CHEMISTRY GLOSSARY

Born-Haber cycle    →   Born-Haberov kružni proces

Born-Haber cycle is a cycle of reactions used for calculating the lattice energies of ionic crystalline solids. For a compound MX, the lattice energy is the enthalpy of the reaction

The standard enthalpy of formation of the ionic solid is the enthalpy of the reaction

The cycle involves equating this enthalpy (which can be measured) to the sum of the enthalpies of a number of steps proceeding from the elements to the ionic solid. The steps are:

1) Atomization of the metal

2) Atomization of the nonmetal

3) Ionisation of the metal

This is obtained from the ionisation potential.

4) Ionisation of the nonmetal

This is electron affinity.

5) Formation of the ionic solids

Equation of the enthalpies gives

from which ΔH_L can be found.

Bragg angle    →   Braggov kut

Bragg angle (Θ) is the angle between an incident X-ray beam and a set of crystal planes for which the secondary radiation displays maximum intensity as a result of constructive interference. British physicist Sir William Henry Bragg and his son Sir William Lawrence Bragg developed a simple relation for scattering angles, now call Bragg’s law.

which relates the angle θ between a crystal plane and the diffracted X-ray beam, the wavelength λ of the x-rays, the crystal plane spacing d, and the diffraction order n (any integer).

The diffraction experiment as presently considered is intended to provide quantitative information on the lattice constant and shape characteristics of the unit cell.

ideal crystal    →   idealni kristal

Ideal crystal is a single crystal with a perfectly regular lattice that contains no impurities, imperfections, or other defects.

cadmium    →   kadmij

Cadmium was discovered by Friedrich Strohmeyer (Germany) in 1817. The origin of the name comes from the Latin word cadmia meaning calamine (zinc carbonate, ZnCO₃), or from the Greek word kadmeia with the same meaning. It is soft, malleable, blue-white metal. Tarnishes in air, soluble in acids, insoluble in alkalis. Boiling cadmium gives off a weird, yellow-colored vapour that is poisonous. Cadmium can cause a variety of health problems, including kidney failure and high blood pressure. Cadmium is obtained as a by product of zinc refining. The mayor use of cadmium is in electroplating of steel to protect it from corrosion. Also used to make nickel-cadmium batteries. The ability of cadmium to adsorb neutrons has made it of great importance in the design of nuclear reactors. Its compounds are found in paint pigments and a wide variety of intense colours.

caesium    →   cezij

Caesium was discovered by Robert Bunsen and Gustav Kirchhoff (Germany) in 1860. The origin of the name comes from the Latin word caesius meaning sky blue or heavenly blue. It is very soft, light grey, ductile metal. Reacts readily with oxygen. Reacts explosively with water. Caesium is found in pollucite [(Cs₄Al₄Si₉O₂₆)·H₂O] and as trace in lepidolite. Used as a ’getter’ to remove air traces in vacuum and cathode-ray tubes. Also used in producing photoelectric devices and atomic clocks. Since it ionises readily, it is used as an ion rocket motor propellant.

calcium    →   kalcij

Calcium was discovered by Sir Humphry Davy (England) in 1808. The origin of the name comes from the Latin word calix meaning lime. It is fairly hard, silvery-white metal. Exposed surfaces form oxides and nitrides. Reacts with water and oxygen. Occurs only in compounds. Calcium is obtained from minerals like chalk, limestone and marble. Pure metal is produced by replacing the calcium in lime (CaCO₃) with aluminium in hot, low pressure retorts. Used by many forms of life to make shells and bones. Virtually no use for the pure metal, however two of its compounds are, lime (CaO) and gypsum (CaSO₄), are in great demand by a number of industries.

carbon    →   ugljik

Carbon has been known since ancient times. The origin of the name comes from the Latin word carbo meaning charcoal. Graphite form of carbon is a black, odourless, slippery solid. Graphite sublimes at 3825 °C. Diamond form is a clear or colored; an extremely hard solid. C60 is Buckminsterfullerine. Carbon black burns readily with oxidants. Carbon is made by burning organic compounds with insufficient oxygen. There are close to ten million known carbon compounds, many thousands of which are vital to organic and life processes. Radiocarbon dating uses the carbon-14 isotope to date old objects.

ligroine    →   ligroin

Ligroine is a petroleum derivative with the boiling point from 6 °C-90 °C similar to petroleum ether. It is nonpolar. It is used as a solvent for fats, resins and latex.

carbohydrate    →   ugljikohidrat

Carbohydrates (often called carbs for short) are polyhydroxy aldehydes or ketones, or substances that yield such compounds on hydrolysis. They are also known as saccharides, a term derived from the Latin word saccharum for sugar. Carbohydrates are the most abundant class of compounds in the biological world, making up more than 50 % of the dry weight of the Earth’s biomass. Every type of food we eat can have its energy traced back to a plant. Plants use carbon dioxide and water to make glucose, a simple sugar, in photosynthesis. Other carbohydrates such as cellulose and starch are made from the glucose. Light from the sun is absorbed by chlorophyll and this is converted to the energy necessary to biosynthesize carbohydrates

The term carbohydrate was applied originally to monosaccharides, in recognition of the fact that their empirical composition can be expressed as C_x(H₂O)_y. Later structural studies revealed that these compounds were not hydrates but the term carbohydrate persists.

Carbohydrates are generally classed as either simple or complex. Simple sugars, or monosaccharides, are carbohydrates that can’t be converted into smaller subunits by hydrolysis. Complex carbohydrates are made of two (disaccharides) or more (oligosaccharides, polysaccharides) simple sugars linked together by acetal (glycosidic) bonds and can be split into the former by hydrolysis.

copper    →   bakar

Copper has been known since ancient times. The origin of the name comes from the Latin word cuprum meaning the island of Cyprus famed for its copper mines. It is malleable, ductile, reddish-brown metal. Resistant to air and water. Exposed surfaces form greenish carbonate film. Pure copper occurs rarely in nature. Usually found in sulfides as in chalcopyrite (CuFeS₂), coveline (CuS), chalcosine (Cu₂S) or oxides like cuprite (Cu₂O). Most often used as an electrical conductor. Also used in the manufacture of water pipes. Its alloys are used in jewellery and for coins.