CHEMISTRY GLOSSARY

Faraday’s laws of electrolysis    →   Faradayevi zakoni elektrolize

Faraday’s laws of electrolysis are two laws found by British chemist and physicist Michael Faraday (1791-1867) in his experiments on electrolysis:

1. The quantity of matter extracted on the electrode is proportional to the quantity of charge (Q = I·t) which has flown in electrolysis time.

where z = number of electrons changed in reaction and F = Faraday’s constant which equals 96 487 C mol^-1.

2. The masses of the elements liberated by the same quantity of electricity are directly proportional to their chemical equivalents.

96 487 C will discharge 1 mol Ag and 1/2 mol Cu. The relevant half reactions are:

fat    →   mast

Fats are esters of glycerol and long chain carboxylic acids. Fats occur widely in plants and animals as a means of storing food energy, having twice the calorific value of carbohydrates. Fats derived from plants and fish generally have a greater proportion of unsaturated fatty acids than those from mammals. Fats may be either solid or liquid at room temperature, depending on their structure and composition. Unsaturated fats are liquid at room temperature.

Plant oils may be hardened by the addition of hydrogen atoms, converting double bonds to single bonds. This process is known as hydrogenation. Hydrogenated vegetable oils are often present in margarine and other processed foods.

Alkali hydrolysis of fat with sodium hydroxide it gives glycerol and soap (i.e. a mixture of the sodium salts of the fatty acids).

fatty acid    →   masna kiselina

Fatty acids are aliphatic monocarboxylic acids characterized by a terminal carboxyl group (R-COOH). The higher members of this series of acids occur in nature in the combined form of esters of glycerol (fats), and hence all acids of this family are called fatty acids. Natural fatty acids commonly have a chain of 4 to 28 carbons (usually unbranched and even-numbered), which may be saturated or unsaturated. The most important of saturated fatty acids are butyric (C4), lauric (C12), palmitic (C16), and stearic (C18). The most common unsaturated acids are oleic, linoleic, and linolenic (all C18).

The physical properties of fatty acids are determined by the chain length, degree of unsaturation, and chain branching. Short-chain acids are pungent liquids, soluble in water. As the chain length increases, melting points are raised and water-solubility decreases. Unsaturation and chain branching tend to lower melting points.

ferrite    →   ferit

Ferrites are ceramic materials of the nominal formula MO·Fe₂O₃, where M is a divalent metal (Co, Mn, NI, or Zn). The ferrites show either ferrimagnetism or ferromagnetism, but are not electrical conductors, and they are used in high-frequency circuits as magnetic cores, in rectifiers on memory and record tapes, and various related uses in radio, television, radar, computers, and automatic control systems.

filter flask    →   boca za odsisavanje

Filter flask, also known as a vacuum flask, is a flask with a side arm to which a vacuum can be applied. It usually have heavy side walls to withstand high vacuum.

filter paper    →   filtar papir

Filter paper is a quantitative paper used for filtering and made of pure cellulose treated with hydrochloric and hydrofluoric acid. This kind of paper burns out practically without any remains (less than 0.0001 g ashes). Different types of paper are marked with numbers; qualitative bears marking 595 or 597 and quantitative 589 or 590. Dependable upon precipitate character, different types of filter paper are used:

• black band (589¹) - 100 mL of fluid flows through it in 20 s to 30 s. It is used for filtering of gelatinous precipitates.
• white band (589²) - 100 mL of fluid flows through it in 40 s to 60 s. It is used for coarse crystalline precipitates filtration.
• blue band (589³) - 100 mL of fluid flows through it in 200 s to 400 s. It is used for fine crystalline precipitates.

filtration    →   filtriranje

Filtration is a procedure in which liquids are separated from the precipitate by passing a suspension through the filter. The precipitate remains on the filter and through it the filtrate passes. Gaseous heterogeneous mixtures can also be filtrated.

fission    →   fisija

Fission is a nuclear reaction in which an atomic nucleus breaks into smaller nuclei of comparable mass, releasing a large amount of energy.

fractional distillation    →   frakcijska destilacija

Fractional distillation is a procedure in which liquids of close boiling points are separated. It is conducted in fraction or rectification columns in a way that vapour phase created by distillation is condensed and the condensate thus obtained is redistilled. The procedure is repeated several times. Vapour phase always contains more volatile component than the liquid phase, at top of the column vapour of clean volatile component gets out and at the bottom of the column liquid of nonvolatile component.

free radical    →   slobodni radikal

Free radical is a molecular fragment having one or more unpaired electrons, usually short-lived and highly reactive. They can be produced by photolysis or pyrolysis in which a bond is broken without forming ions. In formulas, a free radical is conventionally indicated by a dot (·CH₃, ·SnH₃, ·Cl). Free radicals are known to be formed by ionising radiation and thus play a part in deleterious degradation effects that occur in irradiated tissue. They also act as initiators or intermediates in oxidation, combustion, photolysis, and polymerisation.