CHEMISTRY GLOSSARY

rotational inertia    →   moment tromosti

Rotational inertia of a body is defined as

for a system of discrete particles (each of mass m_i), and as

for a body with continuously distributed mass (dm is the mass element). r_i and r represent the perpendicular distance from the axis of rotation to the mass element of the body.

SI unit for rotational inertia is kg m².

ruthenium    →   rutenij

Ruthenium was discovered by Karl Karlovich Klaus (Russia) in 1844. The origin of the name comes from the Latin word Ruthenia meaning Russia. It is rare, extremely brittle, silver-grey metal. Unaffected by air, water or acids. Reacts with very hot (molten) alkalis. Ruthenium is found in pentlandite and pyroxinite. Used to harden platinum and palladium. Aircraft magnetos use platinum alloy with 10 % ruthenium.

scandium    →   skandij

Scandium was discovered by Lars Fredrik Nilson (Sweden) in 1879. The origin of the name comes from the Latin word Scandia meaning Scandinavia. It is fairly soft, silvery-white metal. Burns easily. Tarnishes readily in air. Reaction with water releases hydrogen. Reacts with air and halogens. Scandium occurs mainly in the minerals thortveitile (~34 % scandium) and wiikite. Also in some tin and tungsten ores. Pure scandium is obtained as a by-product of uranium refining. Scandium metal is used in some aerospace applications. Scandium oxide (Sc₂O₂) is used in the manufacture of high-intensity electric lamps. Scandium iodide (ScI₃) is used in lamps that produce light having a colour closely matching natural sunlight.

Schrodinger equation    →   Schrodingerova jednadžba

Schrödinger equation is the basic equation of wave mechanics which, for systems not dependent on time, takes the form:

where Ψ is the wavefunction, V is the potential energy expressed as a function of the spatial coordinates, E its total energy, ² is the Laplacian operator, h is Planck’s constant, and m is the mass.

semiconductor    →   poluvodič

Semiconductor is a material in which the highest occupied energy band (valence band) is completely filled with electrons at T = 0 K, and the energy gap to the next highest band (conduction band) ranges from 0 to 4 or 5 eV. With increasing temperature electrons are excited into the conduction band, leading to an increase in the electrical conductivity.

serine    →   serin

Serine is neutral amino acids with polar side chains. It is one of two hydroxyl amino acids. Both are commonly considered to by hydrophilic due to the hydrogen bonding capacity of the hydroxyl group. Serine often serves as a nucleophile in many enzyme active sites, and is best known for its role in the serine proteases. Serine is a site of phosphorylation and glycosylation which is important for enzyme regulation and cell signaling. It is not essential to the human diet, since it is synthesized in the body from other metabolites, including glycine.

• Abbreviations: Ser, S
• IUPAC name: 2-amino-3-hydroxypropanoic acid
• Molecular formula: C₃H₇NO₃
• Molecular weight: 105.09 g/mol

silicon    →   silicij

Silicon was discovered by Jöns Jacob Berzelius (Sweden) in 1824. The origin of the name comes from the Latin word silicis meaning flint. Amorphous form of silicon is brown powder; crystalline form has grey metallic appearance. Solid form unreactive with oxygen, water and most acids. Dissolves in hot alkali. Silica dust is a moderately toxic acute irritant. Silicon makes up major portion of clay, granite, quartz and sand. Commercial production depends on a reaction between sand (SiO₂) and carbon at a temperature of around 2200 °C. Used in glass as silicon dioxide (SiO₂). Silicon carbide (SiC) is one of the hardest substances known and used in polishing. Also the crystalline form is used in semiconductors.

simple cubic lattice    →   jednostavna kubična rešetka

Simple or primitive cubic lattice (sc or cubic-P) has one lattice point at the each corner of the unit cell. It has unit cell vectors a = b = c and interaxial angels α=β=γ=90°.

The simplest crystal structures are those in which there is only a single atom at each lattice point. In the sc structures the spheres fill 52 % of the volume. The number of atoms in a unit cell is one (8×1/8 = 1). This is only one metal (α-polonium) that have the sc lattice.

spin    →   spin

Spin is the intrinsic angular momentum of an elementary particle, or system of particles such as nucleus, that is also responsible for the magnetic moment; or, a particle or nucleus possessing such a spin. The spins of nuclei have characteristic fixed values. Pairs of neutrons and protons align to cancel out their spins, so that nuclei with an odd number of neutrons and/or protons will have a net non-zero rotational component characterized by a non-zero quantum nuclear spin number.

Stern-Gerlach experiment: a beam of silver atoms is split into two beams when it traverses a nonuniform magnetic field. Atoms with spin quantum number m_s=+1/2 follow one trajectory, and those with m_s=+1/2 follow another.

square pyramidal molecular geometry    →   kvadratna piramidalna geometrija molekule

Square pyramidal is a molecular shape that results when there are five bonds and one lone pair on the central atom in the molecule. Bromine pentafluoride (BrF₅) has the geometry of a square pyramid, with fluorine atoms occupying five vertices, one of which is above the plane of the other four. This molecule is made up of six equally spaced sp³d² (or d²sp³) hybrid orbitals arranged at 90° angles. The shape of the orbitals is octahedral. Because of the high symmetry of the octahedral arrangement, all six positions are equivalent, so it does not matter in which position in the drawing we put the lone pair. The remaining four atoms connected to the central atom give the molecule a square planar shape.