CHEMISTRY GLOSSARY

critical point    →   kritična točka

In general, critical point is the point on the phase diagram of a two-phase system at which the two coexisting phases have identical properties and therefore represent a single phase. At the liquid-gas critical point of a pure substance, the distinction between liquid and gas vanishes, and the vapour pressure curve ends. The coordinates of this point are called the critical temperature and critical pressure. Above the critical temperature it is not possible to liquefy the substance.

critical mass    →   kritična masa

Critical mass is the minimum mass of a fissionable material (²³⁵U or ²³⁹Pu) that will initiate an uncontrolled chain reaction as in an atomic bomb. The critical mass of pure ²³⁹Pu is about 4.5 kg, and of ²³⁵U about 15 kg.

equivalence point    →   točka ekvivalencije

Eequivalence point is the point in a titration when enough titrant has been added to react completely with the analyte.

critical temperature    →   kritična temperatura

Critical temperature is the temperature of the liquid-vapour critical point, that is, the temperature above which a gas cannot be liquefied by an increase of pressure.

point-like object    →   materijalna točka

Point-like object is an expression, usual in kinematics: a point-like object (or a particle) is an object with dimensions, which can be neglected while considering its motion.

isoelectric point    →   izoelektrična točka

Isoelectric point (pI or IEP) is the pH of a solution or dispersion at which the net charge on the molecules or colloidal particles is zero. In electrophoresis there is no motion of the particles in an electric field at the isoelectric point. The net charge (the algebraic sum of all the charged groups present) of any amino acid, peptide or protein, will depend upon the pH of the surrounding aqueous environment. For example, alanine can have a charge of +1, 0, or -1, depending on the pH of the solution in which it is dissolved.

triple point    →   trojna točka

Triple point is the point in p,T space where the solid, liquid, and gas phases of a substance are in thermodynamic equilibrium.

critical pressure    →   kritični tlak

Critical pressure is the pressure of a fluid in its critical point; i.e. when it is at its critical temperature and critical volume.

critical volume    →   kritični volumen

Critical volume is the volume of a fixed mass of a fluid at critical temperature and pressure.

phase diagram    →   fazni dijagram

Phase diagram is a graphic representation of the equilibrium relationships between phases (such as vapour-liquid, liquid-solid) of a chemical compound, mixture of compounds, or solution.

The figure shows a typical phase diagram of an element or a simple compound. The stability of solid, liquid and gas phases depends on the temperature and the pressure. The three phases are in equilibrium at the triple point. The gas and liquid phases are separated by a phase transition only below the temperature of the critical point.