CHEMISTRY GLOSSARY

Buchner flask    →   Buchnerova tikvica

Büchner flask (also known as a vacuum flask, filter flask, side-arm flask or Kitasato flask) is a thick-walled Erlenmeyer flask with a side arm to which a vacuum can be applied.

Erlenmeyer flask    →   Erlenmeyerova tikvica

Erlenmeyer flask is a glass container which has a narrow, cylindrical mouth and a cone-shaped main body that ends in a wide, flat bottom. It was named after its inventor, a German chemist Richard Erlenmeyer (1825-1909). Erlenmeyer flasks are most often used in titrations to hold the liquid that is being titrated.

Kjeldahl flask    →   Kjeldahlova tikvica

Kjeldahl flask is a round bottom flask with a long wide neck that is used in the determination of nitrogen by Kjeldahl’s method. The method was developed by the Danish chemist Johan Kjeldahl (1849-1900).

volumetric flask    →   odmjerna tikvica

Volumetric flasks are bottles made of glass, in a pear like in shape with long thin necks and flat bottoms. All come with a ground glass stopper for a tight seal. Volume marking is cut in glass with fluoride acid around the neck, so that parallax should be avoided (flask is put in front of the eyes so that one can see only a straight horizontal line). A volumetric flask is calibrated to contain (TC or In) the indicated volume of water at 20 °C when the bottom of the meniscus is adjusted to just rest on the center of the line marked on the neck of the flask. They are used for preparing the exactly known volume of sample solution and standard solutions of reagents. On each flask with volume designation a temperature on which the flask has been calibrated is designated.

vacuum flask    →   vakuum tikvica

See Filter flask

Buchner funnel    →   Buchnerov lijevak

Büchner funnel is one device used for pressure assisted filtration. Buchner funnel is a cylindrical porcelain filtering funnel (glass and plastic funnels are also available) that has a perforated plate on which the flat filter paper is placed. A vacuum in the flask underneath the filter allows atmospheric pressure on the sample to force the liquid through the filter paper. It is named after the German chemist Ernst Wilhelm Büchner (1850-1925) who designed this funnel in 1885.

filter flask    →   boca za odsisavanje

Filter flask, also known as a vacuum flask, is a flask with a side arm to which a vacuum can be applied. It usually have heavy side walls to withstand high vacuum.

aliquot    →   alikvot

Aliquot is a known volume of liquid that represents a part of some larger volume. It is usually taken with a pipette from a measured flask.

Contat-Gockel’s valve    →   Contat-Gockelov ventil

Contat-Göckel’s valve is used for maintenance of inert atmosphere in a flask. The valve is filled with a saturated solution of sodium bicarbonate (NaHCO₃) so that the end of the tube is covered. Solution inside the valve keeps the flask contents away from the oxygen influence from air. If low pressure is created inside the flask (when the flask is cooled), the solution will penetrate inside it from funnel and in a reaction with acid CO₂ is generated which fills up the flask.

Solution from the funnel will keep penetrating until CO₂ pressure in the flask is equalised with the outer pressure.

Kjeldahl’s method    →   Kjeldahlov postupak

Kjeldahl’s method is an analytical method for determination of nitrogen in certain organic compounds. The method was developed by the Danish chemist Johan Kjeldahl (1849-1900).

It involves addition of a small amount of anhydrous potassium sulphate to the test compound, followed by heating the mixture with concentrated sulphuric acid, often with a catalyst such as copper sulphate. As a result ammonia is formed. After alkalyzing the mixture with sodium hydroxyde, the ammonia is separated by distillation, collected in standard acid, and the nitrogen determined by back-titration.

1. Kjeldahl flask for decomposition (500 ml – macro or 100 ml - micro)
2. funnel for alkaline solution
3. Wagner tube (drop catcher)
4. condenser
5. absorption flask with known volume of standard acid