CHEMISTRY GLOSSARY

hydrophilic    →   hidrofilan

Hydrophilic is having a strong tendency to bind or absorb water, which results in swelling and formation of reversible gels. This property is characteristic of carbohydrates.

hygroscopic    →   higroskopnost

When some substance is hygroscopic, it means that that substance can absorb moisture from air.

immersion plating    →   galvaniziranje uranjanjem

Immersion plating involves depositing a metallic coating on a metal immersed in a liquid solution, without the aid of an external electric current. Also called dip plating.

impedance    →   impedancija

Impedance is the analogue of the resistance or resistivity when applied to alternating current. That is, it is a measure of a material’s inability to carry the electrical current. In many materials the impedance varies as the frequency of the applied electrical potential changes, due to the properties of the conducting liquid or solid. In electrochemistry, the impedance of the electrodes is also frequency dependent.

electrode potential    →   elektrodni potencijal

Electrode potential is defined as the potential of a cell consisting of the electrode in question acting as a cathode and the standard hydrogen electrode acting as an anode. Reduction always takes place at the cathode, and oxidation at the anode. According to the IUPAC convention, the term electrode potential is reserved exclusively to describe half-reactions written as reductions. The sign of the half-cell in question determines the sign of an electrode potential when it is coupled to a standard hydrogen electrode.

Electrode potential is defined by measuring the potential relative to a standard hydrogen half cell

The convention is to designate the cell so that the oxidised form is written first. For example

The e.m.f. of this cell is

By convention, at p(H₂) = 101325 Pa and a(H⁺) = 1.00, the potential of the standard hydrogen electrode is 0.000 V at all temperatures. As a consequence of this definition, any potential developed in a galvanic cell consisting of a standard hydrogen electrode and some other electrode is attributed entirely to the other electrode

impurity    →   nečistoća

Impurities are traces of other elements or compounds in an impure substance.

inorganic chemistry    →   anorganska kemija

Inorganic chemistry, the branch of chemistry concerned with compounds of elements other than carbon. Certain simple carbon compounds, such as CO, CO₂, CS₂, carbonates CO₃^2- and cyanides CN^-, are usually treated in inorganic chemistry.

insulator    →   izolator

Insulator is a material in which the highest occupied energy band (valence band) is completely filled with electrons, while the next higher band (conduction band) is empty. Solids with an energy gap of 5 eV or more are generally considered as insulators at room temperature. Their conductivity is less than 10^-6 S/m and increases with temperature.

electrolysis    →   elektroliza

Electrolysis is the decomposition of a substance as a result of passing an electric current between two electrodes immersed in the sample.

electronegativity    →   elektronegativnost

Electronegativity is a parameter originally introduced by L. Pauling which describes, on a relative basis, the power of an atom to attract electrons. For example, in hydrogen chloride, the chlorine atom is more electronegative than the hydrogen and the molecule is polar, with a negative charge on the chlorine atom.

There are various ways of assigning values for the electronegativity of an element. Pauling electronegativities are based on bond dissociation energies using a scale in which fluorine, the most electronegative element, has the value 4 and francium, the lowest electronegative element, has the value 0.7.