CHEMISTRY GLOSSARY

bag filter    →   vrećasti filtar

Bag filter is a unit within a mechanical system that bellows in a bag form when air flows through, cleaning the air by collecting particles of foreign matter. This system of filtering is rated the most efficient- in a range of 92 % to 95 %. Vacuum cleaner have a cloth filter bag.

Bag filter system is an economical method of liquid filtration consisting of the pressure vessel, restrainer basket and micron rated filter bag. Liquid flow is from the inside to the outside of the bag - dirt is trapped inside the bag.

balance    →   vaga

Balance is an instrument to measure the mass (or weight) of a body. Balance beam type scales are the oldest type and measure weight using a fulcrum or pivot and a lever with the unknown weight placed on one end of the lever, and a counterweight applied to the other end. When the lever is balanced, the unknown weight and the counterweight are equal. The equal-arm balance consists of two identical pans hung from either end of a centrally suspended beam. The unequal-arm balance is made with one arm of the balance much longer than the other.

More modern substitution balances use the substitution principle. In this calibrated weights are removed from the single lever arm to bring the single pan suspended from it into equilibrium with a fixed counter weight. The substitution balance is more accurate than the two-pan device and enables weighing to be carried out more rapidly.

Electromagnetic force restoration balances also use a lever system but a magnetic field is used to generate the force on the opposite end of the lever and balance out the unknown mass. The current used to drive the magnetic coil is proportional to the mass of the object placed on the platform.

ball mill    →   kuglični mlin

Ball mill is a grinder for reducing hard materials to powder. The grinding is carried out by the pounding and rolling of a charge of steel or ceramic balls carried within the cylinder. The cylinder rotates at a relatively slow speed, allowing the balls to cascade through the mill base, thus grinding or dispersing the materials.

Type of ball mills, centrifugal and planetary mills, are devices used to rapidly grind materials to colloidal fineness (approximately 1 μm and below) by developing high grinding energy via centrifugal and/or planetary action.

Balmer series    →   Balmerova serija

Balmer series, Balmer lines is a series of lines in the emission spectrum of hydrogen that involve transitions to the n=2 state from states with n>2.

barometer    →   barometar

Barometer is an instrument that measures atmospheric pressure. A mercury barometer is a closed tube filled with mercury inverted in a mercury reservoir. The height of the mercury column indicates atmospheric pressure (with 1 atm = 760 mm of mercury). An aneroid barometer consists of an evacuated container with a flexible wall. When atmospheric pressure changes, the wall flexes and moves a pointer which indicates the changing pressure on a scale.

base-centered monoclinic lattice    →   bazno centrirana monoklinska rešetka

Base-centered or side-centered or end-centered monoclinic lattice (monoclinic-C), like all lattices, has lattice points at the eight corners of the unit cell plus additional points at the centers of two parallel sides of the unit cell. It has unit cell vectors a≠b≠c, and interaxial angles α=γ=90°≠β.

base-centered orthorhombic lattice    →   bazno centrirana ortorompska rešetka

Base-centered or side-centered or end-centered monoclinic lattice (orthorhombic-C), like all lattices, has lattice points at the eight corners of the unit cell plus additional points at the centers of two parallel sides of the unit cell. It has unit cell vectors a≠b≠c and interaxial angles α=β=γ=90°.

Beer’s law    →   Beerov zakon

Beer’s law (or Beer-Lambert law) is the functional relationship between the quantity measured in an absorption method (A) and the quantity sought, the analyte concentration (c). As a consequence of interactions between the photons and absorbing particles, the power of the beam is attenuated from P_o to P. Beer’s law can be written

where A is the absorbance at a given wavelength of light, ε is the molar absorbtivity or extinction coefficient (L mol^-1 cm^-1), unique to each molecule and varying with wavelength, b is the length of light path through the sample (cm), and c is the concentration of the compound in solution (mol L^-1).

benzene    →   benzen

Benzene is a colourless liquid hydrocarbon, C₆H₆, b.p. 80 °C. It is now made from petroleum by catalytic reforming (formerly obtained from coal tar). Benzene is the archetypal aromatic compound. It has an unsaturated molecule, yet will not readily undergo addition reactions. On the other hand, it does undergo substitution reactions in which hydrogen atoms are replaced by other atoms or groups.

In 1865, Friedrich August Kekulé purposed the benzene molecule structure as a hexagonal ring which consists of six carbon atoms with alternate carbon-carbon single and carbon-carbon double bond. But such a structure should be highly reactive, and so didn't account for the unreactive nature of benzene. We now know that the best representation for the structure of benzene is indeed, hexagonal, with each C-C bond distance being identical and intermediate between those for a single and double bond. The π-orbitals from each neighbouring carbon atom overlap to form a delocalised molecular orbital which extends around the ring, giving added stability and with it, decreased reactivity. That is the reason the structural formula of benzene represents as a hexagon with a circle in the center which represents the delocalized electrons.

beryllium    →   berilij

Beryllium was discovered by Friedrich Wöhler (Germany) and independently by A. B. Bussy (France) in 1828. The origin of the name comes from the Greek word beryllos meaning mineral beryl; also called glucinium from the Greek word glykys meaning sweet. It is steel-grey metal. It resists attack by concentrated nitric acid, has excellent thermal conductivity and is nonmagnetic. At ordinary temperatures, it resists oxidation in air. Beryllium and its salts are toxic and should be handled with the greatest of care. Beryllium is found mostly in minerals like beryl [AlBe₃(Si₆O₁₈)] and chrysoberyl (Al₂BeO₄). Pure beryllium is obtained by chemically reducing beryl mineral. Also by electrolysis of beryllium chloride. Its ability to absorb large amounts of heat makes it useful in spacecraft, missiles, aircraft, etc. Emeralds are beryl crystals with chromium traces giving them their green colour.