CHEMISTRY GLOSSARY

transition metal    →   prijelazni element

This group of metals is distinguished from other metals not by their physical properties, but by their electronic structure. Transition metals are elements characterized by a partially filled d subshell. The First Transition Series comprises scandium (Sc), titanium (Ti), vanadium (V), chromium (Cr), manganese (Mn), iron (Fe), cobalt (Co), nickel (Ni) and copper (Cu). The Second and Third Transition Series include the lanthanides and actinides, respectively.

The transition metals are noted for their variability in oxidation state. Thus, manganese has two electrons in its outside shell and five electrons in the next shell down, and exhibits oxidation states of +1, +2, +3, +4, +5, +6, and +7.

They are also characterised by the fact that well into the series, going from left to right, the properties of the succeeding metals do not differ greatly from the preceding ones.

wash bottle    →   boca štrcaljka

Plastic wash bottle is a squeeze bottle made of low density polyethylene (LDPE) whose contents can be forced out through a narrow hole at the top by squeezing the bottle.

Glass wash bottle is a bottle fitted with two glass tubes pass through the cap, so that on blowing into one of the tubes a stream of water issuing from the other may be directed upon anything to be washed or rinsed, as a precipitate upon a filter.

Ziegler process    →   Zieglerov proces

Ziegler process is an industrial process for the manufacture of high-density polyethene using catalysts of titanium(IV) chloride (TiCl₄) and aluminium alkyls (e.g. triethylaluminium, Al(C₂H₅)₃). The process was introduced in 1953 by the German chemist Karl Ziegler (1898-1973). It allowed the manufacture of polythene at lower temperatures (about 60 °C) and pressures (about 1 atm) than used in the original process.

T-S diagram    →   T-S dijagram

The relationship between the temperature (T) and the salinity (S) of a seawater can be illustrated graphically on a T-S diagram, which is a simple, but powerful tool used in studies of seawater density, mixing, and circulation. In a T-S diagram, temperature is plotted along the vertical axis in degrees Celsius and salinity is measured along the horizontal axis in PSU (Practical Salinity Units). Seawater density is illustrated in the diagram by curved lines of constant density (isopycnals). Water tends to move horizontally throughout the deep ocean, moving along lines of equal density.

Chitosan    →   Kitozan

Chitosan is a linear polysaccharide composed of randomly distributed N-acetyl D-glucosamine and D-glucosamine units. It can be easily derived from partial deacetylation of natural polymer chitin. At a minimum deacetylization level of 60 % (amount of free amino groups in the polymer) it is considered to be chitosan. Thanks to the amino groups of D-glucosamine, chitosan can be protonated and turned into polycation, which is one of the sources of unique properties of chitosan as biopolymer, like aqueous solubility, antibacterial properties, biodegradability with non-toxic residues and biocompatibility.