CHEMISTRY GLOSSARY

Bragg angle    →   Braggov kut

Bragg angle (Θ) is the angle between an incident X-ray beam and a set of crystal planes for which the secondary radiation displays maximum intensity as a result of constructive interference. British physicist Sir William Henry Bragg and his son Sir William Lawrence Bragg developed a simple relation for scattering angles, now call Bragg’s law.

which relates the angle θ between a crystal plane and the diffracted X-ray beam, the wavelength λ of the x-rays, the crystal plane spacing d, and the diffraction order n (any integer).

The diffraction experiment as presently considered is intended to provide quantitative information on the lattice constant and shape characteristics of the unit cell.

bronze    →   bronca

Bronze is an alloy made primarily of copper and tin. It may contain as much as 25 % tin. Bronzes with 10 % or more tin are harder, stronger, and resistant to corrosion. As bronze weathers, a brown or green film forms on the surface. This film inhibits corrosion. Silicon or aluminium is often added to bronze to improve resistance to corrosion. Phosphorus, lead, zinc, and other metals may be added for special purposes. The alloy is hard and easily cast and is extensively used in bearings, valves and other machine parts.

Bronze was one of the first alloys developed by ancient metal workers. The Bronze Age occurred in Europe around 2200 to 700 BC. Bronze was used for weapons such as spearheads, swords, and knives. Since ancient times, bronze has been the most popular metal for casting statues and other art objects.

The term bronze has been adopted commercially for many copper-rich alloys that contain little or no tin but are similar in colour to bronze, including aluminium bronze, manganese bronze, and silicon bronze. Aluminium bronze is used to make tools and, because it will not spark when struck. Manganese bronze is actually a brass that contains manganese. It is often used to make ship propellers because it is strong and resists corrosion by sea water.

cathode ray    →   katodna zraka

Cathode ray is a negatively charged beam that emanates from the cathode of a discharge tube. Cathode rays are streams of electrons.

chiral molecule    →   kiralne molekule

Chiral molecule is a molecule which cannot be superimposed on its mirror image. A common example is an organic molecule containing a carbon atom to which four different atoms or groups are attached. Such molecules exhibit optical activity, i.e., they rotate the plane of a polarised light beam.

darmstadtium    →   darmstadtij

Darmstadtium was discovered by S. Hofmann et al. collaboration at the Heavy Ion Research Laboratory (Gesellschaft für Schwerionenforschung, GSI) in Darmstadt, Germany in November 1994. The title honours the Laboratory for Heavy Ion Research (called GSI) in Darmstadt, Germany, where the substance was first made. It is synthetic radioactive metal. The fusion-evaporation reaction using a ⁶²Ni beam on an isotopically enriched ²⁰⁸Pb target produced four chains of alpha-emitting nuclides following the presumed formation of ²⁶⁹110 + ¹n.

dialysis    →   dijaliza

Dialysis is a method by which large molecules (such as starch or protein) and small molecules (such as glucose or amino acids) may be separated in a solution by selective diffusion through a semipermeable membrane. Through this kind of membrane dissolved particles pass and colloid dimension particles fall behind. For example, if a mixed solution of starch and glucose is placed in a closed container made of a semipermeable substance (such as cellophane), which is then immersed in a beaker of water, the smaller glucose molecules will pass trough the membrane into the water, while the starch molecules remain behind.

dioxin    →   dioksin

Dioxin is a general term that describes a group of hundreds of chemicals that are highly persistent in the environment. The most toxic compound is 2,3,7,8-tetrachlorodibenzo-p-dioxin or TCDD. The toxicity of other dioxins and chemicals like PCBs that act like dioxin are measured in relation to TCDD. Dioxin is formed as an unintentional by-product of many industrial processes involving chlorine such as waste incineration, chemical and pesticide manufacturing and pulp and paper bleaching. Dioxin was the primary toxic component of Agent Orange, found at Love Canal in Niagara Falls, NY and was the basis for evacuations at Times Beach, MO and Seveso, Italy.

Dioxin is formed by burning chlorine-based chemical compounds with hydrocarbons. The major source of dioxin in the environment comes from waste-burning incinerators of various sorts and also from backyard burn-barrels. Dioxin pollution is also affiliated with paper mills which use chlorine bleaching in their process, with the production of Polyvinyl Chloride (PVC) plastics, and with the production of certain chlorinated chemicals (like many pesticides).

dubnium    →   dubnij

Dubnium was discovered by workers at the Nuclear Institute at Dubna (USSR) and by workers at the University of California, Berkeley (USA) in 1967. The origin of the name dubnium is the Joint Nuclear Institute at Dubna, Russia, an institute heavily involved in the search for heavy elements. It is synthetic radioactive metal. Dubnium was made by bombarding californium-249 with a beam of nitrogen-15 ions. There are now five known isotopes of dubnium. The longest-lived is dubnium-262, with a half-life of 34 seconds.

electron microscope    →   elektronski mikroskop

Electron microscope is a form of microscope that uses a beam of electrons instead of a beam of light (as in the optical microscope) to form a large image of a very small object. In optical microscopes the resolution is limited by the wavelength of the light. High-energy electrons, however, can be associated with a considerably shorter wavelength than light; for example, electrons accelerated to energy of 10⁵ electronvolts have a wavelength of 0.004 nm enabling a resolution of from 0.2 nm to 0.5 nm to be achieved.

equal-arm balance    →   vaga s jednakim krakovima

The simplest type of balance, the equal-arm balance, is an application of a first class lever. The beam of the balance is supported on a central knife-edge, usually of agate, which rests upon a plane agate plate. The point of support is called the fulcrum. Two pans of equal weight are suspended from the beam, one at each end, at points equidistant from the fulcrum. A long pointer attached at right angles to the beam at the fulcrum indicates zero on a scale when the beam is at rest parallel to a level surface.

To prevent the knife-edge from becoming dull under the weight of the beam and pans the balance is equipped with a special device called an arrest. The arrest is operated by means of milled knob underneath the base plate in the middle and in front of the balance (sometimes the arrest knob is at one side of the balance).

The object to be weighed is placed on one pan, and standard weights are added to the other until the balance of the beam is established again. When not in use and during loading or unloading of the pans, the balance should be arrested.