Water softeners are substances which help remove constant water hardness. It reacts with calcium and magnesium salts, creating compounds that do not react with soap.
The proportions of the major constituents of ocean water are almost constant throughout the world. Salinity (total salt content) and the concentrations of individual chemical constituents in sea wateris given the units psu (practical salinity units). For most purposes one can assume that the new unit, psu, and the older unit, ‰, are synonymous.
The average composition of the ocean water is as shown on the following table.
Constituent | Percentage of total salt |
---|---|
Chlorine | 55.3 % |
Sodium | 30.8 % |
Magnesium | 3.7 % |
Sulphur | 2.6 % |
Calcium | 1.2 % |
Potassium | 1.1 % |
Water purification is a procedure of harmful substances removal in order to obtain pure drinking-water.
Water softening is a process in which calcium and magnesium ions are removed from water. It is usually done by ion exchanger which exchanges removed ions with sodium ones.
The ion-product constant. For the reaction:
the equilibrium expression would be:
Note that all pure liquid terms are omitted, hence H2O does not appear in the denominator. At 25 °C
Water ion product (Kw) is a concentration product of hydrogen and hydroxide ions. For the reaction:
the equilibrium expression would be:
Note that all pure liquid terms are omitted, hence H2O does not appear in the denominator. At 25 °C, Kw = 1.0×10-14 mol2dm-6 = (Ka)(Kb)
Hardness is defined as the concentrations of calcium and magnesium ions expressed in terms of calcium carbonate. These minerals in water can cause some everyday problems. They react with soap and produce a deposit called soap curd that remains on the skin and clothes and, because it is insoluble and sticky, cannot be removed by rinsing.
Hard water may also shorten the life of plumbing and water heaters. When water containing calcium carbonate is heated, a hard scale is formed that can plug pipes and coat heating elements. Scale is also a poor heat conductor. With increased deposits on the unit, heat is not transmitted to the water fast enough and overheating of the metal causes failure. Build-up of deposits will also reduce the efficiency of the heating unit, increasing the cost of fuel.
There are two types of water hardness, temporary and permanent.
Temporary Hardness is due to the bicarbonate ion, HCO3-, being present in the water. This type of hardness can be removed by boiling the water to expel the CO2, as indicated by the following equation:
Permanent hardness is due to calcium and magnesium nitrates, sulphates, and chlorides etc. This type of hardness cannot be eliminated by boiling.
Water supply classification | |
---|---|
Hardness | Concentration of Calcium carbonate (mg/L) |
Soft Water | 0 to 75 |
Medium Hard Water | 75 to 150 |
Hard Water | 150 to 300 |
Very Hard Water | over 300 |
Aqueous solutions are those solutions where water is the solvent. An aqueous solution found in an equation describing a chemical reaction is denoted by the state symbol, (aq).
Conductivity is a measure of the ability of a material to conduct electric current.
Crystal water is water contained in certain salt crystals. It can be removed by heating. Crystals that contain crystal water are called hydrated and their salts hydrates.
Generalic, Eni. "Omekšivač vode." Croatian-English Chemistry Dictionary & Glossary. 29 June 2022. KTF-Split. {Date of access}. <https://glossary.periodni.com>.
Glossary
Periodic Table