Nerve poison (nerve gas, agents) have had an entirely dominant role since the Second World War. Nerve poisons acquired their name because they affect the transmission of nerve impulses in the nervous system. All nerve poisons belong chemically to the group of organo-phosphorus compounds. They are stable and easily dispersed, highly toxic and have rapid effects both when absorbed through the skin and via respiration. Nerve poisons can be manufactured by means of fairly simple chemical techniques. The raw materials are inexpensive and generally readily available.
The most important nerve agents included in modern chemical weapons arsenals are:
Tabun | (o-ethyl dimethylamidophosphorylcyanide) |
Sarin | (isopropyl methylphosphonofluoridate) |
Soman | (pinacolyl methylphosphonofluoridate) |
GF | (cyclohexyl methylphosphonofluoridate) |
VX | (o-ethyl S-diisopropylaminomethyl methylphosphonothiolate) |
Nerve poisons are colorless, odorless, tasteless liquids of low volatility. Antidotes are atropine sulfate and pralidoxime iodide.
Nitrogen was discovered by Daniel Rutherford (Scotland) in 1772. The origin of the name comes from the Greek words nitron genes meaning nitre and forming and the Latin word nitrum (nitre is a common name for potassium nitrate, KNO3). It is colourless, odourless, generally inert gas. Minimally reactive at room temperature. A component of many organic and inorganic compounds. Makes up about 78 % of earth’s atmosphere. Nitrogen is obtained from liquid air by fractional distillation. Primarily to produce ammonia and other fertilizers. Also used in making nitric acid, which is used in explosives. Also used in welding and enhanced oil recovery.
Ostwald viscometer, also known as U-tube viscometer or capillary viscometer is a device used to measure the viscosity of the liquid with a known density. The method of determining viscosity with this instrument consists of measuring the time for a known volume of the liquid (the volume contained between the marks A and B) to flow through the capillary under the influence of gravity. Ostwald viscometers named after the German chemist Wilhelm Ostwald (1853-1932).
The instrument must first be calibrated with materials of known viscosity such as pure (deionized) water. Knowing the value of viscosity of one liquid, one can calculate the viscosity of other liquid.
where η1 and η2 are viscosity coefficients of the liquid and water, and ρ1 and ρ2 are the densities of liquid and water, respectively.
Atoms can give one or more electrons for bond forming. The valence of any atom, which comes from stechiometrical relation of interbonded atoms, is called an oxidation number or an oxidation degree. Oxidation number of atoms in elementary state is zero. An atom of greater electronegativity has a negative, and an atom of lesser electronegativity has a positive oxidation number.
Parallax is a deceptive change of the position of an object which is observed while the position of the observer changes. Position of eye at all volumetric vessels must be at the same level as the meniscus. If not, the parallax will cause an error while reading the position of the meniscus of a liquid in a burette. It will be a positive mistake if the eye is lower, and negative if the eye is higher than the meniscus plane.
Paschen series are the series of lines in the spectrum of the hydrogen atom which corresponds to transitions between the state with principal quantum number n = 3 and successive higher states.
Phosphorescence is emission of light from a substance exposed to radiation and persisting as an afterglow after the exciting energy has been removed. Unlike fluorescence, in which the absorbed energy is spontaneously emitted about 10-8 second after excitation, phosphorescence requires additional excitation to produce radiation and may last from about mili second to days or years, depending on the circumstances.
Picnometer is a special glass flask which is used for determining a relative density of liquids using the weight of a known volume. It usually has a glass faceted cork which is pierced in the centre like a thin capillary through which surplus of liquid runs out.
Generalic, Eni. "Tekuće agregatno stanje." Croatian-English Chemistry Dictionary & Glossary. 29 June 2022. KTF-Split. {Date of access}. <https://glossary.periodni.com>.
Glossary
Periodic Table