CHEMISTRY GLOSSARY

dielectric constant    →   dielektrična konstanta

Dielectric constant or permittivity (ε) is an index of the ability of a substance to attenuate the transmission of an electrostatic force from one charged body to another. The lower the value, the greater the attenuation. The standard measurement apparatus utilises a vacuum whose dielectric constant is 1. In reference to this, various materials interposed between the charged terminal have the following value at 20 °C:

The exceptionally high value for water accounts for its unique behaviour as a solvent and in electrolytic solutions. Dielectric constant values decrease as the temperature rises.

oxalate    →   oksalat

Oxalates are salts of oxalic acid (H₂C₂O₄), an acid found in many plants and vegetables.

parchment paper    →   pergamentni papir

Parchment paper is impermeable paper obtained by dipping cellulosic paper in the sulphuric acid.

pectin    →   pektin

Pectins are complex highmolecular carbohydrates, formed mostly from galacturonic acid. They are present in many kinds of fruit and vegetable and are used in the production of fruit jellies.

polyamide    →   poliamid

Polyamides are copolymers formed by condensation polymerization of monomers of dycarboxyl acid with a monomer of diamine, for example nylon.

dissociation    →   disocijacija

Dissociation is the process by which a chemical combination breaks up into simpler constituents as a result of either added energy (dissociated by heat), or the effect of a solvent on a dissolved polar compound (electrolytic dissociation). It may occur in the gaseous, solid, or liquid state, or in a solution.

An example of dissociation is the reversible reaction of hydrogen iodide at high temperatures

The term dissociation is also applied to ionisation reactions of acids and bases in water. For example

which is often regarded as a straightforward dissociation into ions

dissociation constant    →   konstanta disocijacije

Dissociation constant is a constant whose numerical value depends on the equilibrium between the undissociated and dissociated forms of a molecule. A higher value indicates greater dissociation.

The term dissociation is also applied to ionisation reactions of acids and bases in water. For example

which is often regarded as a straightforward dissociation into ions

The equilibrium constant of such a dissociation is called the acid dissociation constant or acidity constant, given by

The concentration of water [H₂O] can be taken as constant.

Similarly, for a base, the equilibrium

is also a dissociation; with the base dissociation constant or basicity constant, given by

K_a (K_b) is a measure of the strength of the acid (base).

propagation    →   propagacija

Propagation is the step in a polymerization mechanism, where new monomer molecules are added to the growing polymer chain in the free radical process.

reactivity series    →   reaktivni niz

Reactivity series or activity series is a series of elements (usually metals) ranked by their reactivity degree, made for comparison of reactions of elements with other substances, e.g. acids and oxygen.

regeneration    →   regeneracija

Regeneration is the process of restoring an ion exchange medium to a usable state after exhaustion. The cation exchanger is normally regenerated with hydrochloric acid and the anion exchanger with sodium hydroxide.