’s computer memory and automatically deducted from the mass of the container plus its contents.
standard → standard
Standards are materials containing a known concentration of an analyte. They provide a reference to determine unknown concentrations or to calibrate analytical instruments.
The accuracy of an analytical measurement is how close a result comes to the true value. Determining the accuracy of a measurement usually requires calibration of the analytical method with a known standard. This is often done with standards of several concentrations to make a calibration or working curve.
A primary standard is a reagent that is extremely pure, stable, has no waters of hydration, and has a high molecular weight.
A secondary standard is a standard that is prepared in the laboratory for a specific analysis. It is usually standardised against a primary standard.
abundance of elements → rasprostranjenost elemenata
Elements in nature are mostly found in different compounds and, rarely, in the free (elementary) state. In Earth’s crust the most abundant of all elements is oxygen (with 49.5 %), then silicon (25 %), aluminium (7.5 %), iron (4.7 %), calcium (3.4 %), sodium (2.6 %), potassium (2.4 %), magnesium (1.9 %) and hydrogen (1.9 %). These nine elements make up almost 99 % of the Earth’s composition.
allotropy → alotropija
Allotropy (Gr. allos, other, and tropos, manner) is the phenomenon of an element existing in two or more physical forms in the same physical state. The difference between the forms involves either crystaline structure (white, red and black phosphorus), the number of atoms in the molecule of a gas (diatomic oxygen and triatomic ozone), or the molecular structure of a liquid (liquid helium an helium II).
In some cases, the allotropes are stable over a temperature range, with a definite transition point at which one changes into the other. For instance, tin has two allotropes: white (metallic) tin stable above 13.2 °C and grey (nonmetallic) tin stable below 13.2 °C. This form allotropy is called enantiotropy. Form of allotropy, in which there is no transition temperature at which the two are in equilibrium, is called monotropy.
Allotropy does not apply to the substance existing in different physical states as, for example, when ice melts and changes from solid ice to liquid water.
Allotropy is generally restricted to describing polymorphic behaviour in elements, while polymorphism may refer to any material having multiple crystal structures.
Citing this page:
Generalic, Eni. "Vaga s različitim krakovima." Croatian-English Chemistry Dictionary & Glossary. 29 June 2022. KTF-Split. {Date of access}. <https://glossary.periodni.com>.
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