CHEMISTRY GLOSSARY

substitution    →   supstitucija

Substitution (substitution reaction) is a reaction in which an atom or fragment within a molecule is replaced with another atom or a fragment.

substrate    →   supstrat

1. Substrate is a surface upon which an organism grows, sometimes by using chemicals of particles in the material as food

2. Substrate is a substance that is acted upon by an enzyme during a biochemical reaction.

3. Substrate is the material or product that is to be coated (for example, paint or laminate.).

Haber process    →   Haberov proces

Haber process is an industrial process for producing ammonia by reaction of nitrogen with hydrogen:

The reaction is reversible and exothermic, so that a high yield of ammonia is favoured by low temperature. However, the rate of reaction would be too slow for equilibrium to be reached at normal temperatures, so an optimum temperature of about 450 °C is used, with a catalyst of iron containing potassium aluminium oxide promoters. The higher the pressure the greater the yield, although there are technical difficulties in using very high pressures. A pressure of about 250 atmospheres is commonly employed. The removal of ammonia from the batch as soon as it is formed ensures that an equilibrium favouring product formation is maintained. The nitrogen is obtained from air. Formerly, the hydrogen was from water gas and the water-gas shift reaction (the Bosch process) but now the raw material (called synthesis gas) is obtained by steam reforming natural gas.

The process is of immense importance for the fixation of nitrogen for fertilisers and explosives. It was developed in 1908 by German chemist Fritz Haber (1868-1934) and was developed for industrial use by Carl Bosch (1874-1940), hence the alternative name Haber-Bosch process.

half-life of a reactant    →   poluživot reaktanta

For a given reaction the half-life, t_1/2, of a reactant is the time required for its concentration to reach a value that is the arithmetic mean of its initial and final (equilibrium) value.

Half-life is constant for first-order reactions.

Half-life is not constant for second-order reactions but rather it varies with initial concentration and k.

hydrogen    →   vodik

Hydrogen was discovered by Sir Henry Cavendish (England) in 1766. The origin of the name comes from the Greek words hydro and genes meaning water and generate. It is colourless, odourless gas, burns and forms explosive mixtures in air. Reacts violently with oxidants. Hydrogen is the most abundant element in the universe. Commercial quantities of hydrogen are produced by reacting superheated steam with methane or carbon. In lab work from reaction of metals with acid solutions or electrolysis. Most hydrogen is used in the production of ammonia and in metal refining. Also used as fuel in rockets. Its two heavier isotopes (deuterium and tritium) used respectively for nuclear fusion.

termination    →   terminacija

Termination is the final step in a free radical mechanism that results in the stopping of the free radical reaction.

theoretical yield    →   teoretski prinos

Theoretical yield is the maximum quantity of a product that could be formed in a chemical reaction if all the limiting reactants reacted to form products (distinguished from actual yield).

theories of catalysis    →   teorije katalize

Theories of catalysis explain the influence of the catalysts upon the rate of a reaction by describing the detailed mechanism by which the catalyst is involved in the steps of the chemical reaction.

Hesse’s law    →   Hessov zakon

Hesse’s law says that reaction heat of some chemical change does not depend on the way in which the reaction is conducted, but only on starting and ending system state. Hesse’s law is also known as the law of constant heat summation. Hesse’s law is also known as the law of constant heat summation. The law was first put forward in 1840 by the Swiss-born Russian chemist Germain Henri Hess (1802-1850).

Hesse’s law can be used to obtain thermodynamic data that cannot be measured directly. For example, it is very difficult to control the oxidation of graphite to give pure CO. However, enthalpy for the oxidation of graphite to CO₂ can easily be measured. So can the enthalpy of oxidation of CO to CO₂. The application of Hess’s law enables us to estimate the enthalpy of formation of CO.

The equation shows the standard enthalpy of formation of CO to be -110 kJ/mol.

hydrolysis    →   hidroliza

Hydrolysis is a chemical reaction in which water reacts with another substance to form two or more new substances. This involves ionisation of the water molecule, as well as splitting of the compound hydrolysed, e.g.

Examples are conversion of starch to glucose by water in the presence of suitable catalysts and a reaction of the ions of a dissolved salt to form various products, such as acids, complex ions, etc.