CHEMISTRY GLOSSARY

non-metal    →   nemetal

Non-metals are defined as elements that are not metals.

Their physical properties generally include:

• They are poor conductors.
• They are brittle, not ductile in their solid state.
• They show no metallic lustre.
• They may be transparent or translucent.
• They have low density.
• They form molecules which consists of atoms covalently bonded; the noble gases are monoatomic.

Their chemical properties are generally:

• They usually have four to eight valence electrons.
• They have high electron affinities (except the noble gases)
• They are good oxidising agents (except the noble gases)
• They have hydroxides which are acidic (except the noble gases)
• They are electronegative.

octet rule    →   pravilo okteta

Octet rule states that the chemical properties of the elements repeat on a regular basis with increasing atomic mass, and that the chemical properties of each eight element are similar. Since the inert gases, with the exception of helium have eight electrons in their outer shells, this stable electronic configuration is called the octet rule. In chemical reactions atoms of elements tend to react in such a way as to achieve the electronic configuration of the inert gas nearest to them in the periodic table. There are a number of exceptions to the octet rule.

Onsager relations    →   Onsagerove relacije

Onsager relations are an important set of equations in the thermodynamics of irreversible processes. They express the symmetry between the transport coefficients describing reciprocal processes in systems with a linear dependence of flux (J_i) on driving forces (X_j).

In Onsager’s theory the coupling coefficients are equal, L_ij = L_ji. This is known as reciprocal relations. The theory was developed by the Norwegian chemist Lars Onsager (1903-1976) in 1931.

orbital    →   orbitala

Orbital is the area in space about an atom or molecule in which the probability of finding an electron is greatest.

The possible atomic orbitals correspond to subshells of the atom. Thus there is one s-orbital for each shell (orbital quantum number l = 0). There are three p-orbitals (corresponding to the three values of l) and five d-orbitals. The shapes of orbitals depend on the value of l.

organic    →   organski

1. Organic refers to any chemical compound based on carbon (C) with the exception of some of the simple compounds of carbon, such as carbon dioxide, which are frequently classified as inorganic compounds. Additional elements that are commonly found in organic compounds are hydrogen (H), nitrogen (N), oxygen (O), phosphorus (P) and sulfur (S).

2. Organic or organically-grown foods are grown or raised without synthetic fertilizers, pesticides, growth stimulators, or antibiotics and other drugs. Pests are controlled by cultivation techniques and the use of pesticides derived from natural sources and the use of natural fertilizers. In addition, organically grown foods must also be stored without the use of chemicals such as artificial additives and preservatives, and without food irradiation.

Ostwald’s process    →   Ostwaldov proces

Ostwald’s process is a process by which the nitric acid can be obtained in three degrees. In the first stage ammonia and oxygen react (with platinum-rhodium as a catalyst), whereby the nitrogen monoxide and water emerge

In the second stage nitrogen monoxide reacts with oxygen whereby nitrogen dioxide emerges

and in the third stage nitrogen dioxide dissolves in water, in the presence of air, giving the nitric acid

Ostwald’s viscometer    →   Ostwaldov viskozimetar

Ostwald viscometer, also known as U-tube viscometer or capillary viscometer is a device used to measure the viscosity of the liquid with a known density. The method of determining viscosity with this instrument consists of measuring the time for a known volume of the liquid (the volume contained between the marks A and B) to flow through the capillary under the influence of gravity. Ostwald viscometers named after the German chemist Wilhelm Ostwald (1853-1932).

The instrument must first be calibrated with materials of known viscosity such as pure (deionized) water. Knowing the value of viscosity of one liquid, one can calculate the viscosity of other liquid.

where η₁ and η₂ are viscosity coefficients of the liquid and water, and ρ₁ and ρ₂ are the densities of liquid and water, respectively.

oxygen    →   kisik

Oxygen was discovered by Joseph Priestley (England) in 1774. The origin of the name comes from the Greek words oxy genes meaning acid and forming (acid former). It is colourless, odourless gas; pale blue liquid. Extremely reactive. Forms oxides with nearly all other elements except noble gases. It is the most abundant element in the earth’s crust and makes up almost 21 % of the atmosphere. Oxygen is obtained primarily from liquid air by fractional distillation. Small amounts are made in the laboratory by electrolysis of water. Used in steel making, welding and supporting life. Naturally occurring ozone (O₃) in the upper atmosphere shields the earth from ultraviolet radiation.

palladium    →   paladij

Palladium was discovered by William Hyde Wollaston (England) in 1803. Named after the asteroid Pallas which was discovered at about the same time and from the Greek name Pallas, goddess of wisdom. It is soft, malleable, ductile, silvery-white metal. Resists corrosion; dissolves in oxidizing acids. Absorbs hydrogen. Metal dust is combustible. Palladium is obtained with platinum, nickel, copper and mercury ores. Used as a substitute for silver in dental items and jewellery. The pure metal is used as the delicate mainsprings in analog wristwatches. Also used in surgical instruments and as catalyst.

parallax    →   paralaksa

Parallax is a deceptive change of the position of an object which is observed while the position of the observer changes. Position of eye at all volumetric vessels must be at the same level as the meniscus. If not, the parallax will cause an error while reading the position of the meniscus of a liquid in a burette. It will be a positive mistake if the eye is lower, and negative if the eye is higher than the meniscus plane.