CHEMISTRY GLOSSARY

analytical balance    →   analitička vaga

Analytical balances are instruments used for precise determining mass of matter. Analytical balances are sensitive and expensive instruments, and upon their accuracy and precision the accuracy of analysis result depends. The most widely used type of analytical balances are balances with a capacity of 100 g and a sensitivity of 0.1 mg. Not one quantitative chemical analysis is possible without usage of balances, because, regardless of which analytical method is being used, there is always a need for weighing a sample for analysis and the necessary quantity of reagents for solution preparation.

The working part of the balance is enclosed in a glass-fitted case. The baseplate is usually of black glass or black slate. The beam has agate knife-edges at its extremes, supporting stirrups from which balance pans are suspended. Another agate or steel knife-edge is fixed exactly in the middle of the beam on its bottom side. This knife-edge faces downwards and supports the beam. When not in use and during loading or unloading of the pans, the balance should be arrested.

The principle of operation of a modern laboratory balance bears some resemblance to its predecessor - the equal arm balance. The older instrument opposed the torque exerted by an unknown mass on one side of a pivot to that of an adjustable known weight on the other side. When the pointer returned to the center position, the torques must be equal, and the weight was determined by the position of the moving weights.

Modern electronic laboratory balances work on the principle of magnetic force restoration. In this system, the force exerted by the object being weighed is lifted by an electromagnet. A detector measures the current required to oppose the downward motion of the weight in the magnetic field.

angular momentum    →   moment količine gibanja

Angular momentum is a physical quantity defined for rotating motion (in analogy to momentum that is defined for linear motion). If a body rotates around a specified axis, its angular momentum equals

Where I is the rotational inertia concerning that axis and ω is the angular velocity of the body.

Angular momentum can also be defined for a point-like body concerning a specified origin (in that case, it is not necessary that the point-like body undergoes circular motion). Rotational inertia of the point-like body, concerning that origin equals:

Where m is the mass of the body and r is its distance from the origin.

colligative properties    →   koligativna svojstva

Colligative properties are properties which affect a solvent based on the number of molecules of solute present such as melting point, boiling point and osmotic pressure.

conductometry    →   konduktometrija

Conductometry is a volumetric analytic method in which the end of titration (equivalent point) is defined by an electric conductivity appliance.

angular velocity    →   kutna brzina

A point-like object that undergoes circular motion changes its angular position from initial Θ_i to final Θ_f, relative to a fixed axis, specified in a coordinate system with an origin that coincides the centre of the circular path of object. The change in its angular position is called angular displacement ΔΘ = Θ_f - Θ_i. Also, a rigid body that rotates about a specified rotation axis, changing its angular position from initial Θ_i to final Θ_f, undergoes an angular displacement ΔΘ.

The average angular velocity, ω_av, is the ratio of the angular displacement and the time interval Δt=t_f-t_i, in which that displacement occurs.

Θ_f and Θ_i are the initial and final angular position, respectively.

The instantaneous angular velocity ω is the limit of the average angular velocity, as Δt is made to approach zero.

ω_av and ω are positive for the counterclockwise rotation (in direction of increasing Θ) and negative for the clockwise rotation (in direction of decreasing Θ).

SI unit for angular velocity is s^-1.The measure for the angle Θ is radian. The relationship between radians and degrees is:

For example, the angular velocity of the minute hand of a clock is:

cryoscopic constant    →   krioskopska konstanta

Cryoscopic constant (E_f) is the constant that expresses the amount by which the freezing point T_f of a solvent is lowered by a non-dissociating solute, through the relation

where m is the molality of the solute.

crystal    →   kristal

Crystal is a solid with a regular geometric shape, having a characteristic internal structure and enclosed by symmetrically arranged plane surfaces, intersecting at definite and characteristic angles. In crystals the particles (atoms, ions, or molecules) have a regular three-dimensional repeating arrangement in space. This is called the crystal structure. The crystal lattice is the arrangement of points in space at which the particles are positioned.

barometer    →   barometar

Barometer is an instrument that measures atmospheric pressure. A mercury barometer is a closed tube filled with mercury inverted in a mercury reservoir. The height of the mercury column indicates atmospheric pressure (with 1 atm = 760 mm of mercury). An aneroid barometer consists of an evacuated container with a flexible wall. When atmospheric pressure changes, the wall flexes and moves a pointer which indicates the changing pressure on a scale.

base-centered monoclinic lattice    →   bazno centrirana monoklinska rešetka

Base-centered or side-centered or end-centered monoclinic lattice (monoclinic-C), like all lattices, has lattice points at the eight corners of the unit cell plus additional points at the centers of two parallel sides of the unit cell. It has unit cell vectors a≠b≠c, and interaxial angles α=γ=90°≠β.

base-centered orthorhombic lattice    →   bazno centrirana ortorompska rešetka

Base-centered or side-centered or end-centered monoclinic lattice (orthorhombic-C), like all lattices, has lattice points at the eight corners of the unit cell plus additional points at the centers of two parallel sides of the unit cell. It has unit cell vectors a≠b≠c and interaxial angles α=β=γ=90°.