CHEMISTRY GLOSSARY

accumulation    →   akumulacija

Accumulation (Lat. accumulatio) is storage of matter or energy.

accumulator    →   akumulator

Accumulator (secondary cell, storage battery) is a type of voltaic cell or battery that can be recharged by passing current through it from an external D.C. supply. The charging current reverses the chemical reactions in the cell. The common types are the lead-acid accumulator and the nickel-cadmium cell.

Acheson process    →   Achesonov proces

Acheson process is an industrial process to synthesize graphite and silicon carbide (carborundum), named after its inventor the American chemist Edward Goodrich Acheson (1856-1931). In this process, a solid-state reaction between pure silica sand (SiO₂) and petroleum coke (C) at very high temperature (more than 2500 °C) leads to the formation of silicon carbide under the general reaction:

While studying the effects of high temperature on carborundum, Acheson had found that silicon vaporizes at about 4150 °C, leaving behind graphitic carbon.

acid dissociation constant    →   konstanta disocijacije kiseline

Acid dissociation constant (K_a) is the equilibrium constant for the dissociation of an acid HA through the reaction

The quantity pK_a = -log K_a is often used to express the acid dissociation constant.

acid rain    →   kisela kiša

Acid rain is rainwater that shows acid reaction because of nitrogen and sulphur oxides absorption. It is generated mainly by industrial pollutions.

activated complex    →   aktivirani kompleks

Activated complex is an intermediate structure formed in the conversion of reactants to products. The activated complex is the structure at the maximum energy point along the reaction path; the activation energy is the difference between the energies of the activated complex and the reactants.

additive    →   aditivi

Additive is a substance added to a material to improve its properties in some way. Additives are often present in small amounts and are used for a variety of purposes, as in preventing corrosion, stabilizing polymers, and preserving and improving food.

adiabatic process    →   adijabatski proces

Adiabatic process is a thermodynamic process in which no heat enters or leaves the system. In general, an adiabatic change involves a fall or rise in temperature of the system.

ageing    →   starenje

Ageing is the physical and/or chemical change of a material with respect to time, under defined environmental conditions, leading to improvement or deterioration of properties.

allomerism    →   alomerija

Allomerism is the appearance of substances with different chemical composition but the same crystalline form.