In 1836 the British chemist John Frederic Daniell (1790-1845) proposed an improved electric cell that supplied an even current during continuous operation. Daniell cell consisted of a glass jar containing copper and zinc electrodes, each immersed in their respective acidic sulphate solutions. The two solutions were separated by a porous clay cylinder separator. It was a galvanic cell in which the spontaneous electrodissolution of zinc and electroplating of copper provided the electrical current.
Zn(s) |
→ | Zn2+ + 2e- |
+0.763 V |
Cu2+ + 2e- |
→ | Cu(s) |
+0.337 V |
Zn(s) + Cu2+ |
→← | Zn2+ + Cu(s) |
+1.100 V |
Dielectric constant or permittivity (ε) is an index of the ability of a substance to attenuate the transmission of an electrostatic force from one charged body to another. The lower the value, the greater the attenuation. The standard measurement apparatus utilises a vacuum whose dielectric constant is 1. In reference to this, various materials interposed between the charged terminal have the following value at 20 °C:
vacuum | 1 |
air | 1.00058 |
glass | 3 |
benzene | 2.3 |
acetic acid | 6.2 |
ammonia | 15.5 |
ethanol | 25 |
glycerol | 56 |
water | 81 |
The exceptionally high value for water accounts for its unique behaviour as a solvent and in electrolytic solutions. Dielectric constant values decrease as the temperature rises.
Dissociation is the process by which a chemical combination breaks up into simpler constituents as a result of either added energy (dissociated by heat), or the effect of a solvent on a dissolved polar compound (electrolytic dissociation). It may occur in the gaseous, solid, or liquid state, or in a solution.
An example of dissociation is the reversible reaction of hydrogen iodide at high temperatures
The term dissociation is also applied to ionisation reactions of acids and bases in water. For example
which is often regarded as a straightforward dissociation into ions
Dysprosium was discovered by Paul Emile Lecoq de Boisbaudran (France) in 1886. The origin of the name comes from the Greek word dysprositos meaning hard to obtain. It is soft, lustrous, silvery metal. Reacts with oxygen. Reacts rapidly with water; dissolves in acids. Metal ignites and burns readily. Reductant. Dysprosium usually found with erbium, holmium and other rare earths in some minerals such as monazite sand. Dysprosium uses are limited to the experimental and esoteric. Some isotopes of dysprosium are effective absorbers of thermal neutrons and are being considered for use in the control rods in nuclear reactors.
Parchment paper is impermeable paper obtained by dipping cellulosic paper in the sulphuric acid.
Plain salt is a salt that contains only metal ions (or ammonium ions) and acid radical. It is created when all ions of hydrogen in an acid are replaced with ions of metal (or ammonium ions).
Generalic, Eni. "Kiselo-bazna titracija." Croatian-English Chemistry Dictionary & Glossary. 29 June 2022. KTF-Split. {Date of access}. <https://glossary.periodni.com>.
Glossary
Periodic Table