CHEMISTRY GLOSSARY

gasoline    →   motorni benzin

Gasoline is a complex mixture of volatile hydrocarbons that may have between 5 to 12 carbons. The major components are branched-chain paraffins, cycloparaffins, and aromatics. Gasoline is most often produced by the fractional distillation of crude oil as the fraction of hydrocarbons in petroleum boiling between 30 °C and 200 °C. The quality of a fuel is measured with its octane number. Octane number is the measure of the resistance of gasoline against detonation or preignition of the fuel in the engine. The higher the octane number, the more compression the fuel can withstand before detonating. The octane number is determined by comparing the characteristics of a gasoline to isooctane with good knocking properties (octane number of 100) and heptane with bad (octane number of 0).

Geiger counter    →   Geigerov brojač

Geiger counter (Geiger-Muller counter) is a device used to detect and measure ionising radiation. It consists of a tube containing a low-pressure gas (usually argon or neon with methane) and a cylindrical hollow cathode through the centre of which runs a fine-wire anode. A potential difference of about 1 000 V is maintained between the electrodes. An ionising particle or photon passing through a window into the tube will cause an ion to be produced and the high potential will accelerate it towards its appropriate electrode, causing an avalanche of further ionisations by collision. The consequent current pulses can be counted in electronic circuits or simply amplified to work a small loudspeaker in the instrument. It was first devised in 1908 by the German physicist Hans Geiger (1882-1945). Geiger and W. Muller produced an improved design in 1928.

half-wave potential    →   poluvalni potencijal

Half-wave potential (E_1/2) is a potential at which polarographic wave current is equal to one half of diffusion current (i_d). In a given supporting electrolyte, the half-wave potential is unique for each element and its different valence states and chemical forms. Observation of a current peak at a specific half-wave potential therefore identifies the chemical species producing the current.

Kjeldahl flask    →   Kjeldahlova tikvica

Kjeldahl flask is a round bottom flask with a long wide neck that is used in the determination of nitrogen by Kjeldahl’s method. The method was developed by the Danish chemist Johan Kjeldahl (1849-1900).

Kjeldahl’s method    →   Kjeldahlov postupak

Kjeldahl’s method is an analytical method for determination of nitrogen in certain organic compounds. The method was developed by the Danish chemist Johan Kjeldahl (1849-1900).

It involves addition of a small amount of anhydrous potassium sulphate to the test compound, followed by heating the mixture with concentrated sulphuric acid, often with a catalyst such as copper sulphate. As a result ammonia is formed. After alkalyzing the mixture with sodium hydroxyde, the ammonia is separated by distillation, collected in standard acid, and the nitrogen determined by back-titration.

1. Kjeldahl flask for decomposition (500 ml – macro or 100 ml - micro)
2. funnel for alkaline solution
3. Wagner tube (drop catcher)
4. condenser
5. absorption flask with known volume of standard acid

nuclear magnetic resonance    →   nuklearna magnetska rezonancija

Nuclear magnetic resonance (NMR) is a type of radio-frequency spectroscopy based on the magnetic field generated by the spinning of electrically charged atomic nuclei. This nuclear magnetic field is caused to interact with a very large (1 T - 5 T) magnetic field of the instrument magnet. NMR techniques have been applied to studies of electron densities and chemical bonding and have become a fundamental research tool for structure determinations in organic chemistry.

Ostwald’s viscometer    →   Ostwaldov viskozimetar

Ostwald viscometer, also known as U-tube viscometer or capillary viscometer is a device used to measure the viscosity of the liquid with a known density. The method of determining viscosity with this instrument consists of measuring the time for a known volume of the liquid (the volume contained between the marks A and B) to flow through the capillary under the influence of gravity. Ostwald viscometers named after the German chemist Wilhelm Ostwald (1853-1932).

The instrument must first be calibrated with materials of known viscosity such as pure (deionized) water. Knowing the value of viscosity of one liquid, one can calculate the viscosity of other liquid.

where η₁ and η₂ are viscosity coefficients of the liquid and water, and ρ₁ and ρ₂ are the densities of liquid and water, respectively.

picnometer    →   piknometar

Picnometer is a special glass flask which is used for determining a relative density of liquids using the weight of a known volume. It usually has a glass faceted cork which is pierced in the centre like a thin capillary through which surplus of liquid runs out.

platinum    →   platina

Platinum was discovered by Antonio de Ulloa (South America) in 1735. The origin of the name comes from the Spanish word platina meaning silver. It is rare, very heavy, soft, silvery-white metal. Resists oxygen and water. Platinum is produced from deposits of native, or elemental. Used in jewellery, to make crucible and special containers and as a catalyst. Used with cobalt to produce very strong magnets. Also to make standard weights and measures. Resists corrosion and acid attacks except aqua regia.

polarography    →   polarografija

Polarography is a volumetric technique which is based on a diffusion controlled analyte travel to the surface of dropping mercury electrode (DME). The surface of the working electrode (dropping mercury electrode) is constantly renewed under dropping conditions and, thus, the conditions under which reaction takes place are readily reproducible. Depolarisation potential enables identification of ions present in the solution, and by measuring the diffusion current their concentration is calculated. Polarography was discovered in 1922 by the Czech chemist Jaroslav Heyrovský (1890-1967).