CHEMISTRY GLOSSARY

lattice energy    →   energija kristalne rešetke

Lattice energy is the energy per ion pair required to separate completely the ions in a crystal lattice at a temperature of absolute zero.

tetragonal crystal system    →   tetragonski kristalni sustav

Minerals of the tetragonal crystal system are referred to three mutually perpendicular axes. The two horizontal axes are of equal length, while the vertical axis is of different length and may be either shorter or longer than the other two.

fcc    →   fcc

fcc is abbreviation for face-centered cubic lattice.

ice    →   led

Ice is a solid form of water. Water expands when it freezes due to hydrogen bonds thus making ice less density than water so it floats on it.

Bragg angle    →   Braggov kut

Bragg angle (Θ) is the angle between an incident X-ray beam and a set of crystal planes for which the secondary radiation displays maximum intensity as a result of constructive interference. British physicist Sir William Henry Bragg and his son Sir William Lawrence Bragg developed a simple relation for scattering angles, now call Bragg’s law.

which relates the angle θ between a crystal plane and the diffracted X-ray beam, the wavelength λ of the x-rays, the crystal plane spacing d, and the diffraction order n (any integer).

The diffraction experiment as presently considered is intended to provide quantitative information on the lattice constant and shape characteristics of the unit cell.

lumen    →   lumen

Lumen (lm) is the SI derived unit of luminous flux. The lumen is the luminous flux emitted in a solid angle of one steradian by a point source having a uniform intensity of one candela (1 lm =1 cd·sr).

luminous flux    →   svjetlosni tok

Luminous flux (Φ) is the intensity of light from a source multiplied by the solid angle. The SI unit is lumen.

Born-Haber cycle    →   Born-Haberov kružni proces

Born-Haber cycle is a cycle of reactions used for calculating the lattice energies of ionic crystalline solids. For a compound MX, the lattice energy is the enthalpy of the reaction

The standard enthalpy of formation of the ionic solid is the enthalpy of the reaction

The cycle involves equating this enthalpy (which can be measured) to the sum of the enthalpies of a number of steps proceeding from the elements to the ionic solid. The steps are:

1) Atomization of the metal

2) Atomization of the nonmetal

3) Ionisation of the metal

This is obtained from the ionisation potential.

4) Ionisation of the nonmetal

This is electron affinity.

5) Formation of the ionic solids

Equation of the enthalpies gives

from which ΔH_L can be found.

Curie temperature    →   Curiejeva temperatura

For a ferromagnetic material, Curie temperature or Curie point (T_C) is the critical temperature above which the material becomes paramagnetic. For iron the Curie point is 760 °C and for nickel 356 °C. It was named after the French physicist Pierre Curie (1859-1906).

electrochemical cell    →   elektrokemijski članak

Electrochemical cell is a device that converts chemical energy into electrical energy or vice versa when a chemical reaction is occurring in the cell. It consist of two electronically conducting phases (e.g., solid or liquid metals, semiconductors, etc) connected by an ionically conducting phase (e.g. aqueous or non-aqueous solution, molten salt, ionically conducting solid). As an electric current passes, it must change from electronic current to ionic current and back to electronic current. These changes of conduction mode are always accompanied by oxidation/reduction reactions.

An essential feature of the electrochemical cell is that the simultaneously occurring oxidation-reduction reactions are spatially separated. E.g., in a spontaneous chemical reaction during the oxidation of hydrogen by oxygen to water, electrons are passed directly from the hydrogen to the oxygen.

In contrast, in the spontaneous electrochemical reaction in a galvanic cell the hydrogen is oxidised at the anode by transferring electrons to the anode and the oxygen is reduced at the cathode by accepting electrons from the cathode. The ions produced in the electrode reactions, in this case positive hydrogen ions and the negative hydroxyl (OH^-) ions, will recombine in the solution to form the final product of the reaction: water. During this process the electrons are conducted from the anode to the cathode through an outside electric circuit where the electric current can drive a motor, light a light bulb, etc. The reaction can also be reversed: water can be decomposed into hydrogen and oxygen by the application of electrical power in an electrolytic cell.