CHEMISTRY GLOSSARY

Arrhenius equation    →   Arheniusova jednadžba

In 1889, Svante Arrhenius explained the variation of rate constants with temperature for several elementary reactions using the relationship

where the rate constant k is the total frequency of collisions between reaction molecules A times the fraction of collisions exp(-E_a/RT) that have an energy that exceeds a threshold activation energy E_a at a temperature of T (in kelvin). R is the universal gas constant.

autocatalysis    →   autokataliza

Autocatalysis is a reaction in which its product can act as a catalyst. Oxalate oxidation with permanganate in an acid solution is a slow reaction

Mn²⁺-ions catalyse this reaction. When enough Mn²⁺-ions are created, the reaction occurs instantly.

base    →   baza

Historically, base is a substance that yields an OH - ion when it dissociates in solution, resulting in a pH>7. In the Brønsted definition, a base is a substance capable of accepting a proton in any type of reaction. The more general definition, due to G.N. Lewis, classifies any chemical species capable of donating an electron pair as a base. Typically, bases are metal oxides, hydroxides, or compounds (such as ammonia) that give hydroxide ions in aqueous solution.

battery    →   baterija

Battery a device that converts chemical energy to electrical energy. The process underlying the operation of a battery involves a chemical reaction in which electrons are transferred from one chemical species to another. This process is carried out in two half-reactions, one that involves the loss of electrons and one that involves their gain. The battery is an electrochemical cell divided in two half-cells, and reaction proceeds when these are connected together by an electrically conducting pathway. The passage of electrons from one half-cell to the other corresponds to an electric current. Each half-cell contains an electrode in contact with the reacting species. The electrode which passes electrons into the circuit when battery discharges is called anode and is negative terminal. The electrode which receives electrons is called cathode, and is the battery’s positive terminal. The electrical circuit is completed by an electrolyte, an electrically conducting substance placed between the two electrodes which carriers a flow of charge between them. In wet cells, the electrolyte is a liquid containing dissolved ions, whose motion generates an electrical current; in dry cells the electrolyte is basely solid, for example, a solid with mobile ions or porous solid saturated with an ionic solution.

benzene    →   benzen

Benzene is a colourless liquid hydrocarbon, C₆H₆, b.p. 80 °C. It is now made from petroleum by catalytic reforming (formerly obtained from coal tar). Benzene is the archetypal aromatic compound. It has an unsaturated molecule, yet will not readily undergo addition reactions. On the other hand, it does undergo substitution reactions in which hydrogen atoms are replaced by other atoms or groups.

In 1865, Friedrich August Kekulé purposed the benzene molecule structure as a hexagonal ring which consists of six carbon atoms with alternate carbon-carbon single and carbon-carbon double bond. But such a structure should be highly reactive, and so didn't account for the unreactive nature of benzene. We now know that the best representation for the structure of benzene is indeed, hexagonal, with each C-C bond distance being identical and intermediate between those for a single and double bond. The π-orbitals from each neighbouring carbon atom overlap to form a delocalised molecular orbital which extends around the ring, giving added stability and with it, decreased reactivity. That is the reason the structural formula of benzene represents as a hexagon with a circle in the center which represents the delocalized electrons.

blast furnace    →   visoka peć

Blast furnace is a furnace for smelting of iron from iron oxide ores (hematite, Fe₂O₃ or magnetite, Fe₃O₄). Coke, limestone and iron ore are poured in the top, which would normally burn only on the surface. The hot air blast to the furnace burns the coke and maintains the very high temperatures that are needed to reduce the ore to iron. The reaction between air and the fuel generates carbon monoxide. This gas reduces the iron(III) oxide in the ore to iron.

Because the furnace temperature is in the region of 1500 °C, the metal is produced in a molten state and this runs down to the base of the furnace.

The production of iron in a blast furnace is a continuous process. The furnace is heated constantly and is re-charged with raw materials from the top while it is being tapped from the bottom. Iron making in the furnace usually continues for about ten years before the furnace linings have to be renewed.

condensational polymerisation    →   kondenzacijska polimerizacija

Condensational polymerisation is a reaction of polymerisation in which monomers together create a polymer by losing small molecules like water.

critical mass    →   kritična masa

Critical mass is the minimum mass of a fissionable material (²³⁵U or ²³⁹Pu) that will initiate an uncontrolled chain reaction as in an atomic bomb. The critical mass of pure ²³⁹Pu is about 4.5 kg, and of ²³⁵U about 15 kg.

dehydrogenation    →   dehidrogenacija

Dehydrogenation is a chemical reaction in which hydrogen is removed from a compound. Dehydrogenation of organic compounds converts single carbon-carbon bonds into double bonds. It is usually affected by means of a metal catalyst or in biological systems by enzyme dehydrogenases.

Born-Haber cycle    →   Born-Haberov kružni proces

Born-Haber cycle is a cycle of reactions used for calculating the lattice energies of ionic crystalline solids. For a compound MX, the lattice energy is the enthalpy of the reaction

The standard enthalpy of formation of the ionic solid is the enthalpy of the reaction

The cycle involves equating this enthalpy (which can be measured) to the sum of the enthalpies of a number of steps proceeding from the elements to the ionic solid. The steps are:

1) Atomization of the metal

2) Atomization of the nonmetal

3) Ionisation of the metal

This is obtained from the ionisation potential.

4) Ionisation of the nonmetal

This is electron affinity.

5) Formation of the ionic solids

Equation of the enthalpies gives

from which ΔH_L can be found.