CHEMISTRY GLOSSARY

lattice constants    →   konstante kristalne rešetke

Lattice constants are parameters specifying the dimensions of a unit cell in a crystal lattice, specifically the lengths of the cell edges and the angles between them.

mucopolysaccharide    →   mukopolisaharid

Mucopolysaccharides are carbohydrates that can be found in cellular membranes of bacteria.

negative pole    →   negativan pol

Negative pole is that half-cell in electrochemical cell that has the most negative electrode potential.

Bragg angle    →   Braggov kut

Bragg angle (Θ) is the angle between an incident X-ray beam and a set of crystal planes for which the secondary radiation displays maximum intensity as a result of constructive interference. British physicist Sir William Henry Bragg and his son Sir William Lawrence Bragg developed a simple relation for scattering angles, now call Bragg’s law.

which relates the angle θ between a crystal plane and the diffracted X-ray beam, the wavelength λ of the x-rays, the crystal plane spacing d, and the diffraction order n (any integer).

The diffraction experiment as presently considered is intended to provide quantitative information on the lattice constant and shape characteristics of the unit cell.

calomel electrode    →   kalomel elektroda

Calomel electrode is a type of half cell in which the electrode is mercury coated with calomel (Hg₂Cl₂) and the electrolyte is a solution of potassium chloride and saturated calomel. In the calomel half cell the overall reaction is

Table: Dependence of potential of calomel electrode upon temperature and concentration of KCl according to standard hydrogen electrode

overpotential    →   prenapon

Overpotential (η) is a potential that must be applied in an electrolytic cell in addition to the theoretical potential required to liberate a given substance at an electrode. The value depends on the electrode material and on the current density.

carbohydrate    →   ugljikohidrat

Carbohydrates (often called carbs for short) are polyhydroxy aldehydes or ketones, or substances that yield such compounds on hydrolysis. They are also known as saccharides, a term derived from the Latin word saccharum for sugar. Carbohydrates are the most abundant class of compounds in the biological world, making up more than 50 % of the dry weight of the Earth’s biomass. Every type of food we eat can have its energy traced back to a plant. Plants use carbon dioxide and water to make glucose, a simple sugar, in photosynthesis. Other carbohydrates such as cellulose and starch are made from the glucose. Light from the sun is absorbed by chlorophyll and this is converted to the energy necessary to biosynthesize carbohydrates

The term carbohydrate was applied originally to monosaccharides, in recognition of the fact that their empirical composition can be expressed as C_x(H₂O)_y. Later structural studies revealed that these compounds were not hydrates but the term carbohydrate persists.

Carbohydrates are generally classed as either simple or complex. Simple sugars, or monosaccharides, are carbohydrates that can’t be converted into smaller subunits by hydrolysis. Complex carbohydrates are made of two (disaccharides) or more (oligosaccharides, polysaccharides) simple sugars linked together by acetal (glycosidic) bonds and can be split into the former by hydrolysis.

cathode    →   katoda

Cathode is a negative electrode of an electrolytic cell to which positively charged ions (cations) migrate when a current is passed as in electroplating baths.

In a primary or secondary cell (battery or accumulator) the cathode is the electrode that spontaneously becomes negative during discharge, and form which therefore electrons emerge.

In vacuum electronic devices electrons are emitted by the cathode and flow to the anode.

paper    →   papir

Paper is the thin sheet of material made of cellulose pulp, derived mainly from wood, but also from rags and certain grasses, and processed into flexible leaves or rolls. It is manufactured by bleaching raw material using the bleaching-powder, mixing it with inorganic fillers, colours and glues, and drying. Used primarily for writing, printing, drawing, wrapping, and covering walls.

parchment paper    →   pergamentni papir

Parchment paper is impermeable paper obtained by dipping cellulosic paper in the sulphuric acid.