CHEMISTRY GLOSSARY

blast furnace    →   visoka peć

Blast furnace is a furnace for smelting of iron from iron oxide ores (hematite, Fe₂O₃ or magnetite, Fe₃O₄). Coke, limestone and iron ore are poured in the top, which would normally burn only on the surface. The hot air blast to the furnace burns the coke and maintains the very high temperatures that are needed to reduce the ore to iron. The reaction between air and the fuel generates carbon monoxide. This gas reduces the iron(III) oxide in the ore to iron.

Because the furnace temperature is in the region of 1500 °C, the metal is produced in a molten state and this runs down to the base of the furnace.

The production of iron in a blast furnace is a continuous process. The furnace is heated constantly and is re-charged with raw materials from the top while it is being tapped from the bottom. Iron making in the furnace usually continues for about ten years before the furnace linings have to be renewed.

body-centered cubic lattice    →   prostorno centrirana kubična rešetka

Body-centered cubic lattice (bcc or cubic-I), like all lattices, has lattice points at the eight corners of the unit cell plus an additional points at the center of the cell. It has unit cell vectors a = b = c and interaxial angles α=β=γ=90°.

The simplest crystal structures are those in which there is only a single atom at each lattice point. In the bcc structures the spheres fill 68 % of the volume. The number of atoms in a unit cell is two (8 × 1/8 + 1 = 2). There are 23 metals that have the bcc lattice.

body-centered orthorhombic lattice    →   prostorno centrirana ortorompska rešetka

Body-centered orthorhombic lattice (orthorhombic-I), like all lattices, has lattice points at the eight corners of the unit cell plus an additional points at the center of the cell. It has unit cell vectors a≠b≠c and interaxial angles α=β=γ=90°.

body-centered tetragonal lattice    →   prostorno centrirana tetragonska rešetka

Body-centered tetragonal lattice (tetragonal-I), like all lattices, has lattice points at the eight corners of the unit cell plus an additional points at the center of the cell. It has unit cell vectors a=b≠c and interaxial angles α=β=γ=90°.

bomb calorimeter    →   kalorimetrijska bomba

Bomb calorimeter is a type of constant-volume calorimeter used in measuring the heat of combustion of samples which can be burned in oxygen. Four essential parts are required in any bomb calorimeter:

1. a bomb or vessel in which the combustible charges can be burned,
2. a bucket or container for holding the bomb in a measured quantity of water, together with a stirring mechanism,
3. an insulating jacket to protect the bucket from transient thermal stresses during the combustion process, and
4. a thermometer or other sensor for measuring temperature changes within the bucket.

Boyle’s law    →   Boyleov zakon

Boyle’s law (sometimes referred to as the Boyle-Mariott’s law) is the empirical law, exact only for an ideal gas, which states that the volume of a gas is inversely proportional to its pressure at constant temperature.

Bragg angle    →   Braggov kut

Bragg angle (Θ) is the angle between an incident X-ray beam and a set of crystal planes for which the secondary radiation displays maximum intensity as a result of constructive interference. British physicist Sir William Henry Bragg and his son Sir William Lawrence Bragg developed a simple relation for scattering angles, now call Bragg’s law.

which relates the angle θ between a crystal plane and the diffracted X-ray beam, the wavelength λ of the x-rays, the crystal plane spacing d, and the diffraction order n (any integer).

The diffraction experiment as presently considered is intended to provide quantitative information on the lattice constant and shape characteristics of the unit cell.

branched chain    →   razgranati lanac

Branched chain is an open chain of atoms with one or more side chains attached to it.

Brinell hardness    →   Brinellova tvrdoća

Brinell hardness is a scale for measuring the hardness of metals introduced around 1900 by Swedish metallurgist Johan Brinell (1849-1925). A small chromium steel ball is pressed into the surface of the metal by a load of known weight. The loading force is in the range of 300 N to 30 000 N. The ratio of the mass of the load in kilograms to the area of the depression formed in square millimetres is the Brinell Hardness Number.

Buchner flask    →   Buchnerova tikvica

Büchner flask (also known as a vacuum flask, filter flask, side-arm flask or Kitasato flask) is a thick-walled Erlenmeyer flask with a side arm to which a vacuum can be applied.