CHEMISTRY GLOSSARY

Born-Haber cycle    →   Born-Haberov kružni proces

Born-Haber cycle is a cycle of reactions used for calculating the lattice energies of ionic crystalline solids. For a compound MX, the lattice energy is the enthalpy of the reaction

The standard enthalpy of formation of the ionic solid is the enthalpy of the reaction

The cycle involves equating this enthalpy (which can be measured) to the sum of the enthalpies of a number of steps proceeding from the elements to the ionic solid. The steps are:

1) Atomization of the metal

2) Atomization of the nonmetal

3) Ionisation of the metal

This is obtained from the ionisation potential.

4) Ionisation of the nonmetal

This is electron affinity.

5) Formation of the ionic solids

Equation of the enthalpies gives

from which ΔH_L can be found.

Carnot cycle    →   Carnotov kružni proces

Carnot cycle is the most efficient cycle of operations for a reversible heat engine. Published in 1824 by French physicist Nicolas Léonard Sadi Carnot (1796-1832), it consists of four operations on the working substance in the engine:

1-2: Isothermal expansion at thermodynamic temperature T₁ with heat Q_H taken in.

2-3: Adiabatic expansion with a fall of temperature to T₂.

3-4: Isothermal compression at temperature T₂ with heat Q_C given out.

4-1: Adiabatic compression at temperature back to T₁.

According to the Carnot principle, the efficiency of any reversible heat engine depends only on the temperature range through which it works, rather than the properties of the working substances.

sublimation    →   sublimacija

Sublimation is the conversion of a substance from its solid form directly to its gaseous form without the intervening liquid form. Dry ice (frozen carbon dioxide) sublimates at normal room temperature.

EDTA    →   EDTA

Ethyldiaminetetraacetic acid (C₁₀H₁₆N₂O₈) or shortened EDTA is a hexadentant ligand, and it forms chelates with both transition-metal ions and main-group ions. EDTA is used as a negative ion - EDTA^4-. The diagram shows the structure of the ion with the important atoms picked out. The EDTA ion entirely wraps up a metal ion using all 6 of the positions. The co-ordination number is again 6 because of the 6 co-ordinate bonds being formed by the central metal ion.

EDTA is frequently used in soaps and detergents, because it forms a complexes with calcium and magnesium ions. These ions are in hard water and interfere with the cleaning action of soaps and detergents. EDTA is also used extensively as a stabilizing agent in the food industry and as an anticoagulant for stored blood in blood banks. EDTA is the most common reagent in complexometric titration.

gas liquefying    →   ukapljivanje plinova

In order to achieve transition of a gas into liquid state it is necessary to lower its temperature, or decrease its volume, or increase its pressure. Above the critical temperature it is impossible to liquefy a gas. When liquefying a gas by Linde’s procedure, dampening or Joule-Thomson’s effect is used. First, the compressed air from the compressor is cooled with cooling water, the cooled air expands at a lower pressure in the dampening valve at which it cooled. The cooled air now returns to the compressor, cooling down the expanding air. By repeating this process the air is cooled enough to transit to the liquid state.

ionisation    →   ionizacija

Ionisation is the process of producing ions. Certain molecules ionise in a solution; for example, acids ionise when dissolved in water.

Electron transfer also causes ionisation in certain reactions, for example sodium and chlorine react by transfer of a valence electron from the sodium atom to the chlorine atom to form the ions that constitute a sodium chloride crystal.

lanthanides    →   lantanoidi

Lanthanides (lanthanons, lanthanoids or rare-earth elements) are a series of fourteen elements in the periodic table, generally considered to range in proton number from cerium to lutetium inclusive. It was convenient to divide these elements into the cerium group or light earth: cerium (Ce), praseodymium (Pr), neodymium (Nd), promethium (Pm), samarium (Sm), europium (Eu); and the yttrium group or heavy earths: gadolinium (Gd), terbium (Tb), dysprosium (Dy), holmium (Ho), erbium (Er), thulium (Tm), ytterbium (Yb) i lutetium (Lu). The position of lanthanum is somewhat equivocal and, although not itself a lanthanide, it is often included with them for comparative purpose. The lanthanides are sometimes simply called the rare earths. Apart from unstable Pm, the lanthanides are actually not rare. Cerium is the 26. most abundant of all elements, 5 times as abundant as Pb. All are silvery very reactive metals.

luminescence    →   luminiscencija

Luminescence (from Latin lumen, light) is the emission of electromagnetic radiation (UV, visible or IR) from atoms or molecules as a result of the transition of an electronically excited state to a lower energy state, usually the ground state. Luminescence can be divided into categories by duration (fluorescence or phosphorescence) or by the mechanism that creates the light (radioluminescence, electroluminescence, photoluminescence, thermoluminescence, triboluminescence, chemiluminescence, bioluminescence). The prefix identifies the energy source responsible for generating or releasing the light.

Phosphorescence is emission of light from a substance exposed to radiation and persisting as an afterglow after the source of excitation has been removed. Fluorescence, on the other hand, is an almost instantaneous effect, ending within about 10^-8 second after excitation.

metallic glass    →   metalno staklo

Certain alloys can solidify by extremely rapid cooling out of melt without formation of a crystal lattice, that is in the amorphous form - such, amorphous alloys are so called metallic glasses. The alloy of zirconium, beryllium, titanium, copper, and nickel is one of the first metallic glasses that can be made in bulk and formed into strong, hard, useful objects.

Unlike pure metals and most metal alloys, metallic glasses have no regular crystalline structure. This lack of long range order or microstructure is related to such desirable features as strength and low damping which is one reason why the premier use for zirconium-based metallic glass is in the manufacture of expensive golf club heads. Metallic glasses can be quite strong yet highly elastic, and they can also be quite tough (resistant to fracture). Even more interesting are the thermal properties; for instance, just like an oxide glass, there is a temperature (called the glass transition temperature) above which a metallic glass becomes quite soft and flows easily. This means that there are lots of opportunities for easily forming metallic glasses into complex shapes.

Nusselt number    →   Nusseltova značajka

Nusselt number (Nu) is a dimensionless quantity used in fluid mechan-ics, defined by

where h is coefficient of heat transfer, l is length, and k is thermal conductivity.