CHEMISTRY GLOSSARY

catalytic hydrogenation    →   katalitičko hidrogeniranje

Catalytic hydrogenation is the infusing of unsaturated or impure hydrocarbons with hydrogen gas at controlled temperatures and pressures and in the presence of a catalyst for the purpose of obtaining saturated hydrocarbons and/or removing various impurities such as sulphur and nitrogen.

cycloalkanes    →   cikloalkani

Cycloalkanes are cyclic saturated hydrocarbons containing a ring of carbon atoms joined by single bonds. They have the general formula C_nH_2n, for example cyclohexane, C₆H₁₂. In general, they behave like the alkanes but are rather less reactive.

dienes    →   dieni

Dienes are unsaturated organic compounds that contain two fixed double bonds between carbon atoms. Dienes in which the two double-bond units are linked by one single bond are termed conjugated.

benzene    →   benzen

Benzene is a colourless liquid hydrocarbon, C₆H₆, b.p. 80 °C. It is now made from petroleum by catalytic reforming (formerly obtained from coal tar). Benzene is the archetypal aromatic compound. It has an unsaturated molecule, yet will not readily undergo addition reactions. On the other hand, it does undergo substitution reactions in which hydrogen atoms are replaced by other atoms or groups.

In 1865, Friedrich August Kekulé purposed the benzene molecule structure as a hexagonal ring which consists of six carbon atoms with alternate carbon-carbon single and carbon-carbon double bond. But such a structure should be highly reactive, and so didn't account for the unreactive nature of benzene. We now know that the best representation for the structure of benzene is indeed, hexagonal, with each C-C bond distance being identical and intermediate between those for a single and double bond. The π-orbitals from each neighbouring carbon atom overlap to form a delocalised molecular orbital which extends around the ring, giving added stability and with it, decreased reactivity. That is the reason the structural formula of benzene represents as a hexagon with a circle in the center which represents the delocalized electrons.

carboxylic acids    →   karboksilne kiseline

Carboxylic acids are organic compounds characterized by the presence of one or more RC(=O)OH groups (the carboxyl group). In the systematic chemical nomenclature carboxylic acids names end in the suffix -oic (e.g. ethanoic acids, CH₃COOH). The carbon of the terminal group being counted as part of the chain. They are generally weak acids. Carboxylic acids include a large and important class of fatty acids and may be either saturated or unsaturated. There are also some natural aromatic carboxylic acids (benzoic, salicylic).

kerosine    →   kerozin

Kerosine is a flammable hydrocarbon oil used as fuel in lamps and heaters

reforming    →   reforming

Reforming is a thermal or catalytic refining process in which the hydrocarbon molecules of petroleum are rearranged to improve its octane number; the resulting product is used in blending high-octane petrol.

Schiff base    →   Schiffova baza

Schiff base is a class of compounds derived by the chemical reaction (condensation) of aldehydes or ketones with aromatic amines, for example

They were named after the German chemist Hugo Schiff (1834-1915).

catalytic cracking    →   katalitčko krekiranje

Catalytic cracking is a petroleum refining process in which heavy-molecular weight hydrocarbons are broken up into light hydrocarbon molecules by the application of heat and pressure in the presence of a catalyst.

cracking    →   krekiranje

Cracking is the process whereby heavy molecules of petroleum or crude oil are broken down into hydrocarbons of lower molecular weight (especially in the oil-refining process).