Ziegler process is an industrial process for the manufacture of high-density polyethene using catalysts of titanium(IV) chloride (TiCl4) and aluminium alkyls (e.g. triethylaluminium, Al(C2H5)3). The process was introduced in 1953 by the German chemist Karl Ziegler (1898-1973). It allowed the manufacture of polythene at lower temperatures (about 60 °C) and pressures (about 1 atm) than used in the original process.
Absorption is a phenomenon that occurs when matter crosses from one phase to another passing through the border surface and in the other phase more or less monotonously distributes itself in a concentration higher than the one within the first phase.
Activation energy (Ea) is the energy that must be added to a system in order for a process to occur, even though the process may already be thermodynamically possible. In chemical kinetics, the activation energy is the height of the potential barrier separating the products and reactants. It determines the temperature dependence on the reaction rate.
Acylaction reaction involves the introduction of an acyl group (RCO-) into a compound. An alkyl halide is reacted with an alcohol or a carboxylic acid anhydride e.g.
The introduction of an acetyl group (CH3CO-) is acetylation, a process used for protecting -OH groups in organic synthesis.
Adsorption is a process in which molecules of gas, of dissolved substances in liquids, or of liquids adheres in an extremely thin layer to surfaces of solid bodies with which they are in contact.
Antioxidants are compounds that slow down oxidation processes that degrade foods, fuels, rubber, plastic, and other materials. Antioxidants like butylated hydroxyanisole (BHA), are added to food to prevent fats from becoming rancid and to minimize decomposition of vitamins and essential fatty acids; they work by scavenging destructive free radicals from the food.
Atom marking is a process of infusing radioactive isotopes in live organism, with the purpose of revealing a way, diffusion, or a role of certain substance.
Generalic, Eni. "Born-Haberov kružni proces." Croatian-English Chemistry Dictionary & Glossary. 29 June 2022. KTF-Split. {Date of access}. <https://glossary.periodni.com>.
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