CHEMISTRY GLOSSARY

allotropy    →   alotropija

Allotropy (Gr. allos, other, and tropos, manner) is the phenomenon of an element existing in two or more physical forms in the same physical state. The difference between the forms involves either crystaline structure (white, red and black phosphorus), the number of atoms in the molecule of a gas (diatomic oxygen and triatomic ozone), or the molecular structure of a liquid (liquid helium an helium II).

In some cases, the allotropes are stable over a temperature range, with a definite transition point at which one changes into the other. For instance, tin has two allotropes: white (metallic) tin stable above 13.2 °C and grey (nonmetallic) tin stable below 13.2 °C. This form allotropy is called enantiotropy. Form of allotropy, in which there is no transition temperature at which the two are in equilibrium, is called monotropy.

Allotropy does not apply to the substance existing in different physical states as, for example, when ice melts and changes from solid ice to liquid water.

Allotropy is generally restricted to describing polymorphic behaviour in elements, while polymorphism may refer to any material having multiple crystal structures.

antimony    →   antimon

Antimony has been known since ancient times. The origin of the name comes from the Latin word stibium meaning mineral stibnite. It is hard, brittle, silvery-white semimetal. Stable in dry air. Toxic by ingestion or inhalation. Antimony is found in stibnite (Sb₂S₃) and in valentinite (Sb₂O₃). It is alloyed with other metals to increase their hardness. Also in the manufacture of a few special types of semiconductor devices. Also in plastics and chemicals. A few kinds of over-the-counter cold and flu remedies use antimony compounds.

arsenic    →   arsen

Arsenic was discovered by Albertus Magnus (Germany) in 1250. The origin of the name comes from the Greek word arsenikon meaning yellow orpiment. It is steel-grey, brittle semi-metal. Resists water, acids and alkalis. Tarnishes in air, burns in oxygen. Highly toxic by inhalation or ingestion. Arsenic is found in mispickel (arsenopyrite). Many of its compounds are deadly poison and used as weed killer and rat poison. Used in semiconductors. Some compounds, called arsenides, are used in the manufacture of paints, wallpapers and ceramics.

cadmium coating    →   kadmiranje

Cadmium coating is a galvanic coating of metallic objects with a cadmium layer for corrosion resistance.

ceramics    →   keramika

Ceramics are an inorganic material of a very high melting point. Ceramics are metal silicates, oxides, nitrides, etc.

complex    →   kompleks

Complex or coordination compound is formed when metal ion (central ion) reacts with molecules or ions which have free electron pairs (ligand). Metal ion and ligand are bonded with a polar covalent bond in which both electrons are given by the ligand.

cyanide process    →   cijanidni postupak

Cyanide process is a method for separating a metal from an ore. Crushed ore is treated with cyanide ion to produce a soluble metal cyanide complex. The complex is washed out of the ore and reduced to metallic form using an active metal (usually zinc).

analytical balance    →   analitička vaga

Analytical balances are instruments used for precise determining mass of matter. Analytical balances are sensitive and expensive instruments, and upon their accuracy and precision the accuracy of analysis result depends. The most widely used type of analytical balances are balances with a capacity of 100 g and a sensitivity of 0.1 mg. Not one quantitative chemical analysis is possible without usage of balances, because, regardless of which analytical method is being used, there is always a need for weighing a sample for analysis and the necessary quantity of reagents for solution preparation.

The working part of the balance is enclosed in a glass-fitted case. The baseplate is usually of black glass or black slate. The beam has agate knife-edges at its extremes, supporting stirrups from which balance pans are suspended. Another agate or steel knife-edge is fixed exactly in the middle of the beam on its bottom side. This knife-edge faces downwards and supports the beam. When not in use and during loading or unloading of the pans, the balance should be arrested.

The principle of operation of a modern laboratory balance bears some resemblance to its predecessor - the equal arm balance. The older instrument opposed the torque exerted by an unknown mass on one side of a pivot to that of an adjustable known weight on the other side. When the pointer returned to the center position, the torques must be equal, and the weight was determined by the position of the moving weights.

Modern electronic laboratory balances work on the principle of magnetic force restoration. In this system, the force exerted by the object being weighed is lifted by an electromagnet. A detector measures the current required to oppose the downward motion of the weight in the magnetic field.

barometer    →   barometar

Barometer is an instrument that measures atmospheric pressure. A mercury barometer is a closed tube filled with mercury inverted in a mercury reservoir. The height of the mercury column indicates atmospheric pressure (with 1 atm = 760 mm of mercury). An aneroid barometer consists of an evacuated container with a flexible wall. When atmospheric pressure changes, the wall flexes and moves a pointer which indicates the changing pressure on a scale.

Faraday cage    →   Faradayev kavez

Faraday cage is a container giving protection from electrical fields: an assembly of conducting material, for example, metal mesh or grid, placed around electrical equipment to protect it from external electrical fields. Faraday cages are named after the English scientist Michael Faraday (1791-1867).