CHEMISTRY GLOSSARY

nitride    →   nitrid

Nitrides are compounds of nitrogen with metal in which nitrogen has an oxidation number -3, are hard and resistant to high temperatures.

polyvalent element    →   polivalentni elementi

Polyvalent element is a molecule which having more than one valence, for example oxygen is a divalent in H₂O, nitrogen is a trivalent in NH₃, carbon is a tetravalent in methane (CH₄).

reactive metal    →   reaktivni metal

Reactive metals are metals that readily combine with oxygen at elevated temperatures to form very stable oxides, for example titanium, zirconium, and beryllium. Reactive metals may also become embrittled by the interstitial absorption of oxygen, hydrogen, and nitrogen.

smog    →   smog

Smog is a mixture of smoke and fog. The term is used to describe city fogs in which there is a large proportion of particulate matter (tiny pieces of carbon from exhausts) and also a high concentration of sulphur and nitrogen gases.

decomposition    →   raspadanje

Decomposition occurs when chemical compounds are broken up into simple molecules, and even as far as their original elements. These processes are normally irreversible. An example of decomposition is when ammonium nitrate is heated. This produces nitrous oxide and water which are unable to recombine.

deoxyribonucleic acid    →   dezoksiribonukleinska kiselina

Deoxyribonucleic acid (DNA) is a nucleic acid with 2-deoxy-D-ribose as the sugar in its nucleotides. DNA contains encoded genetic information, specifically templates for the synthesis of all of an organism’s proteins and enzymes.

DNA was first identified in the 1869 by Swiss chemist Friedrich Miescher (1844-1895). In 1953, American biologist James Dewey Watson (1928-) and English physicist Francis Harry Compton Crick (1916–2004) had discovered that DNA occurs in the cell as a double helix, with two long strands of the molecule wound around each other, and further that the chemical structure of the molecule dictates that adenine (A) always aligns or pairs with thymine (T), and cytosine (C) always pairs with guanine (G). It is this base pairing that allows DNA in a cell to copy itself, and transfer its information to a new cell. The diameter of the helix is 2.0 nm and there is a residue on each chain every 0.34 nm in the z direction. The angle between each residue on the same strand is 36°, so that the structure repeats after 10 residues (3.4 nm) on each strand.

dipole    →   dipol

Dipole is a pair of separated opposite electric charges. Electric dipole is an assemblage of atoms or subatomic particles having equal electric charges of opposite sign separated by a finite distance. In the case of HCl, the electrons are attracted towards the more electronegative chlorine atom.

dubnium    →   dubnij

Dubnium was discovered by workers at the Nuclear Institute at Dubna (USSR) and by workers at the University of California, Berkeley (USA) in 1967. The origin of the name dubnium is the Joint Nuclear Institute at Dubna, Russia, an institute heavily involved in the search for heavy elements. It is synthetic radioactive metal. Dubnium was made by bombarding californium-249 with a beam of nitrogen-15 ions. There are now five known isotopes of dubnium. The longest-lived is dubnium-262, with a half-life of 34 seconds.

EDTA    →   EDTA

Ethyldiaminetetraacetic acid (C₁₀H₁₆N₂O₈) or shortened EDTA is a hexadentant ligand, and it forms chelates with both transition-metal ions and main-group ions. EDTA is used as a negative ion - EDTA^4-. The diagram shows the structure of the ion with the important atoms picked out. The EDTA ion entirely wraps up a metal ion using all 6 of the positions. The co-ordination number is again 6 because of the 6 co-ordinate bonds being formed by the central metal ion.

EDTA is frequently used in soaps and detergents, because it forms a complexes with calcium and magnesium ions. These ions are in hard water and interfere with the cleaning action of soaps and detergents. EDTA is also used extensively as a stabilizing agent in the food industry and as an anticoagulant for stored blood in blood banks. EDTA is the most common reagent in complexometric titration.

global warming    →   globalno zatopljenje

Global warming or greenhouse effect is an effect occurring in the atmosphere because of the presence of certain gases (greenhouse gases) that absorb infrared radiation. Light and ultraviolet radiation from the sun is able to penetrate the atmosphere and warm the Earth’s surface. This energy is re-radiated as infrared radiation which because of its longer wavelength, is absorbed by such substances as carbon dioxide. The overall effect is that the average temperature of the Earth and its atmosphere is increasing (so-called global Warming). The effect is similar to that occurring in a greenhouse, where light and long-wavelength ultraviolet radiation can pass through the glass into greenhouse but the infrared radiation is absorbed by the glass and part of it is re-radiated into the greenhouse.

The greenhouse effect is seen as a major environmental hazard. Average increases in temperature could change weather patterns and agricultural output. It might also lead to melting of the polar ice caps and a corresponding rise in sea level. Carbon dioxide, from fossil-fuel power stations and car exhausts, is the main greenhouse gas. Other contributory pollutants are nitrogen oxides, ozone, methane, and chloroflourocarbons.