CHEMISTRY GLOSSARY

Born-Haber cycle    →   Born-Haberov kružni proces

Born-Haber cycle is a cycle of reactions used for calculating the lattice energies of ionic crystalline solids. For a compound MX, the lattice energy is the enthalpy of the reaction

The standard enthalpy of formation of the ionic solid is the enthalpy of the reaction

The cycle involves equating this enthalpy (which can be measured) to the sum of the enthalpies of a number of steps proceeding from the elements to the ionic solid. The steps are:

1) Atomization of the metal

2) Atomization of the nonmetal

3) Ionisation of the metal

This is obtained from the ionisation potential.

4) Ionisation of the nonmetal

This is electron affinity.

5) Formation of the ionic solids

Equation of the enthalpies gives

from which ΔH_L can be found.

brass    →   mjed

Brasses are alloys of copper and zinc (generally 5 % to 40 %). Brass has been known to man since prehistoric times, long before zinc itself was discovered. It was produced by melting copper together with calamine, a zinc ore. Its ductility reaches a maximum with about 30 % zinc and its tensile strength with 45 % although this property varies greatly with the mechanical and heat treatment of the alloy. Typical applications included gears, plumbing ware fittings, adapters, valves and screw machine products. The French horn is a valved brass wind instrument.

Brass may contain small amounts of other alloying elements, such as aluminum, lead, tin, or nickel. Lead can be added as an alloying element resulting in a brass that can be rapidly machined and produces minimal tool wear. Additions of aluminium, iron and manganese to brass improve strength, whilst silicon additions improve wear resistance. Brass containing tin (< 2 % ) is less liable to corrosion in seawater; it is sometimes called naval brass and is used in naval construction.

equation of state    →   jednadžba stanja

Equation of state is an equation relating the pressure, volume, and temperature of a substance or system. Equation of state for ideal gas

where p is pressure, V molar volume, T temperature, and R the molar gas constant (8.314 JK^-1mol^-1).

glass    →   staklo

Glass is a brittle transparent solid with the molecular structure of a liquid. It is made by fusing together sand (SiO₂), soda (Na₂CO₃), and lime (CaCO₃) with small quantities other compounds. It is used for window panes and mirrors, for articles of table and culinary use, for lenses, and various articles of ornament.

electrolytes    →   elektroliti

Electrolytes are substances which, when melted or dissolved in water, conduct electric current. By melting or dissolving they are dissociated into electrically charged particles (ions) which are able to conduct electric current. By passing of electric current the transfer of matter occurs. Positively charged particles (cations) travel towards the negative pole (the cathode) and negatively charged particles (the anions) travel towards the positive pole (the anode). Liquid metals, in which the conduction is by free electrons, are not usually regarded as electrolytes. Solid conductors of ions, as in the sodium-sulphur cell, are also known as electrolytes. Depending upon how it conducts electric current, matter can be divided into strong electrolytes, weak electrolytes and nonconductors.

Gibbs free energy    →   Gibbsova slobodna energija

Gibbs free energy (G) is an important function in chemical thermodynamics, defined by

where H is the enthalpy, S the entropy, and T the thermodynamic temperature. Gibbs free energy is the energy liberated or absorbed in a reversible process at constant pressure and constant temperature. Sometimes called Gibbs energy and, in older literature, simply free energy.

Changes in Gibbs free energy, ΔG, are useful in indicating the conditions under which a chemical reaction will occur. If ΔG is negative the reaction will proceed spontaneously to equilibrium. In equilibrium position ΔG = 0.

gravimetrical factor    →   gravimetrijski faktor

Gravimetrical factor is stechiometric proportion between molar mass of analyte and molar mass of precipitate in gravimetry.

gravimetry    →   gravimetrija

Gravimetry is the quantitative measurement of an analyte by weighing a pure, solid form of the analyte. Since gravimetric analysis is an absolute measurement, it is the principal method for analysing and preparing primary standards.

A typical experimental procedure to determine an unknown concentration of an analyte in a solution is as follows:

- quantitatively precipitate the analyte from the solution

- collect the precipitate by filtering and wash it to remove impurities

- dry the solid in an oven to remove the solvent

- weigh the solid on an analytical balance

- calculate the analyte concentration in the original solution based on the weight of the precipitate.

Heat of atomisation    →   toplina atomiziranja

Heat of atomisation or enthalpy of atomisation is the energy required to dissociate one mole of a given substance into atoms.

heat of combustion    →   toplina izgaranja

Heat of combustion or enthalpy of combustion is the heat evolved when a definite quantity of a substance is completely oxidised (burned).