CHEMISTRY GLOSSARY

global hectare    →   globalni hektar

Global hectares (gha) are hectares with world-average productivity for all productive land and water areas in a given year. Because different land types have different productivity, a global hectare of, for example, cropland, would occupy a smaller physical area than the much less biologically productive pasture land, as more pasture would be needed to provide the same biocapacity as one hectare of cropland ("ordinary" hectare is an area equal to a square that is 100 meters on each side, so a hectare has 10 000 m²). Global hectare is unit for measuring our demands on the Earth (ecological footprint) and the ability of the Earth to supply our demands (biocapacity).

Knudsen burette    →   Knudsenova bireta

Knudsen's automatic bulb-burette, developed by the Danish physicist Martin Knudsen (1871-1949), is designed in a way that even routine field analysis in a boat laboratory would provide highly accurate measurements. The burette is filled with a mixture of silver nitrate from reservoir R, located above the burette, by opening the A valve. When the solution crosses the three-way C valve the A valve is closed preventing further solution flow in to the burette. Any extra solution is caught in the W bowl. Turn the C valve, which marks the zero on the scale, in order to allow atmospheric air to enter the burette. Since most open-ocean samples lie in a relatively small chlorinity range, the burette is designed so that much of its capacity is in the bulb (B). This allows the titration to be quick (by quickly releasing contents from the B area) and reduces the error that occurs from the slow drainage along the inner wall of the burette.

Each millimeter is divided in to twenty parts (double millimeter division of the Knudsen burette) which allows for highly accurate measurements (the scale is read up to a precision of 0.005 mL). From 0 to 16 the burette isn't divided, that usually starts from 16 and goes until 20.5 or 21.5. A single double millimeter on a Knudsen burette scale corresponds to one permille of chloride in the seawater sample. This burette can be used for titration of water from all of the oceans and seas, with the exemptions being areas with very low salinity (e.g. the Baltic Sea) and river estuaries which require the use of normal burettes.

living planet index    →   indeks života na planetu

The Living Planet Index (LPI) reflects changes in the health of the planet's ecosystems by tracking trends in nearly 8000 populations of vertebrate species. The LPI first calculates the annual rate of change for each species population in the dataset, then calculates the average change across all populations for each year from 1970, when data collection began, to 2007, the latest date for which data is available.

The Global LPI shows a decline of around 30 % from 1970 to 2007, based on 7953 populations of 2544 species of birds, mammals, amphibians, reptiles and fish.

practical salinity    →   praktični salinitet

Practical salinity S_P is defined on the Practical Salinity Scale of 1978 (PSS-78) in terms of the conductivity ratio K₁₅ which is the electrical conductivity of the sample at temperature t₆₈ = 15 °C and pressure equal to one standard atmosphere, divided by the conductivity of a standard potassium chloride (KCl) solution at the same temperature and pressure. The mass fraction of KCl in the standard solution is 0.0324356 (32.4356 g of KCl in 1 kg of solution). When K₁₅ = 1, the Practical Salinity P S is by definition 35. The conductivity of that reference solution is C(35,1568,0) = 42.914 mS/cm = 4.2914 S/m (Siemens per meter). Note that Practical Salinity is a unit-less quantity. Though sometimes convenient, it is technically incorrect to quote Practical Salinity in "psu". When K₁₅ is not unity, S_P and K₁₅ are related by the PSS-78 equation

At a temperature of t₆₈ = 15 °C, R_t is simply K₁₅ and Practical Salinity S_P can be determined from the above equation. For temperatures other than t₆₈ = 15 °C, Practical Salinity S_P is given by the following function of R_t (k = 0.0162)

redox potential    →   redoks potencijal

Redox potential is the potential of a reversible oxidation-reduction electrode measured with respect to a reference electrode, corrected to the hydrogen electrode, in a given electrolyte.

seawater    →   more

Seawater is a complex mixture of 96.5 % water, 3.5 % salts, and smaller amounts of other substances, including dissolved inorganic and organic materials, particulates, and a few atmospheric gases. The world's oceans cover nearly 71 % (361 840 000 km²) of the Earth's surface (510 100 000 km²), with an average depth of 3 682.2 m.

The density of seawater is higher than that of fresh water because of its higher salinity. Seawater's freezing point is lower than that of pure water and its boiling point is higher. The average salinity of the ocean is 35 ‰, which means that for every kilograms of water, there are 35 g of salt. The relative abundance of the major salts in seawater are constant regardless of the ocean. Only six elements and compounds comprise about 99 % of sea salts: chlorine (Cl^-), sodium (Na⁺), sulfur (SO₄^2-), magnesium (Mg²⁺), calcium (Ca²⁺), and potassium (K⁺).

silver/silver-chloride electrode    →   srebro/srebrov klorid elektroda

Silver/silver-chloride electrode is by far the most common reference type used today because it is simple, inexpensive, very stable and non-toxic. It is mainly used with saturated potassium chloride electrolyte, but can be used with lower concentrations such as 3.5 mol dm^-3 or 1 mol dm^-3 potassium chloride. Silver/silver-chloride electrode is a referent electrode based on the following halfreaction

starch    →   škrob

Starch (C₆H₁₀O5)_x is a polysaccharide used by plants to stockpile glucose molecules. It is the major component of flour, potatoes, rice, beans, corn, and peas. Starch is a mixture of two different polysaccharides: amylose (about 20 %), which is insoluble in cold water, and amylopectin (about 80 %), which is soluble in cold water. Amylose is composed of unbranched chains of D-glucose units joined by α(1→4)-glycosidic linkages. Unlike amylose, which are linear polymers, amylopectin contains α(1→6)-glycoside branches approximately every 25 glucose units.

Starch digestion begins in the mouth via the action of amylase, a digestive enzyme present in saliva. The process is completed in the small intestine by the pancreatic amylase. The final products of starch digestion, glucose molecules, are absorbed into the intestinal bloodstream and transported to the liver. Like most enzymes, glycosidases are highly selective in their action. They hydrolyze only the α-glycoside links in starch and leave the β-glycoside links in cellulose untouched. Starch is important food stuff and is used in adhesives, and sizes, in laundering, pharmacy and medicine.

absolute temperature    →   apsolutna temperatura

Absolute temperature denoting a temperature measured on the absolute scale, a scale of temperature based on absolute zero as the lowest temperature.

abundance of elements    →   rasprostranjenost elemenata

Elements in nature are mostly found in different compounds and, rarely, in the free (elementary) state. In Earth’s crust the most abundant of all elements is oxygen (with 49.5 %), then silicon (25 %), aluminium (7.5 %), iron (4.7 %), calcium (3.4 %), sodium (2.6 %), potassium (2.4 %), magnesium (1.9 %) and hydrogen (1.9 %). These nine elements make up almost 99 % of the Earth’s composition.