CHEMISTRY GLOSSARY

manganometry    →   manganometrija

Manganometry is a quantitative oxidimetric method based on measurement of potassium permanganate (KMnO₄) spent for an oxidation of the matter in question.

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monochromator    →   monokromator

Monochromator (from the Greek words mono and chroma meaning single and colour) is an optical device based on dispersion of light by one or more prisms or diffraction gratings into its constituent wavelengths, which are utilized in turn.

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neutral oxide    →   neutralni oksid

Neutral oxides are those oxides which show neither basic nor acidic properties when they react with water. Examples include carbon monoxide (CO) and nitrous oxide (N₂O) which are only slightly soluble in water, and nitric oxide (NO) which is appreciably soluble in cold water.

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glycoside    →   glikozid

Glycoside is one of a group of organic compounds in which a sugar group is bonded through its anomeric carbon to another group via a glycosidic bond. The sugar group is known as the glycon and the non-sugar group as the aglycon. According to the IUPAC definition, all disaccharides and polysaccharides are glycosides where the aglycone is another sugar.

In the free hemiacetal form, sugars will spontaneously equilibrate between the α and β anomers. However, once the glycosidic bond is formed, the anomeric configuration of the ring is locked as either α or β. Therefore, the alpha and beta glycosides are chemically distinct. They will have different chemical, physical, and biological properties. Many glycosides occur abundantly in plants, especially as flower and fruit pigments.

The term glycoside was later extended to cover not only compounds in which the anomeric hydroxy group is replaced by a group -OR, but also those in which the replacing group is -SR (thioglycosides), -SeR (selenoglycosides), -NR1R2 (N-glycosides), or even -CR1R2R3 (C-glycosides). Thioglycoside and selenoglycoside are legitimate generic terms; however the use of N-glycoside, although widespread in biochemical literature, is improper and not recommended here (glycosylamine is a perfectly acceptable term). C-Glycoside is even less acceptable. All other glycosides are hydrolysable; the C-C bond of C-glycosides is usually not. The use and propagation of names based on C-glycoside terminology is therefore strongly discouraged.

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hexagonal crystal system    →   heksagonski kristalni sustav

Hexagonal crystal system is based on four crystallographic axes. The system of crystallographic axes of the hexagonal crystal system consists of three equivalent horizontal (equatorial) axes of which the positive ends make an angle of 120°. These axes are sometimes denoted as a, b and d axes. The fourth axis is (c) is perpendicular to and shorter or longer than the other three.

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neutral substance    →   neutralna tvar

Neutral substance is a substance that shows no acid or base properties, has an equal number of hydrogen and hydroxyl ions and does not change the colour of litmus-paper.

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neutralisation    →   neutralizacija

Neutralisation is the process in which an acid reacts with a base to form a salt and water.

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Pauling scale    →   Paulingova skala

Pauling scale is a numerical scale of electronegativities based on bond-energy calculations for different elements joined by covalent bonds. Electronegativity is the power of an atom when in a molecule to attract eletrons to itself. Fluorine is the most electronegative element with a Pauling electronegativity value of 4.

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pK    →   pK

pK is the negative logarithm (base 10) of an equilibrium constant K.

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primary amine    →   primarni amin

Primary amine is an amine on which there is only one alkyl group bonded, it is a weak base, and has a fish odour.

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