CHEMISTRY GLOSSARY

lead    →   olovo

Lead has been known since ancient times. The origin of the name comes from the Latin word plumbum meaning liquid silver. It is very soft, highly malleable and ductile, blue-white shiny metal. Tarnishes in moist air; stable in oxygen and water. Dissolves in nitric acid. Compounds toxic by inhalation or ingestion. Danger of cumulative effects. Lead is found most often in ores called galena or lead sulfide (PbS). Used in solder, shielding against radiation and in batteries.

mercury    →   živa

Mercury has been known since ancient times. The origin of the name comes from the Latin word hydrargyrum meaning liquid silver. It is heavy, silver-white metal, liquid at ordinary temperatures. Stable in air and water. Unreactive with alkalis and most acids. Gives off poisonous vapour. Chronic cumulative effects. Mercury only rarely occurs free in nature. The chief ore is cinnabar or mercury sulfide (HgS). Used in thermometers, barometers and batteries. Also used in electrical switches and mercury-vapour lighting products.

lead-acid battery    →   olovni akumulator

Lead-acid battery is a electrical storage device that uses a reversible chemical reaction to store energy. It was invented in 1859 by French physicist Gaston Planté. Lead-acid batteries are composed of a lead(IV) oxide cathode, a sponge metallic lead anode and a sulphuric acid solution electrolyte.

In charging, the electrical energy supplied to the battery is changed to chemical energy and stored. The chemical reaction during recharge is normally written:

In discharging, the chemical energy stored in the battery is changed to electrical energy. During discharge, lead sulfate (PbSO4) is formed on both the positive and negative plates. The chemical reaction during discharge is normally written:

Lead acid batteries are low cost, robust, tolerant to abuse, tried and tested. For higher power applications with intermittent loads however, they are generally too big and heavy and they suffer from a shorter cycle life.

microscope    →   mikroskop

Microscope is an instrument that produces enlarged images of small objects. The optical microscopes (light microscope) use visible light and a system of lenses to magnify images. Typical magnification of a light microscope is up to 1500× ("1500 times")with a theoretical resolution limit of around 200 nm. Instead of using light, electron microscopes transmit a beam of electrons through, or onto the surface of, a specimen. An electron beam has a much shorter wavelength than does light, and can reveal structures as small as 2 nm.

molybdenum    →   molibden

Molybdenum was discovered by Carl William Scheele (Sweden) in 1778. The origin of the name comes from the Greek word molybdos meaning lead. It is silvery white, very hard metal, but is softer and more ductile than tungsten. Molybdenum is found in the minerals molybdenite (MoS₂) and wulfenite (MoO₄Pb). Its alloys are used in aircraft, missiles and protective coatings in boiler plate.

nerve poison    →   živčani bojni otrov

Nerve poison (nerve gas, agents) have had an entirely dominant role since the Second World War. Nerve poisons acquired their name because they affect the transmission of nerve impulses in the nervous system. All nerve poisons belong chemically to the group of organo-phosphorus compounds. They are stable and easily dispersed, highly toxic and have rapid effects both when absorbed through the skin and via respiration. Nerve poisons can be manufactured by means of fairly simple chemical techniques. The raw materials are inexpensive and generally readily available.

The most important nerve agents included in modern chemical weapons arsenals are:

Nerve poisons are colorless, odorless, tasteless liquids of low volatility. Antidotes are atropine sulfate and pralidoxime iodide.

Ostwald’s viscometer    →   Ostwaldov viskozimetar

Ostwald viscometer, also known as U-tube viscometer or capillary viscometer is a device used to measure the viscosity of the liquid with a known density. The method of determining viscosity with this instrument consists of measuring the time for a known volume of the liquid (the volume contained between the marks A and B) to flow through the capillary under the influence of gravity. Ostwald viscometers named after the German chemist Wilhelm Ostwald (1853-1932).

The instrument must first be calibrated with materials of known viscosity such as pure (deionized) water. Knowing the value of viscosity of one liquid, one can calculate the viscosity of other liquid.

where η₁ and η₂ are viscosity coefficients of the liquid and water, and ρ₁ and ρ₂ are the densities of liquid and water, respectively.

Newton’s gravitational law    →   Newtonov zakon gravitacije

Every object in the universe attracts every other object with a force (gravitational force F_G) directed along the line through centres of the two objects that is proportional to the product of their masses and inversely proportional to the square of the distance between them.

m₁ and m₂ are masses of the two objects and r is the distance between them. G is universal constant of gravitation, which equals 6.67•10^-26 N m² kg^-2. Strictly speaking, this law applies only to objects that can be considered pointlike object. Otherwise, the force has to be found by integrating the forces between various mass elements.

It is more properly to express Newton’s gravitational law by vector equation:

in which r₁ and r₂ are position vectors of masses m₁ and m₂.

Gravitational forces act on distance. Newton’s gravitational law is derived from Kepler’s law for planetary motion, using a physical assumption considering Sun as the centre and the source of gravitational force.

Additionally, every object moves in the direction of the force acting on it, with acceleration that is inversely proportional to the mass of object. For bodies on the surface of Earth, the distance r in gravitational law formula is practically equal to the Earth radius, R_E. If the mass of the body on Earth surface is m and the mass of earth is M_E, the gravitational force acting on that body can be expressed as:

where g is gravitational acceleration which is, although dependent on geographical latitude, usually considered as constant equal to 9.81 m s^-2.

picnometer    →   piknometar

Picnometer is a special glass flask which is used for determining a relative density of liquids using the weight of a known volume. It usually has a glass faceted cork which is pierced in the centre like a thin capillary through which surplus of liquid runs out.

precision balance    →   tehnička vaga

Precision balances typically display results from three to one decimal places (0.001 g up to 0.1 g). The readability precision balances are reduced when compared to analytical balances but, precision balances accommodate higher capacities (up to several kilograms). In its traditional form, it consists of a pivoted horizontal lever of equal length arms, called the beam, with a weighing pan, also called scale, suspended from each arm.

In electronic top pan, or toploader balances, mass is determined not by mechanical deflection but by electronically controlled compensation of an electric force. The signal generated enables the mass to be read from a digital display. The mass of the empty container can be stored in the balance’s computer memory and automatically deducted from the mass of the container plus its contents.