Diagenesis is the process that turns sediments into sedimentary rocks. The lithification (literally turning into stone) of the sediments is usually accomplished by a cementing agent. How the weight of the overlying material increases the grains closer together, reducing pore space and eliminating some of the contained water. This water may carry mineral components in solution, and these constituents precipitate as new minerals in the pore spaces. This causes cementation, which will then start to bind the individual particles together. Further compaction and burial may cause recrystallization of the minerals to make the rock even harder.
Dielectric constant or permittivity (ε) is an index of the ability of a substance to attenuate the transmission of an electrostatic force from one charged body to another. The lower the value, the greater the attenuation. The standard measurement apparatus utilises a vacuum whose dielectric constant is 1. In reference to this, various materials interposed between the charged terminal have the following value at 20 °C:
vacuum | 1 |
air | 1.00058 |
glass | 3 |
benzene | 2.3 |
acetic acid | 6.2 |
ammonia | 15.5 |
ethanol | 25 |
glycerol | 56 |
water | 81 |
The exceptionally high value for water accounts for its unique behaviour as a solvent and in electrolytic solutions. Dielectric constant values decrease as the temperature rises.
Dissociation is the process by which a chemical combination breaks up into simpler constituents as a result of either added energy (dissociated by heat), or the effect of a solvent on a dissolved polar compound (electrolytic dissociation). It may occur in the gaseous, solid, or liquid state, or in a solution.
An example of dissociation is the reversible reaction of hydrogen iodide at high temperatures
The term dissociation is also applied to ionisation reactions of acids and bases in water. For example
which is often regarded as a straightforward dissociation into ions
Dissociation constant is a constant whose numerical value depends on the equilibrium between the undissociated and dissociated forms of a molecule. A higher value indicates greater dissociation.
The term dissociation is also applied to ionisation reactions of acids and bases in water. For example
which is often regarded as a straightforward dissociation into ions
The equilibrium constant of such a dissociation is called the acid dissociation constant or acidity constant, given by
The concentration of water [H2O] can be taken as constant.
Similarly, for a base, the equilibrium
is also a dissociation; with the base dissociation constant or basicity constant, given by
Ka (Kb) is a measure of the strength of the acid (base).
Parchment paper is impermeable paper obtained by dipping cellulosic paper in the sulphuric acid.
Plain salt is a salt that contains only metal ions (or ammonium ions) and acid radical. It is created when all ions of hydrogen in an acid are replaced with ions of metal (or ammonium ions).
Generalic, Eni. "Mineralna kiselina." Croatian-English Chemistry Dictionary & Glossary. 29 June 2022. KTF-Split. {Date of access}. <https://glossary.periodni.com>.
Glossary
Periodic Table