CHEMISTRY GLOSSARY

isotherm    →   izoterma

Isotherm is a line connecting points of equal temperature on a graphic representation of a physical system.

isothermal process    →   izotermni proces

Isothermal process is a thermodynamic process in which the temperature of the system does not change.

epimer    →   epimer

Epimers are diastereoisomers that have the opposite configuration at only one of two or more chiral centers present in the respective molecular entities. For example D-glucose and D-mannose, which differ only in the stereochemistry at C-2, are epimers, as are D-glucose and D-galactose (which differ at C-4).

ester    →   ester

Esters are organic compounds formed by a reaction between alcohol and acids. Esters formed from carboxylic acids have the general formula RCOOR’. Triesters, molecules containing three ester groups, occur in nature as oils and fats.

face-centered cubic lattice    →   plošno centrirana kubična rešetka

Face-centered cubic lattice (fcc or cubic-F), like all lattices, has lattice points at the eight corners of the unit cell plus additional points at the centers of each face of the unit cell. It has unit cell vectors a =b =c and interaxial angles α=β=γ=90°.

The simplest crystal structures are those in which there is only a single atom at each lattice point. In the fcc structures the spheres fill 74 % of the volume. The number of atoms in a unit cell is four (8×1/8 + 6×1/2 = 4). There are 26 metals that have the fcc lattice.

law of conservation of energy    →   zakon o očuvanju energije

Law of conservation of energy: In an isolated system energy can be transferred from one form to another but the total energy of the system remains constant.

Le Chatelier’s principle    →   Le Chatelierov princip

The idea that a system at equilibrium will respond to a stress placed upon it in such a manner as to partially offset that stress. The principle was first stated in 1888 by the French physical chemist Henri Le Chatelier (1850-1936).

Mannich reaction    →   Mannichova reakcija

Mannich reaction is a process in which hydrogen atoms in organic compounds are replaced with a methyl group.

mercaptides    →   merkaptidi

Mercaptides are derivatives of mercaptanes in which hydrogen from the SH-group is replaced with a metal atom.

Navier-Stokes equations    →   Navier-Stokesove jednadžbe

Navier-Stokes equations are a set of complex equations for the motion of a viscous fluid subject to external forces.