CHEMISTRY GLOSSARY

refractometer    →   refraktometar

Refractometer is an optical device used from measurement of refractive index. A refractometer takes advantage of the fact that light bends as it passes through different materials. It can be used to measure the salinity of water or the amount of sugar in fresh grapes. Refractometers are available with or without automatic temperature compensation (ATC).

When using a conventional saltwater refractometer, a sample is placed on an optical prism in the sample window. As light shines through the sample, it is bent according to the salinity of the water, and casts a shadow on the scale that is visible through the eyepiece. Salinity is read directly through the eyepiece.

sedimentation    →   sedimentiranje

Sedimentation is a process of separating specifically heavier, suspended matter, than the solution is. Solid matter settles on the bottom of the vessel and the liquid above it is poured off. The settling zone is the largest portion of the sedimentation basin. This zone provides the calm area necessary for the suspended particles to settle. The sludge zone, located at the bottom of the tank, provides a storage area for the sludge before it is removed for additional treatment or disposal.

thermal expansion    →   toplinsko rastezanje

Thermal expansion is a change in dimensions of a material resulting from a change in temperature. All objects change size with changes in temperature. The change ΔL in any linear dimension L is given by

in which α is the thermal coefficient of linear expansion, L_o is the initial or reference dimension at temperature T_o (reference temperature) and ΔT is change in temperature which causes the change in dimension.

The change ΔV in the volume of a sample of solid or liquid is

Here γ is coefficient of volume expansion, V_o is the volume of the sample at temperature T_o and ΔV is the change in volume over the temperature range ΔT. With isotropic substances, the coefficient of volume expansion can be calculated from the coefficient of linear expansion: γ = 3α.

solar cell    →   sunčeva ćelija

Solar cell, or photovoltaic cell, is a device that captures sunlight and transforms it directly to electricity. All solar cells make use of photovoltaic effect, so often they are called photovoltaic cells. Almost all solar cells are built from solid-state semiconducting materials, and in the vast majority of these the semiconductor is silicon.

The photovoltaic effect involves the generation of mobile charge carriers-electrons and positively charged holes-by the absorption of a photon of light. This pair of charge carriers is produced when an electron in the highest filled electronic band of a semiconductor (the valence band) absorbs a photon of sufficient energy to promote it into the empty energy band (the conduction band). The excitation process can be induced only by a photon with an energy corresponding to the width of the energy gap that separates the valence and the conduction band. The creation of an electron-hole pair can be converted into the generation of an electrical current in a semiconductor junction device, wherein a layer of semiconducting material lies back to back with a layer of either a different semiconductor or a metal. In most photovoltaic cells, the junction is p-n junction, in which p-doped and n-doped semiconductors are married together. At the interface of the two, the predominance of positively charged carriers (holes) in the p-doped material and of negatively charged carriers (electrons) in the n-doped material sets up an electric field, which falls off to either side of the junction across a space-charge region. When absorption of a photon in this region generates an electron-hole pair, these charge carriers are driven in opposite directions by the electric field, i.e. away from the interface and toward the top and bottom of the two-layer structure, where metal electrodes on these faces collect the current. The electrode on the top layer (through which light is absorbed) is divided into strips so as not to obscure the semiconducting layers below. In most widely used commercial solar cells, the p-doped and n-doped semiconductive layers are formed within a monolithic piece of crystalline silicon. Silicon is able to absorb sunlight at those wavelengths at which it is most intense-from the near-infrared region (wavelengths of around 1200 nm) to the violet (around 350 nm).

thermal resistance    →   toplinski otpor

Heat always flows from a higher to a lower temperature level. The driving force for the heat flux lies in the temperature difference ΔT between two temperature levels. Analogous to Ohm’s law, the following holds:

where H = dQ/dt is heat flux, measured in watts, ΔT is temperature difference across the thermal resistance, measured in kelvin, and R_th is thermal resistance, measured in K/W.

For example, suppose there were two houses with walls of equal thickness; one is made of glass and the other of asbestos. On a cold day, heat would pass through the glass house much faster. The thermal restistance of asbestos is then higher than of glass.

If the thermal Ohm’s law is divided by the heat capacity C, Newton’s law of cooling is obtained:

where dT/dt is rate of cooling or heating, measured in K s^-1, and C is heat capacity, measured in J K^-1.

thermosphere    →   termosfera

Thermosphere is the layer of the earth’s atmosphere extending from the top of the mesosphere (80 km - 90 km above the surface) to about 500 km. It is characterised by a rapid increase in temperature with increasing altitude up to about 200 km, followed by a levelling off in the 300 km - 500 km region.

visible radiation    →   vidljivo zračenje

Human eye can only see electromagnetic radiation of wavelengths form 400 nm to 760 nm. This narrow part of electromagnetic spectrum is called visible radiation. Visible (white) light is a mixture of light of all kind of colours, it can be separated, with the help of a glass prism, into its component colours - visible light spectrum, and each colour corresponds to a certain area of wavelengths:

water jet vacuum pump    →   vodena sisaljka

The water jet vacuum pump or vacuum aspirator is one of the most popular devices that produces vacuum in laboratories. The rapid flow of water through the device creates a vacuum in a side-arm that is connected to a vacuum application such a Buchner flask. The water jet vacuum pump creates a vacuum by means of Venturi effect named after the Italian physicist Giovanni Battista Venturi (1746–1822). The Venturi effect is the reduction in fluid pressure that results when a fluid flows through a constricted section of pipe. Water jet pumps are manufactured of glass, plastic or metal, depending on the conditions in which they are used.