CHEMISTRY GLOSSARY

Bragg angle    →   Braggov kut

Bragg angle (Θ) is the angle between an incident X-ray beam and a set of crystal planes for which the secondary radiation displays maximum intensity as a result of constructive interference. British physicist Sir William Henry Bragg and his son Sir William Lawrence Bragg developed a simple relation for scattering angles, now call Bragg’s law.

which relates the angle θ between a crystal plane and the diffracted X-ray beam, the wavelength λ of the x-rays, the crystal plane spacing d, and the diffraction order n (any integer).

The diffraction experiment as presently considered is intended to provide quantitative information on the lattice constant and shape characteristics of the unit cell.

deoxyribonucleic acid    →   dezoksiribonukleinska kiselina

Deoxyribonucleic acid (DNA) is a nucleic acid with 2-deoxy-D-ribose as the sugar in its nucleotides. DNA contains encoded genetic information, specifically templates for the synthesis of all of an organism’s proteins and enzymes.

DNA was first identified in the 1869 by Swiss chemist Friedrich Miescher (1844-1895). In 1953, American biologist James Dewey Watson (1928-) and English physicist Francis Harry Compton Crick (1916–2004) had discovered that DNA occurs in the cell as a double helix, with two long strands of the molecule wound around each other, and further that the chemical structure of the molecule dictates that adenine (A) always aligns or pairs with thymine (T), and cytosine (C) always pairs with guanine (G). It is this base pairing that allows DNA in a cell to copy itself, and transfer its information to a new cell. The diameter of the helix is 2.0 nm and there is a residue on each chain every 0.34 nm in the z direction. The angle between each residue on the same strand is 36°, so that the structure repeats after 10 residues (3.4 nm) on each strand.

X-ray diffraction pattern    →   rendgenski difrakcijski uzorci

X-ray diffraction pattern is an interference pattern created by x-rays as they pass through a solid material. Studying X-ray diffraction patterns gives detailed information on the three-dimensional structure of crystals, surfaces, and atoms.

Einstein, Albert    →   Einstein, Albert

Albert Einstein (1879-1955) is a German born American physicist, who took Swiss nationality in 1901. A year later he went to work in the Bern patent office. In 1905. he published five enormously influential papers, one on Brownian movement, one on the photoelectric effect, one on the special theory of relativity, and one on energy and inertia (which included the famous expression E = mc²). In 1915 he published the general theory of relativity, concerned mainly with gravitation. In 1921 he was awarded the Nobel Prize. In 1933, as a Jew, Einstein decided to remain in the USA (where he was lecturing), as Hitler had come to power. For the remainder of his life he sought a unified field theory. In 1939 he informed president Roosevelt that an atom bomb was feasible and that. Germany might be able to make one.

nucleic acid    →   nukleinska kiselina

Nucleic acids are a complex, high-molecular-weight biochemical macromolecules composed of nucleotide chains that convey genetic information. The most common nucleic acids are deoxyribonucleic acid (DNA) and ribonucleic acid (RNA). Each nucleic acid chain is composed of subunits called nucleotides, each containing a sugar, a phosphate group, and nitrogenous base. DNA was first discovered in 1869 by the Swiss biochemist Friedrich Miescher (1844-1895).

Both DNA and RNA contain the two major purine bases adenine (A) and guanine (G) and one of the major pyrimidines, cytosine (C). Of the other two pyrimidines, thymine (T) is found in DNA and uracil (U) is found in RNA. There are two major pentoses in nucleic acids:2'-deoxy-D-ribose in DNA and D-ribose in RNA.

Nucleotides are linked together in both DNA and RNA in a polymeric fashion via covalent bonds. These bonds exist through phosphate-group bridges in which the 5' hydroxyl group of one nucleotide unit is joined to the 3' hydroxyl group of the next nucleotide. RNA is usually a single-stranded molecule, whereas DNA is usually double-stranded.

ribonucleic acid    →   ribonukleinska kiselina

Ribonucleic acid is a complex organic compound in living cells that is concerned with protein synthesis. Plays an intermediary role in converting the information contained in DNA into proteins. RNA carries the genetic information from DNA to those parts of the cell where proteins are made. Some viruses store their genetic information as RNA not as DNA.

Ribonucleic acid is a similar molecule to DNA but with a slightly different structure.

The structural difference with DNA is that RNA contains a -OH group both at the 2' and 3' position of the ribose ring, whereas DNA (which stands, in fact, for deoxy-RNA) lacks such a hydroxy group at the 2' position of the ribose. The same bases can be attached to the ribose group in RNA as occur in DNA, with the exception that in RNA thymine does not occur, and is replaced by uracil, which has an H-group instead of a methyl group at the C-5 position of the pyrimidine. Unlike the double-stranded DNA molecule, RNA is a single-stranded molecule.

The three main functionally distinct varieties of RNA molecules are: (1) messenger RNA (mRNA) which is involved in the transmission of DNA information, (2) ribosomal RNa (rRNA) which makes up the physical machinery of the synthetic process, and (3) transfer RNA (tRNA) which also constitutes another functional part of the machinery of protein synthesis.

ununquadium    →   ununkvadij

The discovery of ununquadium was reported informally in January 1999 following experiments towards the end of December 1998 involving scientists at Dubna (Joint Institute for Nuclear Research) in Russia and the Lawrence Livermore National Laboratory, USA. The new element has not yet been officially named, but it is known as ununquadium, according to the system designated by the IUPAC for naming new elements. It is synthetic radioactive metal. Only few atoms of element 114 (²⁸⁹114) has ever been made (through a nuclear reaction involving fusing a calcium atom with a plutonium atom) isolation of an observable quantity has never been achieved.