Nerve poison (nerve gas, agents) have had an entirely dominant role since the Second World War. Nerve poisons acquired their name because they affect the transmission of nerve impulses in the nervous system. All nerve poisons belong chemically to the group of organo-phosphorus compounds. They are stable and easily dispersed, highly toxic and have rapid effects both when absorbed through the skin and via respiration. Nerve poisons can be manufactured by means of fairly simple chemical techniques. The raw materials are inexpensive and generally readily available.
The most important nerve agents included in modern chemical weapons arsenals are:
Tabun | (o-ethyl dimethylamidophosphorylcyanide) |
Sarin | (isopropyl methylphosphonofluoridate) |
Soman | (pinacolyl methylphosphonofluoridate) |
GF | (cyclohexyl methylphosphonofluoridate) |
VX | (o-ethyl S-diisopropylaminomethyl methylphosphonothiolate) |
Nerve poisons are colorless, odorless, tasteless liquids of low volatility. Antidotes are atropine sulfate and pralidoxime iodide.
Chelating agent is ligand that binds to a metal using more than one atom; a polydentate ligand.
Oxidating agent is a substance that receives electrons and oxidates other substances. Oxidating agent is always reduced in this reaction.
Mustard agents are usually classified as blistering agents owing to the similarity of the wounds caused by these substances resembling burns and blisters. However, since mustard agents also cause severe damage to the eyes, respiratory system and internal organs, they should preferably be described as blistering and tissue-injuring agents. Normal mustard agent (yperite), 1,1-thio-bis-[2-chloroethane], reacts with a large number of biological molecules. The effect of mustard agent is delayed and the first symptoms do not occur between 2-24 hours after exposure. At room temperature, mustard agent is a liquid with low volatility and is very stable during storage.
Reducing agent may be defined in various ways, depending upon the context in which the phrase is used. In broad terms it is often taken to mean a chemical which can act as an electron donor. Thus, in the reaction:
the zinc is being reduced (gaining electrons) by reaction with the iron cations; the Fe2+ in this instance is acting as a reducing agent.
Toxins are effective and specific poisons produced by living organisms. They usually consist of an amino acid chain which can vary in molecular weight between a couple of hundred (peptides) and one hundred thousand (proteins). They may also be low-molecular organic compounds. Toxins are produced by numerous organisms, e.g., bacteria, fungi, algae and plants. Many of them are extremely poisonous, with a toxicity that is several orders of magnitude greater than the nerve agents. Botulinum toxin, produced by the bacteria Clostridium botulinum, is the most poisonous substance known.
Agar, also called agar-agar, is an extract of certain species of red algae (of the Gelidium and Gracilaria genera) that is used as a gelling agent in microbiological culture media, foodstuffs, medicine, and cosmetic. The predominant component of agar is agarose, a polysaccharide made up of subunits of the sugar galactose.
Cerium was discovered by Martin Heinrich Klaproth (Germany) and by Jöns Jacob Berzelius (Sweden) in 1803 and Wilhelm von Hisinger (Germany) in 1814. Named after the asteroid Ceres this discovered two years before the element. It is malleable, ductile, iron-grey metal. Tarnishes in air; reacts easily with water. Dissolves in acids; ignites when heated. Metal ignites and burns readily. Strong reductant. Cerium is most abundant rare earth metal. Found in many minerals like monazite sand [Ce(PO4)]. Its oxides are used in the optics and glass-making industries. Its salts are used in the photography and textile industry. Used in high-intensity carbon lamps and as alloying agents in special metals.
Generalic, Eni. "Nerve agent." Croatian-English Chemistry Dictionary & Glossary. 29 June 2022. KTF-Split. {Date of access}. <https://glossary.periodni.com>.
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