CHEMISTRY GLOSSARY

explosion    →   eksplozija

Explosion is a rapid violent chemical reaction that produces large amounts of gas and heat, accompanied by light, sound and a high-pressure shock wave.

extensive property    →   ekstenzivno svojstvo

Extensive property is a property that changes when the amount of matter in a sample changes. Examples are mass, volume, length, and charge.

free energy    →   slobodna energija

Free energy is an energy that is actually available to do useful work. A decrease in free energy accompanies any spontaneous process. Free energy does not change for systems that are at equilibrium.

diatomaceous earth    →   dijatomejska zemlja

Diatomaceous earth is a naturally occurring siliceous sedimentary mineral compound from microscopic skeletal remains (frustules) of diatoms, unicellular aquatic plants of microscopic size. Their fossilized remains are called diatomite and contains approximately 3000 diatom frustules per cubic millimetre.

Diatomite is relatively inert and has a high absorptive capacity, large surface area, and low bulk density. It consists of approximately 90 % silica, and the remainder consists of compounds such as aluminum and iron oxides. The fine pores in the diatom frustules make diatomite an excellent filtering material for waters, beverages, oils, chemicals, as well as many other products.

dropping mercury electrode    →   kapajuća živina elektroda

Dropping mercury electrode (DME) is a working electrode arrangement for polarography in which mercury continuously drops from a reservoir through a capillary tube (internal diameter 0.03 - 0.05 mm) into the solution. The optimum interval between drops for most analyses is between 2 and 5 s. The unique advantage to the use of the DME is that the constant renewal of the electrode surface, exposed to the test solution, eliminates the effects of electrode poisoning.

Earth’s crust    →   Zemljina kora

Crust is outer layer of the solid earth, above the Mohorovicic discontinuity. Its thickness averages about 35 km on the continents and about 7 km below the ocean floor, and has the approximate chemical composition:

ecological footprint    →   ekološki otisak

The Ecological Footprint is defined as the area of productive land and water ecosystems required to produce the resources that the population consumes (food, fiber, timber, energy, and space for infrastructure) and assimilate the wastes that the population produces (CO₂ is the only waste product currently included), wherever on Earth the land and water is located. It compares actual throughput of renewable resources relative to what is annually renewed. Non-renewable resources are not assessed, as by definition their use is not sustainable.

Ecological footprints and biocapacity are expressed in global hectares (gha). Each unit corresponds to one hectare of biologically productive space with world average productivity. In U.S. Footprint results are often presented in global acres (ga). One U.S. acre is equal to 0.405 hectares.

Humanity is currently consuming renewable resources at a faster rate than ecosystems can regenerate them and continuing to release more CO₂ than ecosystems can absorb. In 2007, humanity's Footprint was 18 billion gha, or 2.7 gha per person. However, the Earth's biocapacity was only 11.9 billion gha, or 1.8 gha per person. This represents an ecological overshoot of 50 per cent. Put another way, people used the equivalent of 1.5 planets to support their activities (more developed countries generally make higher demands on the Earth's ecosystems than poorer, less developed countries).

Helmholz free energy    →   Helmholzova slobodna energija

Helmholz free energy (A) is a thermodynamic function defined by A = U - TS, where U is the internal energy, S the entropy, and T the thermodynamic temperature. For a reversible isothermal process ΔA represents the useful work available.

EDTA    →   EDTA

Ethyldiaminetetraacetic acid (C₁₀H₁₆N₂O₈) or shortened EDTA is a hexadentant ligand, and it forms chelates with both transition-metal ions and main-group ions. EDTA is used as a negative ion - EDTA^4-. The diagram shows the structure of the ion with the important atoms picked out. The EDTA ion entirely wraps up a metal ion using all 6 of the positions. The co-ordination number is again 6 because of the 6 co-ordinate bonds being formed by the central metal ion.

EDTA is frequently used in soaps and detergents, because it forms a complexes with calcium and magnesium ions. These ions are in hard water and interfere with the cleaning action of soaps and detergents. EDTA is also used extensively as a stabilizing agent in the food industry and as an anticoagulant for stored blood in blood banks. EDTA is the most common reagent in complexometric titration.

Einstein equation    →   Einsteinova jednadžba

Einstein equation is the mass-energy relationship introduced by Albert Einstein in 1905 in the form E = mc², where E is a quantity of energy, m its mass, and c is the speed of light. It presents the concept that energy possesses mass.