CHEMISTRY GLOSSARY

cation exchange    →   kationski izmjenjivač

Cation exchange is a cationic resin has positive ions built into its structure and therefore exchanges negative ions. In the cation exchange, the side groups are ionised acidic groups, such as (-SO₃H, -COOH, -OH) to which cations H⁺ are attached. The exchange reaction is one in which different cations in the solution displace the H⁺ from the solid.

amount concentration    →   količinska koncentracija

Amount concentration (also called molar concentration and in older literature molarity) is the amount of a given substance in a stated unit of a mixture, solution, or ore. The common unit is mole per cubic decimetre (moldm⁻³) or mole per litre (molL^-1) sometimes denoted by M.

The concentration of an atom, ion, or molecule in a solution may be symbolised by the use of square brackets, as [Ca²⁺].

aromatic compounds    →   aromatski ugljikovodici

Aromatic compounds are a major group of unsaturated cyclic hydrocarbons containing one or more rings, typified by benzene, which has a 6-carbon ring containing three double bonds. All the bonds in benzene (C₆H₆) are the same length intermediate between double and single C-C bonds. The properties arise because the electrons in the p-orbitals are delocalised over the ring, giving extra stabilization energy of 150 kJ/mol over the energy of Kekulé structure. Aromatic compounds are unsaturated compounds, yet they do not easily partake in addition reactions.

Historical use of the term implies a ring containing only carbon (e.g., benzene, naphthalene), but it is often generalized to include heterocyclic structures such as pyridine and thiophene.

atmosphere    →   atmosfera

1. Atmosphere is the column of air which is extending several hundred kilometers above the surface the Earth's surface. The density of this air decreases as you proceed up from the surface. The air in the atmosphere consists of 78 % nitrogen, 21 % oxygen, and 0.9 % argon. The remaining 0.1 % of the atmosphere consists of ozone, water vapor, carbon dioxide, methane, helium, and neon. The atmosphere is divided into different regions. The lowest two layers are the troposphere (the layer closest to the earth) and the stratosphere respectively. These two layers contain more than 99 % of the atmospheric molecules.

2. Standard atmosphere (atm) is an obsolete pressure and stress unit which should be discontinued. It is unit of pressure equal to the air pressure measured at mean sea level.

1 atm = 101 325 Pa

Technical atmosphere (at) is an obsolete MKpS pressure and sttress derived unit.

1 at = 98 066.5 Pa

1 atm = 1.033 227 453 at

chemical balance    →   kemijska ravnoteža

Chemical balance is a degree of reversible reaction in a closed system, when the forward and backward reaction happen at same rates and their effects annul each other, while the concentration of reactants and products stays the same.

combustion    →   gorenje

Combustion is a phenomenon when a substance is combined with oxygen in the presence of a flame accompanied by the production of heat and light. Combustion requires a supply of both fuel and oxygen (air) and can take place in the open atmosphere such as an open fire, or in a closed system, such as a car engine.

barometer    →   barometar

Barometer is an instrument that measures atmospheric pressure. A mercury barometer is a closed tube filled with mercury inverted in a mercury reservoir. The height of the mercury column indicates atmospheric pressure (with 1 atm = 760 mm of mercury). An aneroid barometer consists of an evacuated container with a flexible wall. When atmospheric pressure changes, the wall flexes and moves a pointer which indicates the changing pressure on a scale.

benzene    →   benzen

Benzene is a colourless liquid hydrocarbon, C₆H₆, b.p. 80 °C. It is now made from petroleum by catalytic reforming (formerly obtained from coal tar). Benzene is the archetypal aromatic compound. It has an unsaturated molecule, yet will not readily undergo addition reactions. On the other hand, it does undergo substitution reactions in which hydrogen atoms are replaced by other atoms or groups.

In 1865, Friedrich August Kekulé purposed the benzene molecule structure as a hexagonal ring which consists of six carbon atoms with alternate carbon-carbon single and carbon-carbon double bond. But such a structure should be highly reactive, and so didn't account for the unreactive nature of benzene. We now know that the best representation for the structure of benzene is indeed, hexagonal, with each C-C bond distance being identical and intermediate between those for a single and double bond. The π-orbitals from each neighbouring carbon atom overlap to form a delocalised molecular orbital which extends around the ring, giving added stability and with it, decreased reactivity. That is the reason the structural formula of benzene represents as a hexagon with a circle in the center which represents the delocalized electrons.

computational chemistry    →   kompjutacijska kemija

Computational chemistry is a branch of chemistry concerned with the prediction or simulation of chemical properties, structures, or processes using numerical techniques.

congener    →   srodnost

Congener is a term in chemistry that refers to one of many variants or configurations of a common chemical structure. Elements belonging to the same group on the periodic table. For example, sodium and potassium are congeners.