CHEMISTRY GLOSSARY

ribonucleic acid    →   ribonukleinska kiselina

Ribonucleic acid is a complex organic compound in living cells that is concerned with protein synthesis. Plays an intermediary role in converting the information contained in DNA into proteins. RNA carries the genetic information from DNA to those parts of the cell where proteins are made. Some viruses store their genetic information as RNA not as DNA.

Ribonucleic acid is a similar molecule to DNA but with a slightly different structure.

The structural difference with DNA is that RNA contains a -OH group both at the 2' and 3' position of the ribose ring, whereas DNA (which stands, in fact, for deoxy-RNA) lacks such a hydroxy group at the 2' position of the ribose. The same bases can be attached to the ribose group in RNA as occur in DNA, with the exception that in RNA thymine does not occur, and is replaced by uracil, which has an H-group instead of a methyl group at the C-5 position of the pyrimidine. Unlike the double-stranded DNA molecule, RNA is a single-stranded molecule.

The three main functionally distinct varieties of RNA molecules are: (1) messenger RNA (mRNA) which is involved in the transmission of DNA information, (2) ribosomal RNa (rRNA) which makes up the physical machinery of the synthetic process, and (3) transfer RNA (tRNA) which also constitutes another functional part of the machinery of protein synthesis.

Schrodinger equation    →   Schrodingerova jednadžba

Schrödinger equation is the basic equation of wave mechanics which, for systems not dependent on time, takes the form:

where Ψ is the wavefunction, V is the potential energy expressed as a function of the spatial coordinates, E its total energy, ² is the Laplacian operator, h is Planck’s constant, and m is the mass.

salinity    →   salinitet

Salinity (S) is a measure of the quantity of dissolved salts in seawater. It is formally defined as the total amount of dissolved solids in seawater in parts per thousand (‰) by weight when all the carbonate has been converted to oxide, the bromide and iodide to chloride, and all organic matter is completely oxidized.

Chlorinity is the oldest of the salinity measures considered and is still a corner-stone in the study of dissolved material in seawater. Based on the principle of constant relative proportions it provides a measure of the total amount of dissolved material in seawater in terms of the concentration of halides. The relationship between chlorinity (Cl) and salinity as set forth in Knudsen’s tables is

In 1962, however, a better expression for the relationship between total dissolved salts and chlorinity was found to be

Practical Salinity (S_P) was introduced as a replacement for Chlorinity. Practical Salinity is is relatively easy to measure using standard conductometers, measurements are more precise and less time consuming than measurements of Chlorinity and accurate measurements can even be made in situ. Practical salinity S_P is defined on the Practical Salinity Scale of 1978 (PSS-78) in terms of the conductivity ratio K₁₅ which is the electrical conductivity of the sample at temperature t₆₈ = 15 °C and pressure equal to one standard atmosphere, divided by the conductivity of a standard potassium chloride (KCl) solution at the same temperature and pressure. The mass fraction of KCl in the standard solution is 0.0324356 (32.4356 g of KCl in 1 kg of solution).

Note that Practical Salinity is a unit-less quantity. Though sometimes convenient, it is technically incorrect to quote Practical Salinity in "psu". For most purposes one can assume that the psu and the ‰, are synonymous.

The global average salinity of ocean waters is about 35 ‰, that is, about 35 g of solid substances are dissolved in 1 kg of seawater.

second    →   sekunda

Second (s) is the SI base unit of time.

The second is the duration of 9 192 631 770 periods of the radiation corresponding to the transition between the two hyperfine levels (F = 4, m_F = 0 to F = 3, m_F = 0) of the ground state of the caesium 133 atom.

sedimentary rocks    →   sedimentne stijene

Sedimentary Rocks are formed by the accumulation and subsequent consolidation of sediments into various types of rock. There are three major types of sedimentary rocks:

Biogenic sedimentary rocks are formed from organic processes when organisms use materials dissolved in water to build a shell or other skeletal structure.

Clastic sedimentary rocks are composed directly of the sediments or fragments from other rocks.

Chemical sedimentary rocks are formed through evaporation of a chemical rich solution.

Based on their sizes, sediment particles are classified, based on their size, into six general categories:

• boulder (>256 mm)
• cobble (64 - 256 mm)
• gravel (2 - 64 mm)
• sand (1/16 - 2 mm)
• silt (1/256 - 1/16 mm)
• clay (<1/256 mm)

sedimentation    →   sedimentiranje

Sedimentation is a process of separating specifically heavier, suspended matter, than the solution is. Solid matter settles on the bottom of the vessel and the liquid above it is poured off. The settling zone is the largest portion of the sedimentation basin. This zone provides the calm area necessary for the suspended particles to settle. The sludge zone, located at the bottom of the tank, provides a storage area for the sludge before it is removed for additional treatment or disposal.

tellurium    →   telurij

Tellurium was discovered by Franz Joseph Muller von Reichstein (Romania) in 1782. The origin of the name comes from the Latin word tellus meaning earth. It is silvery-white, brittle semi-metal. Unreactive with water or HCl; dissolves in HNO₃; burns in air or oxygen. Tellurium is obtained as a by-product of copper and lead refining. Used to improve the machining quality of copper and stainless steel products and to colour glass and ceramics. Also in thermoelectric devices. Some is used in the rubber industry and it is a basic ingredient in manufacturing blasting caps.

silver/silver-chloride electrode    →   srebro/srebrov klorid elektroda

Silver/silver-chloride electrode is by far the most common reference type used today because it is simple, inexpensive, very stable and non-toxic. It is mainly used with saturated potassium chloride electrolyte, but can be used with lower concentrations such as 3.5 mol dm^-3 or 1 mol dm^-3 potassium chloride. Silver/silver-chloride electrode is a referent electrode based on the following halfreaction

thermometer    →   termometar

Thermometers are devices for measuring temperature. Linear and volume thermal expansion are macroscopic properties of matter, which can be easily measured, relative to measurements of microscopic properties, on the basis of which, temperature is defined. Thermometers based on thermal expansion are secondary instruments that is, they have to be calibrated in comparison to a standard thermometer. In a thermometer with liquid, mercury or alcohol is placed in a small glass container. If temperature increases, the liquid undergoes volume expansion and rises in a capillary. The level of the raised liquid is the measure of temperature. Mercury thermometers measure temperatures in the temperature range between -39 °C and 300 °C. Alcohol thermometers measure lower temperatures. Bimetal thermometers have a spiral spring, which consists of two metals with different coefficients of linear expansion. When temperature changes, metals undergo different change in length and the consequence twisting of the spring is transferred to a pointer, the deflection of which is the measure of temperature.

thin layer chromatography    →   tankoslojna kromatografija

Thin layer chromatography. (TLC) is a technique for separating components in a mixture on the basis of their differing polarities. A spot of sample is placed on a flat sheet coated with silica and then carried along by a solvent that soaks the sheet. Different components will move different distances over the surface. TLC is a useful screening technique in clinical chemistry; for example, it can be used to detect the presence of drugs in urine.