CHEMISTRY GLOSSARY
Results 1–10 of 10 for nemetal
non-metal → nemetal
Non-metals are defined as elements that are not metals.
Their physical properties generally include:
- They are poor conductors.
- They are brittle, not ductile in their solid state.
- They show no metallic lustre.
- They may be transparent or translucent.
- They have low density.
- They form molecules which consists of atoms covalently bonded; the noble gases are monoatomic.
Their chemical properties are generally:
- They usually have four to eight valence electrons.
- They have high electron affinities (except the noble gases)
- They are good oxidising agents (except the noble gases)
- They have hydroxides which are acidic (except the noble gases)
- They are electronegative.
allotrope → alotrop
Allotropes are the elements which exist in two or more different forms in the same physical state. Allotropes generally differ in physical properties and may also differ in chemical activity.
Diamond, graphite and fullerenes are three allotropes of the element carbon. Graphite is a soft, black, slippery substance; by contrast, diamond is one of the hardest substances known. The different properties of the allotropes arise from their chemical structures. Diamonds typically crystallize in the cubic crystal system and consist of tetrahedrally bonded carbon atoms. Graphite crystallizes in the hexagonal system. In the fullerenes, the carbon atoms taking the form of a hollow sphere, ellipsoid, or tube.
In some cases, the allotropes are stable over a temperature range, with a definite transition point at which one changes into the other. For instance, tin has two allotropes: white (metallic) tin stable above 13.2 °C and grey (nonmetallic) tin stable below 13.2 °C.
The term allotropes may also be used to refer to the molecular forms of an element. Ozone is a chemically active triatomic allotrope of the element oxygen.
allotropy → alotropija
Allotropy (Gr. allos, other, and tropos, manner) is the phenomenon of an element existing in two or more physical forms in the same physical state. The difference between the forms involves either crystaline structure (white, red and black phosphorus), the number of atoms in the molecule of a gas (diatomic oxygen and triatomic ozone), or the molecular structure of a liquid (liquid helium an helium II).
In some cases, the allotropes are stable over a temperature range, with a definite transition point at which one changes into the other. For instance, tin has two allotropes: white (metallic) tin stable above 13.2 °C and grey (nonmetallic) tin stable below 13.2 °C. This form allotropy is called enantiotropy. Form of allotropy, in which there is no transition temperature at which the two are in equilibrium, is called monotropy.
Allotropy does not apply to the substance existing in different physical states as, for example, when ice melts and changes from solid ice to liquid water.
Allotropy is generally restricted to describing polymorphic behaviour in elements, while polymorphism may refer to any material having multiple crystal structures.
metalloid → polumetal
Metalloid (semimetal) is any of a class of chemical elements intermediate in properties between metals and nonmetals. The classification is not clear cut, but typical metalloids are boron (B), silicon (Si), germanium (Ge), arsenic (As), and tellurium (Te). They are electrical semiconductors and their oxides are amphoteric.
antimony → antimon
Antimony has been known since ancient times. The origin of the name comes from the Latin word stibium meaning mineral stibnite. It is hard, brittle, silvery-white semimetal. Stable in dry air. Toxic by ingestion or inhalation. Antimony is found in stibnite (Sb2S3) and in valentinite (Sb2O3). It is alloyed with other metals to increase their hardness. Also in the manufacture of a few special types of semiconductor devices. Also in plastics and chemicals. A few kinds of over-the-counter cold and flu remedies use antimony compounds.
Born-Haber cycle → Born-Haberov kružni proces
Born-Haber cycle is a cycle of reactions used for calculating the lattice energies of ionic crystalline solids. For a compound MX, the lattice energy is the enthalpy of the reaction
The standard enthalpy of formation of the ionic solid is the enthalpy of the reaction
The cycle involves equating this enthalpy (which can be measured) to the sum of the enthalpies of a number of steps proceeding from the elements to the ionic solid. The steps are:
1) Atomization of the metal
2) Atomization of the nonmetal
3) Ionisation of the metal
This is obtained from the ionisation potential.
4) Ionisation of the nonmetal
This is electron affinity.
5) Formation of the ionic solids
Equation of the enthalpies gives
from which ΔHL can be found.
corrosion → korozija
Corrosion is a harmful and undesirable construction material consumption by the chemical activity of its surroundings. Corrosion concept refers to metal and nonmetal construction materials, but it is usually used for metals, Corrosion of metal, according to the mechanism process, is divided into chemical (corrosion in nonelectrolytes) and electrochemical (corrosion in electrolytes).
Chemical corrosion appears by direct action of molecule of some element or compound on metal, thus directly creating corrosion products.
Electrochemical corrosion of metals occurs in electrolytes, so reduction of metal atom into free cation appears which by secondary processes gives molecules of compound which are considered a corrosion product.
halogens → halogeni elementi
Halogens are the elements fluorine (F) chlorine (Cl), bromine (Br), iodine (I), and astatine (At). They are non-metals, and make up part of the 17 group in the periodic table. Compounds of these elements are called halogenides or halides.
The halogens all have a strong unpleasant odour and will burn flesh. They do not dissolve well in water. The five elements are strongly electronegative. They are oxidising agents, with fluorine being the strongest and astatine being the weakest. They react with most metals and many non-metals.
Halogens form molecules which consist of atoms covalently bonded. With increasing atomic weight there is a gradation in physical properties. For example: Fluorine is a pale green gas of low density. Chlorine is a greenish-yellow gas 1.892 times as dense as fluorine. Bromine is a deep reddish-brown liquid which is three times as dense as water. Iodine is a grayish-black crystalline solid with a metallic appearance. And astatine is a solid with properties which indicate that it is somewhat metallic in character.
metal → metal
Metals are materials in which the highest occupied energy band (conduction band) is only partially filled with electrons.
Their physical properties generally include:
- They are good conductors of heat and electricity. The electrical conductivity of metals generally decreases with temperature.
- They are malleable and ductile in their solid state.
- They show metallic lustre.
- They are opaque.
- They have high density.
- They are solids (except mercury)
- They have a crystal structure in which each atom is surrounded by eight to twelve near neighbours
Their chemical properties generally are:
- They have one to four valence electrons.
- They have low ionisation potentials; they readily lose electrons.
- They are good reducing agents.
- They have hydroxides which are bases or amphoteric.
- They are electropositive.
Metallic characteristics of the elements decrease and non-metallic characteristics increase with the increase of valence electrons. Also metallic characteristics increase with the number of electron shells. Therefore, there is no sharp dividing line between the metals and non-metals.
Of the 114 elements now known, only 17 show primarily non-metallic characteristics, 7 others are metalloids, and 89 may be classed as metals.
Citing this page:
Generalic, Eni. "Nemetal." Croatian-English Chemistry Dictionary & Glossary. 29 June 2022. KTF-Split. {Date of access}. <https://glossary.periodni.com>.
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