Oil of vitriol is an obsolete name for sulfuric acid (H2SO4). Very old way of making sulfuric acid is by heating green vitriol (FeSO4*7H2O) to decomposition and collecting the acid vapors evolved.
Generalic, Eni. "Oil of vitriol." Croatian-English Chemistry Dictionary & Glossary. 29 June 2022. KTF-Split. {Date of access}. <https://glossary.periodni.com>.
Glossary
Periodic Table