CHEMISTRY GLOSSARY

metre    →   metar

Metre (m) is the SI base unit of length.

The meter is the length of the path travelled by light in vacuum during a time interval of 1/299 792 458 s.

This definition, adopted by the General Conference on Weights and Measure in October 1983, replaced the 1967 definition based on the krypton lamp.

glycoside    →   glikozid

Glycoside is one of a group of organic compounds in which a sugar group is bonded through its anomeric carbon to another group via a glycosidic bond. The sugar group is known as the glycon and the non-sugar group as the aglycon. According to the IUPAC definition, all disaccharides and polysaccharides are glycosides where the aglycone is another sugar.

In the free hemiacetal form, sugars will spontaneously equilibrate between the α and β anomers. However, once the glycosidic bond is formed, the anomeric configuration of the ring is locked as either α or β. Therefore, the alpha and beta glycosides are chemically distinct. They will have different chemical, physical, and biological properties. Many glycosides occur abundantly in plants, especially as flower and fruit pigments.

The term glycoside was later extended to cover not only compounds in which the anomeric hydroxy group is replaced by a group -OR, but also those in which the replacing group is -SR (thioglycosides), -SeR (selenoglycosides), -NR1R2 (N-glycosides), or even -CR1R2R3 (C-glycosides). Thioglycoside and selenoglycoside are legitimate generic terms; however the use of N-glycoside, although widespread in biochemical literature, is improper and not recommended here (glycosylamine is a perfectly acceptable term). C-Glycoside is even less acceptable. All other glycosides are hydrolysable; the C-C bond of C-glycosides is usually not. The use and propagation of names based on C-glycoside terminology is therefore strongly discouraged.

mole    →   mol

Mole (mol) is the SI base unit of amount of substance.

The mole is the amount of substance of a system which contains as many elementary entities as there are atoms in 0.012 kg of carbon 12.

When the mole is used, the elementary entities must be specified and may be atoms, molecules, ions, electrons, other particles, or specified groups of such particles. In this definition, it is understood that the carbon 12 atoms are unbound, at rest and in their ground state.

pH    →   pH

pH is a convenient measure of the acid-base character of a solution, usually defined by

where c(H⁺) is the concentration of hydrogen ions in moles per litre. The more precise definition is in terms of activity rather than concentration.

A solution of pH 0 to 7 is acid, pH of 7 is neutral, pH over 7 to 14 is alkaline.

practical salinity    →   praktični salinitet

Practical salinity S_P is defined on the Practical Salinity Scale of 1978 (PSS-78) in terms of the conductivity ratio K₁₅ which is the electrical conductivity of the sample at temperature t₆₈ = 15 °C and pressure equal to one standard atmosphere, divided by the conductivity of a standard potassium chloride (KCl) solution at the same temperature and pressure. The mass fraction of KCl in the standard solution is 0.0324356 (32.4356 g of KCl in 1 kg of solution). When K₁₅ = 1, the Practical Salinity P S is by definition 35. The conductivity of that reference solution is C(35,1568,0) = 42.914 mS/cm = 4.2914 S/m (Siemens per meter). Note that Practical Salinity is a unit-less quantity. Though sometimes convenient, it is technically incorrect to quote Practical Salinity in "psu". When K₁₅ is not unity, S_P and K₁₅ are related by the PSS-78 equation

At a temperature of t₆₈ = 15 °C, R_t is simply K₁₅ and Practical Salinity S_P can be determined from the above equation. For temperatures other than t₆₈ = 15 °C, Practical Salinity S_P is given by the following function of R_t (k = 0.0162)

resistance    →   električni otpor

Electrical resistance (R) of a given object is the opposition to the passage of an electric current through that object. The SI unit of electrical resistance is the ohm, represented by the Greek letter omega (Ω). Resistance is the electric potential difference divided by the current when there is no electromotive force in the conductor. This definition applies to direct current. For a conductor of uniform cross section with area A and length L, and whose resistivity is ρ, the resistance is given by

wavenumber    →   valni broj

Wavenumber is the number of wave cycles per unit distance.

There are unfortunately two different definitions of the wavenumber.

Wavenumber, k, is most frequently defined as

with wavelength λ, phase velocity of wave v_p, and angular frequency ω.

Less frequently it is defined simply as

One must be careful to note which definition is in use. Wavenumbers are used extensively in infrared spectroscopy, and usually have units of cm^-1.