CHEMISTRY GLOSSARY

amount fraction    →   količinski udio

Amount fraction, x_A, (y for gaseous mixtures) is the ratio of the amount of substance (number of moles) of substance A to the total amount of substance in a mixture.

biocapacity    →   biokapacitet

Biocapacity (or biological capacity) is the capacity of ecosystems to produce useful biological materials and to absorb carbon dioxide generated by humans, using current management schemes and extraction technologies. Useful biological materials are defined as those used by the human economy, hence what is considered useful can change from year to year. The biocapacity of an area is calculated by multiplying the actual physical area by the yield factor and the appropriate equivalence factor.

Yield factor is a factor that accounts for differences between countries in productivity of a given land type. Each country and each year has yield factors for cropland, grazing land, forest, and fisheries.

Equivalence factor is a productivity based scaling factor that converts a specific land type into a universal unit of biologically productive area, a global hectare (gha).

Boltzmann equation    →   Boltzmannova jednadžba

Boltzmann equation is a statistical definition of entropy, given by

where S and k are the entropy and Boltzmann’s constant, respectively, and W is the probability of finding the system in a particular state.

carrier gas    →   plin nositelj

Carrier gas is the gas, (usually helium or nitrogen), which carries the sample undergoing analysis through the column in gas chromatography.

coherence    →   koherentnost

If two overlapping light waves are to interfere detectably, the phase difference between them must remain constant with time, i.e. the waves must be coherent.

covalentity    →   kovalentnost

Covalentity is a maximum number of covalent bond that one atom can make, it is equal to the number of hydrogen atoms that are combined with other atoms. It is usually constant.

balance    →   vaga

Balance is an instrument to measure the mass (or weight) of a body. Balance beam type scales are the oldest type and measure weight using a fulcrum or pivot and a lever with the unknown weight placed on one end of the lever, and a counterweight applied to the other end. When the lever is balanced, the unknown weight and the counterweight are equal. The equal-arm balance consists of two identical pans hung from either end of a centrally suspended beam. The unequal-arm balance is made with one arm of the balance much longer than the other.

More modern substitution balances use the substitution principle. In this calibrated weights are removed from the single lever arm to bring the single pan suspended from it into equilibrium with a fixed counter weight. The substitution balance is more accurate than the two-pan device and enables weighing to be carried out more rapidly.

Electromagnetic force restoration balances also use a lever system but a magnetic field is used to generate the force on the opposite end of the lever and balance out the unknown mass. The current used to drive the magnetic coil is proportional to the mass of the object placed on the platform.

blackbody radiation    →   zračenje crnog tijela

Blackbody radiation is the radiation emitted by a perfect blackbody, i.e., a body which absorbs all radiation incident on it and reflects none. The primary law governing blackbody radiation is the Planck Radiation Law, which governs the intensity of radiation emitted by unit surface area into a fixed direction (solid angle) from the blackbody as a function of wavelength for a fixed temperature. The Planck Law can be expressed through the following equation

where λ is the wavelength, h is Planck’s constant, c is the speed of light, k is the Boltzmann constant, and T is the temperature.

Bohr magneton    →   Bohrov magneton

Bohr magneton (μ_B) is the atomic unit of magnetic moment, defined as

where h is Planck’s constant, m_e the electron mass, and e the elementary charge. It is the moment associated with a single electron spin.

bomb calorimeter    →   kalorimetrijska bomba

Bomb calorimeter is a type of constant-volume calorimeter used in measuring the heat of combustion of samples which can be burned in oxygen. Four essential parts are required in any bomb calorimeter:

1. a bomb or vessel in which the combustible charges can be burned,
2. a bucket or container for holding the bomb in a measured quantity of water, together with a stirring mechanism,
3. an insulating jacket to protect the bucket from transient thermal stresses during the combustion process, and
4. a thermometer or other sensor for measuring temperature changes within the bucket.