Fatty acids are aliphatic monocarboxylic acids characterized by a terminal carboxyl group (R-COOH). The higher members of this series of acids occur in nature in the combined form of esters of glycerol (fats), and hence all acids of this family are called fatty acids. Natural fatty acids commonly have a chain of 4 to 28 carbons (usually unbranched and even-numbered), which may be saturated or unsaturated. The most important of saturated fatty acids are butyric (C4), lauric (C12), palmitic (C16), and stearic (C18). The most common unsaturated acids are oleic, linoleic, and linolenic (all C18).
The physical properties of fatty acids are determined by the chain length, degree of unsaturation, and chain branching. Short-chain acids are pungent liquids, soluble in water. As the chain length increases, melting points are raised and water-solubility decreases. Unsaturation and chain branching tend to lower melting points.
Omega-3 fatty acids are polyunsaturated fatty acids, meaning they contain more than one double bond. The name omega-3 indicates that the first double bond occurs on the third carbon atom (n-3) from the methyl (-CH3) end of the molecule (omega position). The three main omega-3 fatty acids are alpha-linolenic acid (ALA, 18:3n-3), eicosapentaenoic acid (EPA, 20:5n-3), and docosahexaenoic acid (DHA, 22:6n-3). ALA comes from plants. EPA and DHA come from fish.
Similarly, the first double bond in omega-6 fatty acids is located between the sixth and seventh carbon atom (n-6) from the methyl end of the fatty acid (omega end).
Saturated fatty acid is a fatty acid carrying the maximum possible number of hydrogen atoms (It doesn’t have any double bounds in the alkyl chain). The most important of these are:
Butyric (butanoic acid) | CH3(CH2)2COOH |
Lauric (dodecanoic acid) | CH3(CH2)10COOH |
Myristic (tetradecanoic acid) | CH3(CH2)12COOH |
Palmitic (hexadecanoic acid) | CH3(CH2)14COOH |
Stearic (octadecanoic acid) | CH3(CH2)16COOH |
Arachidic (eicosanoic acid) | CH3(CH2)18COOH |
Unsaturated fatty acid is a fatty acid whose carbon chain can absorb additional hydrogen atoms. Their carbon chain has one or more double or triple valence bond per molecule. The most important of these are:
Oleic (9-octadecenoic acid) | CH3(CH2)7CH=CH(CH2)7COOH |
Linoleic (9,12-octadecadienoic acid) | CH3(CHCH2)3(CH2CH=CH)2(CHCH2)7COOH |
Linolenic (9,12,15-octadecatrienoic acid) | CH3(CH2CH=CH)3(CHCH2)7COOH |
Antioxidants are compounds that slow down oxidation processes that degrade foods, fuels, rubber, plastic, and other materials. Antioxidants like butylated hydroxyanisole (BHA), are added to food to prevent fats from becoming rancid and to minimize decomposition of vitamins and essential fatty acids; they work by scavenging destructive free radicals from the food.
Asbestos is any one of a group of fibrous amphibole minerals (from the silicate group). It has widespread commercial uses because of its resistance to heat, chemical inertness., and high electrical resistance. Since 1970s short asbestos fibres have been recognized as a cause of asbestosis, a serious lung disorder, and mesothelioma, a fatal form of lung cancer. These concerns have limited its use and imposed many safety procedures when it is used.
Carboxylic acids are organic compounds characterized by the presence of one or more RC(=O)OH groups (the carboxyl group). In the systematic chemical nomenclature carboxylic acids names end in the suffix -oic (e.g. ethanoic acids, CH3COOH). The carbon of the terminal group being counted as part of the chain. They are generally weak acids. Carboxylic acids include a large and important class of fatty acids and may be either saturated or unsaturated. There are also some natural aromatic carboxylic acids (benzoic, salicylic).
Carotenoids are a group of natural pigments in plants responsible for yellow and orange colours, meltable in fats.
Chemical cleaning is a removal of fatty and other impurities combined with it from fabrics with the help of organic solvents.
Coenzyme A (CoA) is an essential metabolic cofactor synthesized from cysteine, pantothenate (vitamin B5), and ATP. CoA plays important roles in many metabolic pathways, including the tricarboxylic acid (TCA) cycle, and the synthesis and oxidation of fatty acids. One of the main functions of CoA is the carrying and transfer of acyl groups. Acylated derivatives (acetyl-CoA) are critical intermediates in many metabolic reactions.
Generalic, Eni. "Fats." Croatian-English Chemistry Dictionary & Glossary. 29 June 2022. KTF-Split. {Date of access}. <https://glossary.periodni.com>.
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