CHEMISTRY GLOSSARY

electromagnetic radiation spectrum    →   spektar elektromagnetskog zračenja

Wavelengths of electromagnetic waves can be shown with the help of electromagnetic radiation spectrum. Electromagnetic radiation spectrum is divided into several areas from γ-radiation of very short wavelengths and great energy to radio waves with wavelengths up to 1 000 m. The human eye can only see a narrow part of the electromagnetic spectrum - visible radiation.

electron microscope    →   elektronski mikroskop

Electron microscope is a form of microscope that uses a beam of electrons instead of a beam of light (as in the optical microscope) to form a large image of a very small object. In optical microscopes the resolution is limited by the wavelength of the light. High-energy electrons, however, can be associated with a considerably shorter wavelength than light; for example, electrons accelerated to energy of 10⁵ electronvolts have a wavelength of 0.004 nm enabling a resolution of from 0.2 nm to 0.5 nm to be achieved.

freon    →   freon

Freon (chlorofluorocarbon, CFC) a type of compound in which some or all of the hydrogen atoms of hydrocarbon (usually an alkane) have been replaced by chlorine and fluorine atoms. Most CFC are chemically uncreative and are stable at high temperatures. They are used as aerosol propellants, refrigerants, and solvents, and in the manufacture of rigid packaging foam. CFC because of their chemical inertness, can diffuse unchanged into the upper atmosphere. Here, photochemical reactions cause them to break down and react with ozone. For his reason, their use has been discouraged.

transmittance    →   transmitancija

Transmittance (τ) is the ratio of the radiant or luminous flux at a given wavelength that is transmitted to that of the incident radiation. Also called transmission factor.

gamma radiation    →   gama-zračenje

Gamma radiation is electromagnetic radiation of extremely short wavelength. Gamma radiation ranges in energy from about 10^-15 J to 10^-10 J (10 keV to 10 MeV) (wavelength less than about 1 pm). Gamma rays are emitted by excited atomic nuclei during the process of passing to a lower excitation state.

Gamma rays are extremely penetrating and are absorbed by dense materials like lead and uranium. Exposure to gamma radiation may be lethal.

global warming    →   globalno zatopljenje

Global warming or greenhouse effect is an effect occurring in the atmosphere because of the presence of certain gases (greenhouse gases) that absorb infrared radiation. Light and ultraviolet radiation from the sun is able to penetrate the atmosphere and warm the Earth’s surface. This energy is re-radiated as infrared radiation which because of its longer wavelength, is absorbed by such substances as carbon dioxide. The overall effect is that the average temperature of the Earth and its atmosphere is increasing (so-called global Warming). The effect is similar to that occurring in a greenhouse, where light and long-wavelength ultraviolet radiation can pass through the glass into greenhouse but the infrared radiation is absorbed by the glass and part of it is re-radiated into the greenhouse.

The greenhouse effect is seen as a major environmental hazard. Average increases in temperature could change weather patterns and agricultural output. It might also lead to melting of the polar ice caps and a corresponding rise in sea level. Carbon dioxide, from fossil-fuel power stations and car exhausts, is the main greenhouse gas. Other contributory pollutants are nitrogen oxides, ozone, methane, and chloroflourocarbons.

X-ray spectrum    →   spektar X-zraka

X-ray spectrum is a set of characteristic X-ray frequencies or wavelengths produced by a substance used as a target in an X-ray tube. Each element has a characteristic X-ray spectrum, and there is a strong correlation between atomic number and the frequencies of certain lines in the X-ray spectrum.

microscope    →   mikroskop

Microscope is an instrument that produces enlarged images of small objects. The optical microscopes (light microscope) use visible light and a system of lenses to magnify images. Typical magnification of a light microscope is up to 1500× ("1500 times")with a theoretical resolution limit of around 200 nm. Instead of using light, electron microscopes transmit a beam of electrons through, or onto the surface of, a specimen. An electron beam has a much shorter wavelength than does light, and can reveal structures as small as 2 nm.

second    →   sekunda

Second (s) is the SI base unit of time.

The second is the duration of 9 192 631 770 periods of the radiation corresponding to the transition between the two hyperfine levels (F = 4, m_F = 0 to F = 3, m_F = 0) of the ground state of the caesium 133 atom.

solar cell    →   sunčeva ćelija

Solar cell, or photovoltaic cell, is a device that captures sunlight and transforms it directly to electricity. All solar cells make use of photovoltaic effect, so often they are called photovoltaic cells. Almost all solar cells are built from solid-state semiconducting materials, and in the vast majority of these the semiconductor is silicon.

The photovoltaic effect involves the generation of mobile charge carriers-electrons and positively charged holes-by the absorption of a photon of light. This pair of charge carriers is produced when an electron in the highest filled electronic band of a semiconductor (the valence band) absorbs a photon of sufficient energy to promote it into the empty energy band (the conduction band). The excitation process can be induced only by a photon with an energy corresponding to the width of the energy gap that separates the valence and the conduction band. The creation of an electron-hole pair can be converted into the generation of an electrical current in a semiconductor junction device, wherein a layer of semiconducting material lies back to back with a layer of either a different semiconductor or a metal. In most photovoltaic cells, the junction is p-n junction, in which p-doped and n-doped semiconductors are married together. At the interface of the two, the predominance of positively charged carriers (holes) in the p-doped material and of negatively charged carriers (electrons) in the n-doped material sets up an electric field, which falls off to either side of the junction across a space-charge region. When absorption of a photon in this region generates an electron-hole pair, these charge carriers are driven in opposite directions by the electric field, i.e. away from the interface and toward the top and bottom of the two-layer structure, where metal electrodes on these faces collect the current. The electrode on the top layer (through which light is absorbed) is divided into strips so as not to obscure the semiconducting layers below. In most widely used commercial solar cells, the p-doped and n-doped semiconductive layers are formed within a monolithic piece of crystalline silicon. Silicon is able to absorb sunlight at those wavelengths at which it is most intense-from the near-infrared region (wavelengths of around 1200 nm) to the violet (around 350 nm).