Electrode of the first kind is a simple metal electrode immersed in a solution containing its own ion (e.g., silver immersed in a silver nitrate solution). The equilibrium potential of this electrode is a function of the concentration (more correctly of activity) of the cation of the electrode metal in the solution (see Nernst’s electrode potential equation).
Generalic, Eni. "Electrode of the first kind." Croatian-English Chemistry Dictionary & Glossary. 29 June 2022. KTF-Split. 1 Apr. 2025. <https://glossary.periodni.com>.
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