CHEMISTRY GLOSSARY

valence shell    →   valentna ljuska

Valence shell is the shell corresponding to the highest value of principal quantum number in the atom. The valence electrons in this shell are on average farther from the nucleus than other electrons. They are often directly involved in chemical reaction.

valence electron    →   valentni elektron

Valence electrons are electrons that can be actively involved in a chemical change, usually electrons in the outermost (valent) shell. For example, sodium’s ground state electron configuration is 1s² 2s² 2p⁶ 3s¹; the 3s electron is the only valence electron in the atom. Germanium (Ge) has the ground state electron configuration 1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p²; the 4s and 4p electrons are the valence electrons.

valence    →   valencija

Valence is the charge on an ion based on the number of electrons transferred or shared within a specific structure. For example, in H₂O, oxygen has a valence of 2, carbon in CH₄ has a valence of four.

valence bond    →   valentna veza

In the valence bond theory, a valence bond is a chemical bond formed by overlap of half-filled atomic orbitals on two different atoms.

valence bond theory    →   teorija valentne veze

Valence bond theory is a theory that explains the shapes of molecules in terms of overlaps between half-filled atomic orbitals, or half filled hybridised orbitals.

electron    →   elektron

The electron is an elementary particle with a negative electric charge of (1.602 189 2±0.000 004 6)×10^-19 C and a mass of 1/1837 that of a proton, equivalent to (9.109 534±0.000 047)×10^-31 kg.

In 1897 the British physicist Joseph John (J.J.) Thomson (1856-1940) discovered the electron in a series of experiments designed to study the nature of electric discharge in a high-vacuum cathode-ray tube. Thomson interpreted the deflection of the rays by electrically charged plates and magnets as evidence of bodies much smaller than atoms that he calculated as having a very large value for the charge to mass ratio. Later he estimated the value of the charge itself.

Electrons are arranged in from one to seven shells around the nucleus; the maximum number of electrons in each shell is strictly limited by the laws of physics (2n²). The outer shells are not always filled: sodium has two electrons in the first shell (2×1² = 2), eight in the second (2×2² = 8), and only one in the third (2×3² = 18). A single electron in the outer shell may be attracted into an incomplete shell of another element, leaving the original atom with a net positive charge. Valence electrons are those that can be captured by or shared with another atom.

Electrons can be removed from the atoms by heat, light, electric energy, or bombardment with high-energy particles. Decaying radioactive nuclei spontaneously emit free electrons, called β particles.

VSEPR    →   VSEPR

Valence shell electron pair repulsion theory (VSEPR) is a model that explains the shapes of molecules by assuming that electron pairs arrange themselves around atoms in a way that minimizes electron-electron repulsions.

metal    →   metal

Metals are materials in which the highest occupied energy band (conduction band) is only partially filled with electrons.

Their physical properties generally include:

- They are good conductors of heat and electricity. The electrical conductivity of metals generally decreases with temperature.

- They are malleable and ductile in their solid state.

- They show metallic lustre.

- They are opaque.

- They have high density.

- They are solids (except mercury)

- They have a crystal structure in which each atom is surrounded by eight to twelve near neighbours

Their chemical properties generally are:

- They have one to four valence electrons.

- They have low ionisation potentials; they readily lose electrons.

- They are good reducing agents.

- They have hydroxides which are bases or amphoteric.

- They are electropositive.

Metallic characteristics of the elements decrease and non-metallic characteristics increase with the increase of valence electrons. Also metallic characteristics increase with the number of electron shells. Therefore, there is no sharp dividing line between the metals and non-metals.

Of the 114 elements now known, only 17 show primarily non-metallic characteristics, 7 others are metalloids, and 89 may be classed as metals.

molecular shape    →   oblik molekule

Molecular shape is the three dimensional arrangement of atoms in space around a central atom. The molecular formula of a substance does not give an indication of its shape. For example, CO₂ is a linear molecule, but SO₂ is angular.

The three-dimensional shapes of many small molecules can be predicted by applying the valence shell electron pair repulsion theory (VSEPR). When atoms combine to form molecules, pairs of valence electrons arrange themselves as far from each other as possible. Another way to characterize molecular shape is in terms of hybrid orbitals.

calcium    →   kalcij

Calcium was discovered by Sir Humphry Davy (England) in 1808. The origin of the name comes from the Latin word calix meaning lime. It is fairly hard, silvery-white metal. Exposed surfaces form oxides and nitrides. Reacts with water and oxygen. Occurs only in compounds. Calcium is obtained from minerals like chalk, limestone and marble. Pure metal is produced by replacing the calcium in lime (CaCO₃) with aluminium in hot, low pressure retorts. Used by many forms of life to make shells and bones. Virtually no use for the pure metal, however two of its compounds are, lime (CaO) and gypsum (CaSO₄), are in great demand by a number of industries.