Racemisation is a conversion, by heat or by chemical reaction, of an optically active compound into an optically inactive form which half of the optically active substance becomes its miror image (enantiomer).
Hesse’s law says that reaction heat of some chemical change does not depend on the way in which the reaction is conducted, but only on starting and ending system state. Hesse’s law is also known as the law of constant heat summation. Hesse’s law is also known as the law of constant heat summation. The law was first put forward in 1840 by the Swiss-born Russian chemist Germain Henri Hess (1802-1850).
Hesse’s law can be used to obtain thermodynamic data that cannot be measured directly. For example, it is very difficult to control the oxidation of graphite to give pure CO. However, enthalpy for the oxidation of graphite to CO2 can easily be measured. So can the enthalpy of oxidation of CO to CO2. The application of Hess’s law enables us to estimate the enthalpy of formation of CO.
C(s) + O2(g) →← CO2(g) | ΔrH1 = -393 kJ mol-1 |
CO(g) + 1/2O2(g) →← CO2(g) | ΔrH2 = -283 kJ mol-1 |
C(s) + 1/2O2(g) →← CO(g) | ΔrH3 = -110 kJ mol-1 |
The equation shows the standard enthalpy of formation of CO to be -110 kJ/mol.
Thermit welding is a group of welding processes in which fusion is produced by heating with superheated liquid metal resulting from a chemical reaction between a metal oxide and aluminium.
Termochemistry is the study of heat absorbed or released during chemical changes.
Thermosetting plastics (thermosets) refer to a range of polymer materials that cure, through the addition of energy, to a stronger form. The energy may be in the form of heat (rubber), through a chemical reaction (two part epoxy), or irradiation. Thermoset materials are usually liquid or malleable prior to curing, and designed to be molded into their final form, or used as adhesive.
Thermoset polymer resins transformed into plastics or rubbers by cross-linking into a rigid, 3-D structure. A thermoset material cannot be melted and re-molded after it is cured.
Chemical cleaning is a removal of fatty and other impurities combined with it from fabrics with the help of organic solvents.
Chemical corrosion is a damaging process of some materials with a chemical agent.
Chemical element is a type of matter of which elementary matter is composed. Chemical element is composed of atoms with the same core charge.
Chemical engineering is the branch of engineering that is concerned with the design, construction and operation of the plants and machinery used in industrial chemical processes.
Chemical glass is a special, resilient glass used in production of chemical vessels; it is composed of quartz and boron, barium, zinc and aluminium oxides.
Generalic, Eni. "Toplina kemijske reakcije." Croatian-English Chemistry Dictionary & Glossary. 29 June 2022. KTF-Split. {Date of access}. <https://glossary.periodni.com>.
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